Poly(ethylene oxide) (PEO)-based electrolytes are often used for Li conduction as they can dissociate the Li salts efficiently. However, high entanglement of the chains and lack of pathways for rapid ion diffusion limit their applications in advanced batteries. Recent developments in ionic covalent organic frameworks (iCOFs) showed that their highly ordered structures provide efficient pathways for Li transport, solving the limitations of traditional PEO-based electrolytes.
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