A thorium-carbon double bond that corresponds to the sum of theoretical covalent double bond radii has long been sought after in the study of actinide-ligand multiple bonding as a synthetic target. However, the stabilization of this chemical bond remains a great challenge to date, in part because of a relatively poor energetic matching between 5f-/6d- orbitals of thorium and the 2s-/2p- frontier orbitals of carbon. Herein, we report the successful synthesis of a thorium-carbon double bond in a carbon-bridged actinide-transition metal cluster, i.
View Article and Find Full Text PDFMetal-metal bonding is crucial in chemistry for advancing our understanding of the fundamental aspects of chemical bonds. Metal-metal bonds based on alkaline-earth (Ae) elements, especially the heavier Ae elements (Ca, Sr, and Ba), are rarely reported due to their high electropositivity. Herein, we report two heteronuclear di-EMFs CaY@(6)-C and CaY@(5)-C, which contain unprecedented single-electron Ca-Y metal-metal bonds.
View Article and Find Full Text PDFHydrodenitrogenation (HDN) experiments and density functional theory (DFT) calculations were combined herein to study the substituent effects of the nitrogen heterocycle on the HDN behaviors of indole and quinoline. Indole (IND), 2-methyl-indole (2-M-IND), 3-methyl-indole (3-M-IND), quinoline (QL), 2-methyl-quinoline (2-M-QL) and 3-methyl-quinoline (3-M-QL) were used as the HDN reactant on the NiMo/γ-AlO catalyst. Some key elementary reactions in the HDN process of these nitrogen compounds on the Ni-Mo-S active nanocluster were calculated.
View Article and Find Full Text PDFA long-time evaluation of -butane oxidation over an industrial vanadium-phosphorus-oxygen (VPO) catalyst was implemented. The catalytic performances for -butane oxidation during this period were obtained. It was shown that the conversion of -butane increased with the evaluation time, but the selectivity of the maleic anhydride (MA) product decreased gradually.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2022
Advanced microwave absorption (MA) materials have attracted widespread attention to meet the challenges of electromagnetic (EM) pollution. Herein, MgFeO/MgO/C fibers were successfully prepared via electrospinning technology and carbonization, and their surfaces were coated by MoS via hydrothermal method. The EM wave absorption performance of composites was enhanced due to the introduction of MoS.
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