Mechanisms of antimony release from lacustrine sediments with increasing temperature.

Antimony (Sb) is more mobile in lacustrine sediments with seasonal warming. However, the mechanisms of Sb mobility in sediments are still unclear, especially considering the interactions among Sb, iron (Fe), manganese (Mn), and dissolved organic matter (DOM). In this study, high-resolution dialysis (HR-Peeper) and multi-spectral techniques simultaneously investigated changes in Sb, Fe, Mn, and DOM in two different ecological types (algal and grass) sediments with increasing temperature.

Sediment arsenic remediation by submerged macrophytes via root-released O and microbe-mediated arsenic biotransformation.

Arsenic (As)-contaminated water restoration is extremely challenging because As remobilization from sediments can result in episodic or long-term release of As to the overlying water. In this study, by combining high-resolution imaging techniques with microbial community profiling, we examined the feasibility of utilizing the rhizoremediation of submerged macrophytes (Potamogeton crispus) to decrease As bioavailability and regulate its biotransformation in sediments. Results showed that P.

Decrease in macrofauna density increases the sediment phosphorus release and maintains the high phosphorus level of water column in Lake Taihu: A case study on Grandidierella taihuensis.

Internal phosphorus (P) loading can increase the P level in the water column and further sustains cyanobacterial blooms. This study focused on the role of benthic fauna bioturbation in affecting the sediment P release and the P level of water column in a eutrophic lake, Lake Taihu. The macrofauna density decreased from 4766.

Three-dimensional arterial spin labeling and diffusion kurtosis imaging in evaluating perfusion and infarct area size in acute cerebral ischemia.

Background: Early thrombolytic therapy is crucial to treat acute cerebral infarction, especially since the onset of thrombolytic therapy takes 1-6 h. Therefore, early diagnosis and evaluation of cerebral infarction is important.

Aim: To investigate the diagnostic value of magnetic resonance multi-delay three-dimensional arterial spin labeling (3DASL) and diffusion kurtosis imaging (DKI) in evaluating the perfusion and infarct area size in patients with acute cerebral ischemia.

Selective and simultaneous high resolution 2-D imaging of As, Cr and Sb and dissolved oxygen by developing a new DGT technique comprising a hybrid sensor.

A new diffusive gradients in thin films technique (HR-MPTS DGT) with mercapto-functionalized attapulgite in a binding gel was developed for simultaneous two-dimensional (2-D) chemical imaging of As, Cr and Sb selectively at the submillimeter scale, combined with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis. The HR-MPTS DGT exhibited selective accumulation of As, Sb and Cr (> 97%), yet negligible accumulation of As, Sb and Cr (< 2%). Accumulation of As, Cr and Sb on the binding gel had a linear relationship (R > 0.

Mechanistic insights into trace metal mobilization at the micro-scale in the rhizosphere of Vallisneria spiralis.

Mobilization of trace metals in the rhizosphere of macrophytes is controlled by root-driven chemical changes, especially the steep gradients of O and pH from the rhizosphere to bulk sediments. Here, the O and pH dynamics, and the distribution of trace metal, in the rhizosphere of Vallisneria spiralis were obtained using planar optodes and diffusive gradients in thin films, respectively. Radial O loss (ROL) and acidification occurred on all visible roots of V.

Phosphorus acquisition strategy of Vallisneria natans in sediment based on in situ imaging techniques.

Phosphorus (P) availability is closely related to the distributions of pH, O and phosphatase activities in the rhizosphere of plants growing in soils and sediments. In this study, the P uptake processes and mechanisms of Vallisneria natans (V. natans) during two vegetation periods (i.

Identification, molecular evolution, and expression analysis of the transcription factor Smad gene family in lamprey.

Transcription factor small mothers against decapentaplegic (Smad) family SMAD proteins are the essential intracellular signal mediators and transcription factors for transforming growth factor β (TGF-β) signal transduction pathway, which usually exert pleiotropic actions on cell physiology, including immune response, cell migration and differentiation. In this study, the Smad family was identified in the most primitive vertebrates through the investigation of the transcriptome data of lampreys. The topology of phylogenetic tree showed that the four Smads (Smad1, Smad3, Smad4 and Smad6) in lampreys were subdivided into four different groups.

Terrain-modulated deposition of atmospheric lead in the soils of alpine forest, central China.

Alpine ecosystem has a potential to intercept the transport of atmospheric metals, while the regulation mechanisms with variations in altitude and slope direction remain unclear. In this study, the soil and moss samples on the northern and southern slopes of Shennongjia Mountain were collected with altitude to quantitatively identify the sources of lead (Pb) and to decipher the regulation mechanisms of altitude and slope on the Pb distribution. The results showed that the concentrations of Pb decreased evidently with soil depth, and in the O (organic soils) and A (surface mineral soils) horizons they increased with altitude.

O distribution and dynamics in the rhizosphere of Phragmites australis, and implications for nutrient removal in sediments.

Root-triggered microscale variations in O distribution in the rhizosphere of young Phragmites australis are important for nutrient removal in sediments. In this study, the micro-scale O dynamics and the small-scale changes of soluble reactive phosphorus (SRP) and ammonium (NH) in the rhizosphere of P. australis were investigated using planar optodes and high-resolution dialysis (HR-Peeper), respectively.

A new DGT technique comprising a hybrid sensor for the simultaneous high resolution 2-D imaging of sulfides, metallic cations, oxyanions and dissolved oxygen.

A new diffusive gradients in thin films technique (HR-ZCA DGT) was developed for simultaneous two-dimensional (2-D) chemical imaging of sulfides, metallic cations and oxyanions (S, Cd, Co, Fe, Cu, Mn, Ni, Pb, Zn, As, Cr, Mo, Sb, Se, V, P and W) at the submillimeter scale, combined with laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) analysis. A novel binding gel was prepared using a double precipitation method with AgI and zirconium oxide (Zr-oxide) deposited sequentially on a preformed Chelex-100 resin gel. A good linear relationship was observed (R>0.

Altitudinal-modulated sediment inputs rather than the land-uses determine the distribution of lead in the riparian soils of the Three Gorges Reservoir.

Lead (Pb) as a toxic metal has potential ecological hazards for aquatic quality. However, the variation in the distribution patterns of Pb and its fractions in flooding soils with frequent and anti-seasonal water-level fluctuation and various human disturbances remains unclear. In this study, the distribution of Pb and its fractions in the riparian soils of the Three Gorges Reservoir (TGR) were delineated based on the differences in altitude and land-uses including farmland, orchard, forest and residential area.

A new DGT technique comprised in a hybrid sensor for the simultaneous measurement of ammonium, nitrate, phosphorus and dissolved oxygen.

A new diffusive gradients in thin films technique (ZrO-AT DGT) with zirconium oxide, A-62 MP and T-42H resins containing in a single binding gel was developed for simultaneous measurement of nitrate (NO-N), ammonium (NH-N) and phosphate (PO-P). The DGT uptake was found to be independent of pH variation from 3.2-8.

Spatiotemporal distribution of vanadium in the flooding soils mediated by entrained-sediment flow and altitude in the Three Gorges Reservoir.

The re-emergence of vanadium (V) as a toxic metal has been highlighted recently due to its long-standing environmental and health hazard. This work targeted the world largest reservoir-Three Gorges Reservoir (TGR) to explore the spatial variation of V in the flooding soils from 2014 to 2018; meanwhile, the typical riparian zones with different altitudes and land-uses at the middle reach of the TGR were selected to decipher the key drivers on the V distribution. The results showed that the concentrations of soil V in the mainstream markedly exceeded local background, but they did not vary significantly with time except a marked increase at the upper-middle reaches.

Divergent patterns of soil phosphorus discharge from water-level fluctuation zone after full impoundment of Three Gorges Reservoir, China.

Phosphorus (P) discharged from soils in the water-level fluctuation (WLF) zone becomes increasingly important to the water quality control of the Three Gorges Reservoir (TGR) as the decrease in P input from upstream reaches and point-source pollution. To investigate the amount of soil P discharge from the WLF zone since the full impoundment of the TGR in 2010, soil and sediment samples were collected along the altitudinal gradients (140, 150, 160, 170, and 180 m above sea level) in three transects in the middle reaches of the TGR. Soil P composition was determined by a sequential extraction procedure.