Tunable Ultrafast Charge Transfer across Homojunction Interface.

Charge transfer at heterojunction interfaces is a fundamental process that plays a crucial role in modern electronic and photonic devices. The essence of such charge transfer lies in the band offset, making charge transfer uncommon in a homojunction. Recently, sliding ferroelectricity has been proposed and confirmed in two-dimensional van der Waals stacked materials such as bilayer boron nitride.

Accelerating the calculation of electron-phonon coupling strength with machine learning.

The calculation of electron-phonon couplings (EPCs) is essential for understanding various fundamental physical properties, including electrical transport, optical and superconducting behaviors in materials. However, obtaining EPCs through fully first-principles methods is notably challenging, particularly for large systems or when employing advanced functionals. Here we introduce a machine learning framework to accelerate EPC calculations by utilizing atomic orbital-based Hamiltonian matrices and gradients predicted by an equivariant graph neural network.

Organic Ligand Engineering for Tailoring Electron-Phonon Coupling in 2D Hybrid Perovskites.

In the emerging two-dimensional organic-inorganic hybrid perovskites, the electronic structures and carrier behaviors are strongly impacted by intrinsic electron-phonon interactions, which have received inadequate attention. In this study, we report an intriguing phenomenon of negative carrier diffusion induced by electron-phonon coupling in (2T)PbI. Theoretical calculations reveal that the electron-phonon coupling drives the band alignment in (2T)PbI to alternate between type I and type II heterostructures.

Ischemia reperfusion myocardium injuries in type 2 diabetic rats: Effects of ketamine and insulin on LC3-II and mTOR expression.

Myocardiopathy occurs in ischemia-induced injury caused by dysregulation of autophagy of cardiac tissues. The present report evaluates the protective effect of ketamine and insulin against myocardial injury in type 2 diabetic rats (T2DM). The effects of ketamine and its combination with insulin on biochemical parameters and inflammatory cytokines in the serum of I/R-induced myocardial injury in T2DM rats were evaluated.

Applicability and effectiveness of ultrasound combined with nerve stimulator-guided lumbosacral plexus block in the supine versus lateral position during surgeries for lower limb fracture-a prospective randomized controlled trial.

Background: Patients with lower limb fracture often have acute pain and discomfort from changes in position, and such pain affects early postoperative recovery. This study aimed to compare the applicability and effectiveness of ultrasound combined with nerve stimulator-guided lumbosacral plexus block (LSPB) in the supine versus lateral position during lower limb fracture surgery.

Methods: We included 126 patients who underwent elective internal fixation for lower limb fracture who were divided into the S group and the L group by the random number table method and underwent LSPB guided by ultrasound combined with a nerve stimulator in the supine and lateral positions, respectively.

Efficacy and safety of repeated esketamine intravenous infusion in the treatment of treatment-resistant depression: A case series.

Repeated intravenous administration of esketamine may increase and prolong the treatment efficacy of depressive patients. Firstly, the patient received esketamine (0.4 mg/kg intravenous over 40 min) infusion every other day, and totally 6 times infusion.

Dynamically reconfigurable topological edge state in phase change photonic crystals.

The observation of topological edge states (TESs) revolutionized our understanding of scattering and propagation of electromagnetic (EM) waves. Supported by topological robustness, the TES at the interface between trivial and non-trivial insulators was not reflected from the structural disorders and imperfections. Recently topological photonic crystals (PhCs) were demonstrated to obtain remarkable one-way propagation of the TES, having the advantages of lossless propagation, dense integration, and high fabrication tolerance over conventional PhCs.