Spectrochim Acta A Mol Biomol Spectrosc
March 2022
Sensitive determination of hypoxanthine (HX), an indicator reflecting the degradation of meat and fish, is significantly important in monitoring food freshness. Herein, we design a novel sensor consisting of orange emissive carbon dots (O-CDs), nitrotetrazolium blue chloride (NTBC), and xanthine oxidase (XOD) for fluorescence turn-off detection of HX. O-CDs, possessing a high fluorescence quantum yield of 37%, are synthesized by hydrothermal treatment of 2,3-diaminopyridine in sulfuric acid.
View Article and Find Full Text PDFFacile detection of malachite green (MG), a toxic dye, in aquaculture is urgently demanded for environment and food safety. Herein, we design a novel fluorescent probe, namely red emissive Se,N,Cl-doped carbon dots (CDs), to accurately determinate MG. CDs are prepared by hydrothermal treatment of selenourea and o-phenylenediamine in HCl solution.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
October 2020
In this paper, we exploit an innovative strategy to reuse waste rubber tires as a low-cost source for the fabrication of a high-value material, fluorescent carbon dots (CDs). In the hydrothermal condition, ammonium persulphate is utilized to oxidize the tires and offer nitrogen atom for doping, to produce CDs with a high quantum yield (QY) of up to 23.8%.
View Article and Find Full Text PDFCrystal violet (CV), a hazardous dye, poses a serious threat to the environment and human health. This motivates us to develop a facile method for its sensitive detection. Herein, we demonstrate a rapid sensing of CV using a novel fluorescent nanomaterial, yellow emissive Se,N-codoped carbon dots (CDs).
View Article and Find Full Text PDFMillion tons of sewage sludge produced yearly creates a severe pollution problem to environment, and thus needs either to be properly disposed of, or recovered. Here, we demonstrate a value-added utilization of sewage sludge by converting its contained organics into nanosized carbon dots (CDs) with microwave irradiation. This synthetic method, using waste resources as precursors and avoiding the requirement of hazardous reagents and complex procedures, has the great advantage of low cost, environmental friendliness, and easy scalability.
View Article and Find Full Text PDFThe increasing production of waste polyethylene terephthalate (PET) is a growing problem worldwide. Environmentally benign conversion of waste PET to valuable materials remains a substantial challenge. In this paper, we developed a green route to reuse waste PET for low-cost synthesis of fluorescent carbon dots (CDs) via air oxidation followed by hydrothermal treatment in aqueous HO solution.
View Article and Find Full Text PDFThe crystallization behavior of poly(butylene adipate) (PBA) in the sheared PBS/PBA blend, as well as on highly orientated poly(butylene succinate) (PBS) substrate, was studied by means of DSC, POM, Raman microscopy, and XRD. The results showed that the pre-existing orientated PBS crystals exhibit a very strong nucleation ability toward PBA as reflected by the increased crystallization temperature and the occurrence of heteroepitaxy and transcrystallization of PBA on the PBS substrate. The epitaxial crystallization of PBA on the PBS substrate results in the formation of α-form PBA crystals in any crystallization conditions.
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