The growing popularity of quasi-solid-state supercapacitors inevitably leads to the unrestricted consumption of commonly used petroleum-derived polymer electrolytes, causing excessive carbon emissions and resulting in global warming. Also, the porosity and liquid electrolyte uptake of existing polymer membranes are insufficient for well-performed supercapacitors under high current and long cycles. To address these issues, poly(lactic acid) (PLA), a widely applied polymers in biodegradable plastics is employed to fabricate a renewable biocomposite membrane with tunable pores with the help of non-solvent phase inversion method, and a small amount of poly (vinylidene fluoride-co-hexafluoropropylene) (PVDF-HFP) is introduced as a modifier to interconnect with PLA skeleton for stabilizing the porous structure and optimizing the aperture of the membrane.
View Article and Find Full Text PDFComposite polymer electrolyte (CPE) films with high room temperature ionic conductivity are urgently needed for the practical application of high-safety solid-state batteries (SSBs). Here, a flexible polymer-polymer CPE thin film reinforced by a three-dimensional (3D) bacterial cellulose (BC) framework derived from natural BC hydrogel was prepared via thephoto-polymerization method. The BC film was utilized as the supporting matrix to ensure high flexibility and mechanical strength.
View Article and Find Full Text PDFSolid-state batteries (SSBs) have attracted considerable attention for high-energy-density and high-safety energy storage devices. Many efforts have focused on the thin solid-state-electrolyte (SSE) films with high room-temperature ionic conductivity, flexibility, and mechanical strength. Here, we report a composite polymer electrolyte (CPE) reinforced by electrospun PI nanofiber film, combining with succinonitrile-based solid composite electrolyte.
View Article and Find Full Text PDFLithium-sulfur batteries are one of the most promising energy storage systems due to their high energy density. Many efforts have been made to improve the electrochemical performance of lithium-sulfur batteries. However, the complex and time-consuming preparation process hinders their practical application.
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