Efficient and stable adsorption uranium from wastewater by P-ZBCT composite adsorbent at low dosage.

In this research, a new synthesis approach was developed for an adsorbent, namely the phosphorylated ZIF-8/bamboo charcoal/chitosan/tannic acid (P-ZBCT) composite, for the efficient adsorption of uranyl ions from wastewater at low dosages. Impressively, the uranium adsorption rate of P-ZBCT reaches up to 98 % at a low dosage of 0.056 g/L in a 10-mg/L uranium solution, outperforming most reported uranium adsorption materials.

Collaborative disposal of beryllium-containing wastewater with modified graphite@chitosan from waste lithium-ion batteries.

In order to recover and effectively remove beryllium from beryllium-containing wastewater and relieve the environmental pressure caused by waste batteries. In this study, the gel material was synthesized based on the modified graphite material separated from the waste battery, and the graphite-@chitosan composite gel (CWBG@CH) was designed and synthesized. Interestingly, CWBG@CH has a maximum fitted adsorption capacity (Q) of 83.

An eco-friendly porous hydrogel adsorbent based on dextran/phosphate/amino for efficient removal of Be(II) from aqueous solution.

A novel environmentally-friendly porous hydrogel adsorbent (GHPN) is firstly designed and prepared using dextran, phosphate, and calcium hydroxide for the adsorption of Be(II). GHPN shows good adsorption selectivity for Be(II) (K = 1.53 × 10 mL/g).

Preparation of novel polyvinyl alcohol-carbon nanotubes containing imidazolyl ionic liquid/chitosan hydrogel for highly efficient uranium extraction from seawater.

A novel polyvinyl alcohol-carbon nanotube containing an imidazolyl ionic liquid/chitosan composite hydrogel (termed CBCS) was prepared for highly selective uranium adsorption from seawater. The results show that CBCS has good adsorption properties for uranium within the pH range of 5.0-8.

Mechanism for the seleikctive adsorption of uranium from seawater using carboxymethyl-enhanced polysaccharide-based amidoxime adsorbent.

Land-based uranium resources are becoming scarce because of the widespread development and use of nuclear energy. Therefore, to make up for the shortage of uranium resources, a new chitosan/carboxymethyl-β-cyclodextrin/quaternary ammonium salt-functionalized amidoxime carbon adsorbent (CSAOCF) was designed and synthesized for extracting uranium from seawater. Experimental studies show that the adsorption of uranium by CSAOCF is a spontaneous endothermic reaction and chemical adsorption.

Polyvinyl alcohol/phytic acid/phosphorylated chitosan hydrogel electrode highly efficient electroadsorption of low concentration uranium from uranium tailings leachate.

In order to improve the removal rate of uranium and reduce the harm of radioactive pollution, a physically crosslinked polyvinyl alcohol/phosphorylated chitosan (PPP) hydrogel electrode was designed by freezing thawing method. The results show that PPP hydrogel has a good adsorption effect on uranium, and 200 mL of uranium tailings leachate is absorbed, and the treatment efficiency reaches 100 % within 15 min. PPP hydrogel can adapt to a wide range of pH conditions and exhibit excellent adsorption efficiency in the range of 3-9.

Selective adsorption of uranium (VI) from wastewater using a UiO-66/calcium alginate/hydrothermal carbon composite material.

Uranium mining, smelting, and nuclear industries generate a considerable amount of wastewater containing uranium. To treat this wastewater effectively and inexpensively, a novel hydrogel material (cUiO-66/CA) was developed by co-immobilizing UiO-66 with calcium alginate and hydrothermal carbon. Batch tests were conducted to determine the optimal adsorption conditions for uranium using cUiO-66/CA, and the adsorption behavior was spontaneous and endothermic, confirming the quasi-second-order dynamics model and the Langmuir model.

Effect of mechanical-chemical modification on adsorption of beryllium by calcite.

The treatment of beryllium wastewater has become a major problem in industry. In this paper, CaCO is creatively proposed to treat beryllium-containing wastewater. Calcite was modified by an omnidirectional planetary ball mill by a mechanical-chemical method.

Phosphorylation improved the competitive U/V adsorption on chitosan-based adsorbent containing amidoxime for rapid uranium extraction from seawater.

A novel chitosan-based porous composite adsorbent with multifunctional groups, such as phosphoric acid, amidoxime, and quaternary ammonium groups, was prepared to improve the adsorption rate and competitive uranium‑vanadium adsorption of amidoxime group adsorbents. The maximum uranium adsorption capacity of PACNC was 962.226 mg g at 308 K and pH = 7.

Rapid oxidative removal of Fe and Mn from acidic mining wastewater by a new-type biofilter system: application and mechanism.

Aimed at the problem of excessive concentration of Fe and Mn in acidic mining wastewater during mining and utilization, a new rapid oxidative removal technology of Fe and Mn by a new-type biofilter system was designed and tested. The new-type biofilter system was constructed using a bioreactor filled with special mature bioceramic pellets after continuous biofilm cultivation as the filter layers. The results indicated that the biofilter system could efficiently treat five times its volume of wastewater per hour.

Effect of Surface Heterogeneities on Interactions between Air Bubbles and Heterogeneous Surfaces.

The effects of surface heterogeneities on bubble-particle interactions have received little attention although heterogeneities are common for varieties of substance surfaces. In this work, heterogeneous surfaces consisting of discrete hydrophilic dots on a hydrophobic background were fabricated. The interactions between air bubbles and heterogeneous surfaces with different hydrophilic area fractions were investigated using a high-sensitivity microbalance coupled with a high-speed video camera.

Adsorption of uranium by chitosan/Chlorella pyrenoidosa composite adsorbent bearing phosphate ligand.

In order to remove and recover uranium from acidic uranium-bearing wastewater in uranium mining and metallurgy. Herein, a novel chitosan/Chlorella pyrenoidosa composite adsorbent bearing phosphate ligand (CSP/CP) was designed and synthesized, demonstrating a high uranium adsorption capacity at a pH of 5 and excellent selectivity in an aqueous solution with eight coexisting ions. The CSP/CP exhibits a maximum adsorption capacity (1393.

Cotransport of uranyl carbonate loaded on amorphous colloidal silica and strip-shaped humic acid in saturated porous media: Behavior and mechanism.

Uranyl carbonate (UC(VI)) is a stable form of uranyl (U(VI)) that widely coexists with amorphous colloidal silica (ACSi) and humic acid (HA) in carbonate-rich U-contaminated areas. In this context, the cotransport behavior and mechanism of UC(VI) with ACSi (100 mg L) and HA colloids in saturated porous media were systematically investigated. It was found that the ACSi and strip-shaped HA have a strong adsorption capacity for UC(VI), and their adsorption distribution coefficient (K) is 4-5 orders of magnitude higher than that of quartz sand (QS).

Co-transport of uranyl carbonate and silica colloids in saturated quartz sand under different hydrochemical conditions.

Uranyl carbonate (UC) and silica colloids (cSiO) are widely distributed in carbonate-rich subsurface environments associated with uranium pollution. Mobile colloids such as cSiO can affect uranium's transport efficiency in the groundwater environment. Therefore, elucidating the mechanism of UC and cSiO co-transport in a saturated porous medium with different ionic strength (IS), pH, and UC concentration is essential for the prevention and control of groundwater radioactive pollution.

Synthesizing slow-release fertilizers via mechanochemical processing for potentially recycling the waste ferrous sulfate from titanium dioxide production.

The goal of this study is aimed to develop a novel process to recycle the ferrous sulfate, the by-product of titanium dioxide industry. Zinc sulfate was added in the process of milling ferrous sulfate with calcium carbonate (CaCO). The sulfates were transformed into carbonates to serve as slow-release fertilizers by co-grinding the starting materials of FeSO·7HO, ZnSO·7HO, and CaCO with small amounts of water in a planetary ball mill.