Microplastics and nanoplastics are emerging contaminants that pose a threat to the environment and human. Spectroscopic technologies are advantageous in analyzing nanoplastics, but it is challenging to selectively detect nanoplastics with different size thresholds. In this work, the hyphenated method of electrosorption and surface-enhanced Raman spectroscopy (ES-SERS) was developed for the simple, rapid, and size-resolved analysis of trace polystyrene (PS) nanoplastics from 20 to 300 nm.
View Article and Find Full Text PDFRapid identification of DNA oxidative damage sites is of great significance for disease diagnosis. In this work, electric field-regulated click reaction surface-enhanced Raman spectroscopy (e-Click-SERS) was developed aiming at the rapid and specific analysis of furfural, the biomarker of oxidative damage to the 5-carbon site of DNA deoxyribose. In e-Click-SERS, cysteamine-modified porous Ag filaments (cys@p-Ag) were prepared and used as electrodes, amine-aldehyde click reaction sites, and SERS substrates.
View Article and Find Full Text PDFDue to its special coordination ability to Cu(II)-terpyridine complexes, a simple and straightforward visual recognition of p-DMAP out of its analogues has been realized via selective metallogel collapse. In combination with the selective gel collapse and the self-healing properties of metallohydrogel , its potential application towards chemo-switch is also demonstrated.
View Article and Find Full Text PDFChem Commun (Camb)
September 2014
By using metallo-hydrogel as a new platform, a simple and straightforward selective visual discrimination of cysteine, homocysteine and glutathione from each other as well as from other amino acids has been realized.
View Article and Find Full Text PDFIncorporating the visual discrimination of 2,2'-bipyridine and self-healing properties, a novel photo-switchable metallo-hydrogel system is fabricated using a pincer-type Cu(II) complex and 2,2'-azopyridine.
View Article and Find Full Text PDFCleft Palate Craniofac J
July 2010
Objective: To investigate the effects of unrepaired cleft palate on the development of vocabulary comprehension and expression of Chinese children aged 8 to 15 months.
Methods: The parents or caregivers of 40 infants with unrepaired cleft palate were recruited from the Cleft Lip and Palate Center at the Stomatology School of Peking University. Vocabulary development was assessed using a parent report protocol, the Chinese Communicative Development Inventory: Infant, for Putonghua (PCDI: Infant).