As of the present time, the in-depth study of the structure-activity relationship between electronic configuration and CO photoreduction performance is often overlooked. Herein, a series of Cu species modified CeO nanodots are constructed in situ by flame spray pyrolysis (FSP) to achieve an efficient photocatalytic CO-to-C conversion with an electron utilization of up to 142.5 µmol g.
View Article and Find Full Text PDFACS Appl Mater Interfaces
February 2020
The interfaces between two-dimensional (2D) materials and the silicon dioxide (SiO)/silicon (Si) substrate, generally considered as a solid-solid mechanical contact, have been especially emphasized for the structure design and the property optimization in microsystems and nanoengineering. The basic understanding of the interfacial structure and dynamics for 2D material-based systems still remains one of the inevitable challenges ahead. Here, an interfacial mobile water layer is indicated to insert into the interface of the degraded black phosphorus (BP) flake and the SiO/Si substrate owing to the induced hydroxyl groups during the ambient degradation.
View Article and Find Full Text PDFUnderstanding the nanoscale friction properties of 2D materials and further manipulating their friction behaviors is of great significance for the development of various micro/nanodevices. Recent studies, taking advantage of the close relationship between friction and surface charges, use an external out-of-plane electric field to control the interfacial friction. Nevertheless, friction increases with the application of the out-of-plane electric field in most cases.
View Article and Find Full Text PDF