Publications by authors named "Zhenhua Chi"

A B-site ordered double perovskite oxide CdCrSbO was synthesized under high-pressure and high-temperature conditions. The compound crystallizes to a monoclinic structure with a space group of 2/. The charge configuration is confirmed to be that of Cd/Cr/Sb.

View Article and Find Full Text PDF

The unique electronic structure and crystal structure driven by external pressure in transition metal tellurides (TMTs) can host unconventional quantum states. Here, the discovery of pressure-induced phase transition at ≈2 GPa, and dome-shaped superconducting phase emerged in van der Waals layered NbIrTe is reported. The highest critical temperature (T ) is ≈5.

View Article and Find Full Text PDF
Article Synopsis
  • The crystal structure of EuSn₂As₂ is identified as a magnetic topological insulator in its layered form and has a Bi₂Te₃-like rhombohedral symmetry.
  • Under high pressure (above 14 GPa), it transitions to a new monoclinic structure characterized by a complex 3D network of honeycomb-like Sn sheets and zigzag As chains due to a two-stage reconstruction process.
  • Electrical resistance tests show a transition from insulator to metal, and ultimately to superconductor (with a T_C of ~4 K), which occurs at specific pressures (5 and 15 GPa), indicating the material's fascinating structural and electronic properties.
View Article and Find Full Text PDF

As a follow-up of our previous work on pressure-induced metallization of the 2H_{c}-MoS_{2} [Chi et al., Phys. Rev.

View Article and Find Full Text PDF

As a new type of topological materials, ZrTe5 shows many exotic properties under extreme conditions. Using resistance and ac magnetic susceptibility measurements under high pressure, while the resistance anomaly near 128 K is completely suppressed at 6.2 GPa, a fully superconducting transition emerges.

View Article and Find Full Text PDF

Tungsten ditelluride has attracted intense research interest due to the recent discovery of its large unsaturated magnetoresistance up to 60 T. Motivated by the presence of a small, sensitive Fermi surface of 5d electronic orbitals, we boost the electronic properties by applying a high pressure, and introduce superconductivity successfully. Superconductivity sharply appears at a pressure of 2.

View Article and Find Full Text PDF

From high precision measurements of the complex dielectric constant of especially prepared samples of H2O, we identify the onset temperatures of the phase transition into and out of ice XI from ice Ih to occur at TIh-XI = 58.9 K and TXI-Ih = 73.4 K.

View Article and Find Full Text PDF

X-ray diffraction, Raman spectroscopy, and electrical conductivity measurements of molybdenum disulfide MoS(2) are performed at pressures up to 81 GPa in diamond anvil cells. Above 20 GPa, we find discontinuous changes in Raman spectra and x-ray diffraction patterns which provide evidence for isostructural phase transition from 2H(c) to 2H(a) modification through layer sliding previously predicted theoretically. This first-order transition, which is completed around 40 GPa, is characterized by a collapse in the c-lattice parameter and volume and also by changes in interlayer bonding.

View Article and Find Full Text PDF

A cryogenic loading system for introducing H(2) and D(2) into the diamond anvil cell has been designed and constructed. The integration of pressure loading mechanism, ruby fluorescence spectrometer, and microscope camera allows for in situ tuning and calibrating the pressure. The performance of the system has been demonstrated by successful synthesis of hydride and deuteride of transition metal and rare earth metal.

View Article and Find Full Text PDF

Single-phased polycrystalline BiMnO(3) (hereinafter abbreviated as BMO) ceramic was fabricated via high-pressure solid-state reaction. Microstructure modification of selective grains, signalled by emergence of superlattice diffraction, was scrutinized by means of electron diffraction (ED) combined with high-resolution transmission electron microscopy (HRTEM). It was clearly evidenced that the well established C 2 monoclinic substructure (a = 9.

View Article and Find Full Text PDF