Room-temperature non-volatile optical manipulation of polar order in a charge density wave.

Utilizing ultrafast light-matter interaction to manipulate electronic states of quantum materials is an emerging area of research in condensed matter physics. It has significant implications for the development of future ultrafast electronic devices. However, the ability to induce long-lasting metastable electronic states in a fully reversible manner is a long-standing challenge.

Unraveling the origin of Kondo-like behavior in the 3-electron heavy-fermion compound YFeGe.

The heavy fermion (HF) state of [Formula: see text]-electron systems is of great current interest since it exhibits various exotic phases and phenomena that are reminiscent of the Kondo effect in [Formula: see text]-electron HF systems. Here, we present a combined infrared spectroscopy and first-principles band structure calculation study of the [Formula: see text]-electron HF compound YFe[Formula: see text]Ge[Formula: see text]. The infrared response exhibits several charge-dynamical hallmarks of HF and a corresponding scaling behavior that resemble those of the [Formula: see text]-electron HF systems.

Authentication and validation of key genes in the treatment of atopic dermatitis with Runfuzhiyang powder: combined RNA-seq, bioinformatics analysis, and experimental research.

Background: Atopic dermatitis (AD) is inflammatory disease. So far, therapeutic mechanism of Runfuzhiyang powder on AD remains to be studied. This study aimed to mine key biomarkers to explore potential molecular mechanism for AD incidence and Runfuzhiyang powder treatment.

A topological Hund nodal line antiferromagnet.

The interplay of topology, magnetism, and correlations gives rise to intriguing phases of matter. In this study, through state-of-the-art angle-resolved photoemission spectroscopy, density functional theory, and dynamical mean-field theory calculations, we visualize a fourfold degenerate Dirac nodal line at the boundary of the bulk Brillouin zone in the antiferromagnet YMnGe. We further demonstrate that this gapless, antiferromagnetic Dirac nodal line is enforced by the combination of magnetism, space-time inversion symmetry, and nonsymmorphic lattice symmetry.

Structure searches and superconductor discovery in XB (X = Sc, Ti, V, Cr, and Tc).

With extensive structure searches for XB (X = Sc, Ti, V, Cr, and Tc) under pressures up to 100 GPa, we uncovered that the crystal structures of these compounds with the lowest enthalpy have the same space group (6/) as MgB at ambient pressure. Among them, ScB, TiB and VB are dynamically stable at ambient pressure, but they do not superconduct. CrB becomes dynamically stable at 108 GPa and shows superconductivity with a transition temperature () of 26.

Divergent synthesis of carbamates and -methyl carbamates from dimethyl carbonate and nitroarenes with Mo(CO) as a multiple promoter.

Dialkyl carbonates are green and versatile reagents that can be used in alkylation and alkoxycarbonylation reactions. Herein, we disclosed a reductive methoxycarbonylation of aromatic nitro compounds with dimethyl carbonate for the construction of diverse carbamates and -methyl carbamates. Using Mo(CO) as a multiple promoter, different nitroarenes were smoothly transformed into the corresponding carbamates in yields between 27 and 94% using DMC as both solvent and reagent.

Direct synthesis of phthalimides palladium-catalysed double carbonylation of -dihaloarenes with nitroarenes.

The direct carbonylation of readily available nitro compounds is more attractive and straightforward than the use of traditional amines as nucleophiles. Herein, a practical palladium-catalysed double carbonylation of nitroarenes with -dihaloarenes has been developed for the construction of various -aryl phthalimides. Key to the success of this transformation is the use of Mo(CO), which acts as both a reducing agent and a solid carbonyl source.

Electrically controllable broadband reflective linear cross-polarization conversion based on liquid crystals.

This paper presents an electrically controllable reflective broadband linear polarization (LP) converter based on liquid crystals (LCs) for cross-polarization conversion (CPC) in the terahertz frequency range. The proposed structure achieves a high polarization conversion ratio (PCR) exceeding 0.9 within the frequency range of 236.

Manipulation of sub-terahertz waves using digital coding metasurfaces based on liquid crystals.

This paper presents a novel sub-terahertz liquid crystal (LC) phase shifter based on digital coding metasurfaces. The proposed structure consists of metal gratings and resonant structures. They are both immersed in LC.

Optimized sinusoidal patterns for high-performance computational ghost imaging.

Computational ghost imaging (CGI) can reconstruct scene images by two-order correlation between sampling patterns and detected intensities from a bucket detector. By increasing the sampling rates (SRs), imaging quality of CGI can be improved, but it will result in an increasing imaging time. Herein, in order to achieve high-quality CGI under an insufficient SR, we propose two types of novel sampling methods for CGI, to the best of our knowledge, cyclic sinusoidal-pattern-based CGI (CSP-CGI) and half-cyclic sinusoidal-pattern-based CGI (HCSP-CGI), in which CSP-CGI is realized by optimizing the ordered sinusoidal patterns through "cyclic sampling patterns," and HCSP-CGI just uses half of the sinusoidal pattern types of CSP-CGI.

Wideband linear cross-polarization conversion with 3D metamaterial configuration.

In this Letter, a broadband and wide-angle linear polarization (LP) converter based on a 3D resonator for cross-polarization conversion (CPC) is presented. The designed structure performs a CPC with a polarization conversion ratio (PCR) of more than 90% in the frequency range 16.32 to 34.

Correlation driven near-flat band Stoner excitations in a Kagome magnet.

Among condensed matter systems, Mott insulators exhibit diverse properties that emerge from electronic correlations. In itinerant metals, correlations are usually weak, but can also be enhanced via geometrical confinement of electrons, that manifest as 'flat' dispersionless electronic bands. In the fast developing field of topological materials, which includes Dirac and Weyl semimetals, flat bands are one of the important components that can result in unusual magnetic and transport behaviour.

Electrically active control of terahertz waves in a hybrid metasurface-grating structure with a liquid crystal.

A reflective terahertz phase shifter for wide-range dynamic and continuous phase modulation is proposed. By injecting a tunable liquid crystal between the slotted metasurface and the grating microstructure, the phases of reflected waves can be modulated with different electrically driven methods. Numerical simulations show that the proposed terahertz phase shifter has a phase difference of more than 360° between unbiased and biased states.

Rapid terahertz wave manipulation in a liquid-crystal-integrated metasurface structure.

A terahertz phase shifter based on liquid-crystal-integrated metasurface is proposed, which contains a three-slotted array structure and comb grating. The orientation of the liquid crystal molecules can be completely controlled by the direction of the electric field. From the acquired experimental results, it was demonstrated that the phase shift exceeds 300° in the range of 378.

Liquid crystal-based wide-angle metasurface absorber with large frequency tunability and low voltage.

A tunable metasurface absorber (MA) based on polymer network liquid crystal is introduced in this paper. Despite the well-designed unit cell patterns, the proposed MA can achieve both large frequency tunability and wide-angle stability. Compared with traditional liquid crystal-based metasurfaces, the measured results suggest that the recovery time of the proposed structure was reduced by half.

Active continuous control of terahertz wave based on a reflectarray element-liquid crystal-grating electrode hybrid structure.

In this work, a new and efficient terahertz reflective phase shifter is proposed. The phase shifter is composed of a metal-dielectric-metal structure with a double dipole patch array, as well as copper grating electrodes immersed within the nematic liquid crystal. More specifically, the employed copper grating electrodes consist of two sets of cross-distributed comb grids, whereas at each set of comb grids can be applied an external bias voltage separately.

Palladium-Catalyzed Reductive Double Carbonylation of Nitroarenes with Aryl Halides Using Mo(CO) as a Reductant and Carbonyl Source.

A new palladium-catalyzed reductive double carbonylation of nitroarenes with aryl halides for the synthesis of benzoxazin-4-ones has been reported. The key to success was the use of Mo(CO) as a reductant and bench-stable solid carbonyl sources. Various aryl iodides, bromides, and trifluoromethanesulfonates are suitable reaction partners and produce corresponding benzoxazin-4-one derivatives in moderate to good yields.

Transition-Metal-Catalyzed Carbonylative Multifunctionalization of Alkynes.

Currently, the construction of new carbon-carbon bonds and value-added structures in an atom- and step economical manner has become a continuous pursuit in the synthetic chemistry community. Since the first transition-metal-catalyzed hydroformylation of ethylene was reported by Otto Roelen in the 1930s, impressive progress has been achieved in the carbonylative functionalization of unsaturated C-C bonds. In contrast to alkenes, the carbonylative functionalization of alkynes offers tremendous potential for the construction of multisubstituted carbonyl-containing derivatives because of their two independently addressable π-systems.

Computational design of a new layered superconductor LaOTlF.

A new layered compound LaOTlF is designed and investigated using first-principles calculations in this work. The parent compound is an insulator with an indirect band gap of 3.88 eV.

Circular RNA lysophosphatidic acid receptor 3 (circ-LPAR3) enhances the cisplatin resistance of ovarian cancer.

Circular RNA (circRNA) is considered to be an important regulator that mediates cancer chemoresistance. But whether circ-LPAR3 is involved in ovarian cancer (OC) cisplatin (DDP) resistance is unclear. The circ-LPAR3, miR-634 and pyruvate dehydrogenase kinase 1 (PDK1) expression was measured by quantitative real-time PCR (qRT-PCR).

Ginsenoside RG1 augments doxorubicin-induced apoptotic cell death in MDA-MB-231 breast cancer cell lines.

This study determined the chemosensitizing potential of ginsenoside Rg1 in triple-negative MDA-MB-231 breast cancer cell lines. Ginsenoside Rg1 (10 µM) treated breast cancer cells were exposed to 8 nM of doxorubicin, and the chemosensitizing potential was measured by cell-based assays. Ginsenoside Rg1 (10 µM) treatment lowered the doxorubicin IC value to 0.