Permanganate index (COD) is one of the important indicators of surface water quality measurement. Herein, a portable analytical system was developed for on-site and rapid analysis of COD, organic substances in water were oxidized and transformed into gases, so that COD concentration was converted into a change of gas pressure signal, the pressure signal change was further detected by a gas pressure meter. Heating method and ultraviolet (UV) irradiation method were used as assisting technologies for oxidization of organic substances by acidic KMnO, a linear range of 2-150 mg l and a detectable limit of 2 mg l were obtained.
View Article and Find Full Text PDFPurpose: To investigate the feasibility and effect of free latissimus dorsi myocutaneous flap in the reconstruction of giant head and neck defects.
Methods: Free latissimus dorsi myocutaneous flap on the cadaver was simulated dissected, and measured by Image-Pro Plus 6.0 to assess the feasibility of repairing giant head and neck defects.
Chemical vapor generation (CVG) was used as a gaseous sample introduction technique for the visual/smartphone RGB readout colorimetric system, with the advantages of efficient matrix elimination and high vapor generation efficiency, this analytical system exhibits a good selectivity and sensitivity. Sulfide ion (S) in solution was transformed to its volatile form (HS), the generated HS reacted with a silver-containing metal organic framework (Ag-BTC) selectively, AgS was thus generated. Ag-BTC (fabricated on paper sheet) changed from white to dark brown, the color variance was identified by smartphone and naked-eye simultaneously.
View Article and Find Full Text PDFThe reaction mechanism of Ag-containing metal organic framework (Ag-BTC) and hydrogen arsenide (AsH) was discussed in detail in this work. Silver ions in Ag-BTC were reacted with AsH, and silver nanoparticles were generated on the surface of Ag-BTC, causing its color changed. This property was further applied to a hydride generation-colorimetric analytical system.
View Article and Find Full Text PDFIt is necessary to efficient detection hydrazine in food. Exploring highly sensitive, low-cost and fast response electrochemical hydrazine sensing methods has been a challenge in this field. In this paper, a conformal transformation method is used to prepare rose flower-like NiCo-LDH derivating from the bimetallic NiCo-MOFs, and the NH sensing platform with a large electrocatalytic area, high conductivity and good stability was constructed.
View Article and Find Full Text PDFA miniaturized/portable dual-mode colorimetric analytical system was established for inorganic arsenic determination in honey and drinking water samples. Hydride generation (HG) was utilized as a sampling technique for this colorimetric system, because of its high generation efficiency and efficient matrix separation. AsH was generated HG and then reacted with HAuCl, gold nanoparticles (Au NPs) were formed on the paper sheet, leading the paper color changed from light yellow to dark blue, it could be readout by naked-eye (visual colorimetric mode) and a smartphone (RGB readout mode) simultaneously.
View Article and Find Full Text PDFIn this paper, Co-doped NiMoO nanorods with oxygen vacancies are synthesized on carbon cloth (Co-NiMoO NRs/CC) via microplasma and quenching-induced method.Owing to the surface defects and metal ion doping, the electronic structure and surface properties of the catalyst are tuned.Cyclic voltammetry (CV) and amperometry are used to investigate the electrocatalytic behavior of the glucose sensor in an alkaline medium with sensitivities of 7411 and 3125 μA L mmol cm in the linear range 1.
View Article and Find Full Text PDFIn this study, a 3D surface-folded composite was prepared as a hydrazine sensor by loading a hybrid film of CoNi-layered double hydroxides (LDHs) with nitrogen-doped carbon dots on self-assembled ZnO microspheres. The nanocomposite was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR), and the electrochemical behavior of the sensors was investigated by cyclic voltammetry (CV), amperometry and electrochemical impedance spectroscopy (EIS). The results showed that ZnO microspheres with nitrogen-doped carbon dots strongly coupled with LDHs can significantly reduce the charge transfer resistance, accelerate the oxidation kinetics of hydrazine, and effectively increase the electrochemically active surface area (ECSA).
View Article and Find Full Text PDFThe rational design of high-efficiency catalysts for non-enzymatic glucose sensing is extremely important for the timely and effective monitoring of glucose content in beverages and human blood. A 3D bimetallic organic framework (Coordination Polymer of Oslo, CPO) nanorod array with oxygen vacancies was green fabricated on carbon cloth (NiCo-CPO-27 NRA/CC) using dielectric barrier discharge (DBD) microplasma for the first time. Density functional theory (DFT) calculations demonstrated that the oxygen vacancy of NiCo-CPO-27 can be effectively induced under DBD microplasma conditions.
View Article and Find Full Text PDFComposited carbon nanomaterials have attracted wide attention and are used for high-sensitivity biological assays due to their low toxicity, good biocompatibility, and excellent electrical conductivity. To further promote electron transfer and enhance electrocatalytic activity to detect dopamine (DA), this study proposed carbon dots (CDs) based on glycerol synthesized by liquid dielectric barrier discharge (DBD) microplasma. Combined with the multi-walled carbon nanotubes (MWCNTs) with excellent electrical conductivity, a composited carbon nanomaterial electrode of CDs/MWCNTs was constructed.
View Article and Find Full Text PDFIn this work, a 3D ultra-thin NiCo-LDH nanosheet array coated Cu nanoparticles on carbon cloth (NiCo-LDH@Cu NSA/CC) was ultrafast synthesized by plasma magnetron sputtering for the first time. This method has low toxicity and is easy to operate. As a durable and efficient 3D heteronanoarray electrocatalyst for glucose detection, NiCo-LDH@Cu NSA/CC has higher stable conductivity and faster electron transport rate than NiCo-LDH NSA/CC and Cu nanoparticles, which work through synergistic effect to form a high-performance sensing platform.
View Article and Find Full Text PDFA miniaturized/portable visual colorimetric system based on hydride generation headspace solid phase extraction (HG-HS-SPE) was proposed for arsenic detection by naked eyes. As(III) was transformed into AsHvia hydride generation process, the volatile AsH was introduced into reaction bottle and reacted with AgNO subsequently. Silver nanoparticles (Ag NPs) were generated in situ, resulting in the color changed from white to black, it could be readout by naked eyes or a smartphone application (color extraction, for RGB readout).
View Article and Find Full Text PDFThe red light (R) to far-red light (FR) ratio (R:FR) regulates plant responses to salt stress, but the regulation mechanism is still unclear. In this study, tomato seedlings were grown under half-strength Hoagland solution with or without 150 mM NaCl at two different R:FR ratios (7.4 and 0.
View Article and Find Full Text PDFPhotoperiod is a crucial inducer of plant flowering. Cycling DOF factors (CDFs) play pivotal roles in the flowering of long-day (LD) and short-day (SD) plants. However, the functions of in the photoperiod regulated flowering remain unclear in day-neutral plants.
View Article and Find Full Text PDFIn plants, 14-3-3 proteins are recognized as mediators of signal transduction and function in both development and stress response. However, there are only a few preliminary functional researches in the C4 crop foxtail millet. Here, phylogenetic analysis categorized foxtail millet 14-3-3s (SiGRFs) into 10 discrete groups (Clusters I to X).
View Article and Find Full Text PDFThe extensive use of chemical fertilizers poses serious collateral problems such as environmental pollution, pest resistance development and food safety decline. Researches focused on applying plant-beneficial microorganisms to partially replace chemical fertilizer use is increasing due to the requirement of sustainable agriculture development. Thus to investigate the possibility of a plant-beneficial Trichoderma strain and its bio-organic fertilizer product in saving chemical fertilizer application and in improving crop quality, a field trial and continuous pot experiments were carried out with tomato.
View Article and Find Full Text PDFPlants grown under highly variable natural light regimes differ strongly from plants grown under constant light (CL) regimes. Plant phenotype and adaptation responses are important for plant biomass and fitness. However, the underlying regulatory mechanisms are still poorly understood, particularly from a transcriptional perspective.
View Article and Find Full Text PDFCarbon dioxide concentration (CO ) and light intensity are known to play important roles in plant growth and carbon assimilation. Nevertheless, the underlying physiological mechanisms have not yet been fully explored. Tomato seedlings (Solanum lycopersicum Mill.
View Article and Find Full Text PDFSalinity-alkalinity stress has caused severe environment problems that negatively impact the growth and development of watermelon ( L.). In this study, watermelon seedlings were inoculated with the arbuscular mycorrhizal fungi (AMF) to investigate its effect on watermelon growth and development.
View Article and Find Full Text PDFDowny mildew (DM), caused by Pseudoperonospora cubensis, is one of the major foliar diseases prevailing in cucumber-growing areas. The mechanism of DM resistance in cucumber, particularly the plant introduction (PI) 197088 from India, is presently unclear. Quantitative trait locus (QTL) mapping is an efficient approach to studying DM resistance genes in cucumber.
View Article and Find Full Text PDFThis study demonstrated the application of transmasseteric anterior parotid approach for open reduction of mandibular subcondylar fractures depending on the basis of the anatomical study of the temporomandibular joint and parotid gland area. The anatomical study was performed on 5 Chinese adult cadavers fixed by 10% formalin. The temporomandibular joints and parotid regions were studied.
View Article and Find Full Text PDFBackground: Phytochromes are dimeric proteins with critical roles in perceiving day length and the environmental signals that trigger flowering. Night break (NB) and the red to far-red light ratio (R:FR) have been used extensively as tools to study the photoperiodic control of flowering. However, at the molecular level, little is known about the effect of NB and different R:FR values on flowering in day-neutral plants (DNPs) such as tomato.
View Article and Find Full Text PDFBackground: Red (R) and far-red (FR) light distinctly influence phytochrome-mediated initial tomato growth and development, and more recent evidence indicates that these spectra also modulate responses to a multitude of abiotic and biotic stresses. This research investigated whether different R: FR values affect tomato growth response and salinity tolerance. Tomato seedlings were exposed to different R: FR conditions (7.
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