Catalytic Enantioselective [4+2] Cycloadditions of Salicylaldehyde Acetals with Enol Ethers.

A readily accessible conjugate-base-stabilized carboxylic acid (CBSCA) catalyst facilitates highly enantioselective [4+2] cycloaddition reactions of salicylaldehyde-derived acetals and cyclic enol ethers, resulting in the formation of polycyclic chromanes with oxygenation in the 2- and 4-positions. Stereochemically more complex products can be obtained from racemic enol ethers. Spirocyclic products are also accessible.

Divergent Functionalization of Alkynes Enabled by Organic Photoredox Catalysis.

Direct functionalization of alkynes under oxidative conditions is challenging, as alkynes are usually recalcitrant towards typical oxidants. Herein, we communicate a strategy for the divergent functionalization of alkynes with photoexcited acridinium organic dyes, presumably via the formation of vinyl cation radicals as key intermediates. Based on the nature of the nucleophiles, different types of difunctionalized products were obtained in moderate to good yields.

Freeform mirror array design for concentrating sunlight onto a CPV solar cell.

In a concentrating photovoltaic (CPV) system, realizing an illumination spot consistent with the photosensitive area of the CPV cell while maintaining high optical performances is a challenging but rewarding issue. For instance, uniform irradiance distribution not only reduces the risk of damage to CPV cells due to the local heat accumulation, but also improves photoelectric conversion efficiency; free chromatic aberration ensures that a wide solar spectrum can be regulated; a high concentration ratio helps reduce the usage of CPV cells, and so on. Here, we propose a method to design a freeform mirror array to concentrate sunlight and generate a square light pattern with uniform irradiance distribution on the photovoltaic cell.

Design and parameter study of banana crown mechanical cutting device.

Banana mechanical crown cutting tool which is a critical component of banana crown cutting machine is designed and studied in this paper. Experiments were designed to optimize parameters of the cutting tool. Indexes are cut surface quality grade of banana crown, maximum cutting force and useful power consumption.

Freeform illumination optics design for extended LED sources through a localized surface control method.

Freeform illumination optics design with extended light sources to realize an accurate light control is very important, but still remains a challenging issue. Here, we propose a new method to design compact and efficient freeform lenses for extended sources. We employ a localized surface control strategy to directly modify the freeform surface to redistribute the light rays emitted from the extended LED source in a desired manner.

Freeform illumination optics for 3D targets through a virtual irradiance transport.

Freeform illumination optics design for 3D target surfaces is a challenging and rewarding issue. The current researches on freeform illumination optics are mostly involved in planar targets, especially for the cases where the targets are perpendicular to the optical axis. Here, we propose a general method to design freeform optics for illuminating 3D target surfaces for zero-étendue sources.

Least-squares ray mapping method for freeform illumination optics design: erratum.

We provide corrections of the author list as well as Eq. (12) and (13) in our previous publication [Opt. Express28, 38113811 (2020)10.

Design of a high-throughput telescope based on scanning an off-axis three-mirror anastigmat system.

A high-throughput optical system possesses a large field of view (FOV) and high resolution. However, it is a major challenge to design such a telescope with these two conflicting specifications. In this paper, we propose a method to design a high-throughput telescope based on the classical off-axis three-mirror anastigmat (TMA) configuration by introducing a scanning mechanism.

Variable-diameter beam-shaping system design with high zoom ratio containing aspheric optical components.

Recently, the optical design of refractive beam-shaping systems has been extensively studied, although such study remains focused on two optical surfaces. Designing a beam-shaping system with variable output beam sizes and prescribed irradiance profiles remains a challenging but rewarding task. Here, we present a design framework, including calculation of the initial system and optimization process, to achieve variable-diameter beam-shaping systems with high zoom ratios.

Hemin-decreased cadmium uptake in pak choi (Brassica chinensis L.) seedlings is heme oxygenase-1 dependent and relies on its by-products ferrous iron and carbon monoxide.

Cadmium (Cd) is a major pollutant in farmland, which not only greatly restricts crop production, but also brings a serious threat to human health through entering the food chain. Our previous study showed that hemin treatment could reduce the accumulation of Cd in pak choi seedlings. However, the underlying mechanism remains unclear.

Modular Design of Chiral Conjugate-Base-Stabilized Carboxylic Acids: Catalytic Enantioselective [4 + 2] Cycloadditions of Acetals.

Readily available 1,2-amino alcohols provide the framework for a new generation of chiral carboxylic acid catalysts that rival the acidity of the widely used chiral phosphoric acid catalyst ()-TRIP. Covalently linked thiourea sites stabilize the carboxylate conjugate bases of these catalysts via anion-binding, an interaction that is largely responsible for the low p values. The utility of the new catalysts is illustrated in the context of challenging [4 + 2] cycloadditions of salicylaldehyde-derived acetals with homoallylic and bishomoallylic alcohols, providing polycyclic chromanes in a highly enantioselective fashion.

Least-squares ray mapping method for freeform illumination optics design.

Computing a source-target map that yields integrable surface normal field is quite challenging for freeform illumination design. Here, we propose a least-squares ray mapping method to calculate a superior ray mapping by iteratively correcting an integrable map to approach the energy conservation and boundary condition. The process is implemented via solving three minimization problems.

Globally optimal first-order design of zoom systems with fixed foci as well as high zoom ratio.

In this paper, we propose a systematic approach to automatically retrieve the first-order designs of three-component zoom systems with fixed spacing between focal points based on Particle Swarm Optimization (PSO) algorithm. In this method, equations are derived for the first-order design of a three-component zoom lens system in the framework of geometrical optics to decide its basic optical parameters. To realize the design, we construct the mathematical model of the special zoom system with two fixed foci based on Gaussian reduction.

Highly Acidic Conjugate-Base-Stabilized Carboxylic Acids Catalyze Enantioselective oxa-Pictet-Spengler Reactions with Ketals.

Acyclic ketone-derived oxocarbenium ions are involved as intermediates in numerous reactions that provide valuable products, however, they have thus far eluded efforts aimed at asymmetric catalysis. We report that a readily accessible chiral carboxylic acid catalyst exerts control over asymmetric cyclizations of acyclic ketone-derived trisubstituted oxocarbenium ions, thereby providing access to highly enantioenriched dihydropyran products containing a tetrasubstituted stereogenic center. The high acidity of the carboxylic acid catalyst, which exceeds that of the well-known chiral phosphoric acid catalyst TRIP, is largely derived from stabilization of the carboxylate conjugate base through intramolecular anion-binding to a thiourea site.

Double freeform surfaces design for beam shaping with non-planar wavefront using an integrable ray mapping method.

We propose a method to design double smooth freeform surfaces applied in beam shaping with a ray mapping method in the paper. We couple the calculation of ray mapping and the construction of freeform surfaces to approach the surface normal field integrability condition based on the symplectic flow mapping scheme. In this paper, the incident beam wavefront is not limited to be planar or spherical.

Automatically retrieving an initial design of a double-sided telecentric zoom lens based on a particle swarm optimization.

In this paper, we propose an efficient and robust approach to retrieve an optimal first-order design of a double-sided telecentric zoom lens based on the particle swarm optimization (PSO) algorithm. In this method, the design problem is transformed to realize a zoom system with fixed positions of both the front focal point and the rear focal point during zooming. Equations are derived for the paraxial design of the basic parameters of a three-component zoom lens in the framework of geometrical optics.

Hydrogen gas alleviates toxic effects of cadmium in Brassica campestris seedlings through up-regulation of the antioxidant capacities: Possible involvement of nitric oxide.

Hydrogen gas (H) has been shown as an important factor in plant tolerance to abiotic stresses, but the underlying mechanisms remain unclear. In the present study, the effects of H and its interaction with nitric oxide (NO) on alleviating cadmium (Cd) stress in Brassica campestris seedlings were investigated. NO donor (SNP) or hydrogen-rich water (HRW) treatment showed a significant improvement in growth of Cd-stressed seedlings.

Increased antioxidative capacity and decreased cadmium uptake contribute to hemin-induced alleviation of cadmium toxicity in Chinese cabbage seedlings.

Hemin (ferroprotoporphyrin IX), a compound derivative of heme, has been shown to exert numerous beneficial physiological functions in the resistance of plant to various abiotic stresses. This work investigated the effects of hemin on ameliorating Cd toxicity in Chinese cabbage (Brassica chinensis L.).

Lower cadmium accumulation and higher antioxidative capacity in edible parts of Brassica campestris L. seedlings applied with glutathione under cadmium toxicity.

Glutathione (GSH) is involved in not only plant developmental processes but also plant responses to abiotic stresses. A hydroponic experiment was performed to explore the protective roles of exogenous GSH in mitigating cadmium (Cd) stress in Brassica campestris L. seedlings by analyzing the morphological and physiological parameters.

Design of a head-up display based on freeform reflective systems for automotive applications.

Automotive head-up display (HUD), a typical application in augmented reality (AR), has gained popularity in recent years. In this paper, we propose a novel design configuration of freeform off-axis three-mirror systems for automotive head-up display (HUD) application. In the configuration, the image source, the flat mirror, and the freeform mirror are allocated on the same horizontal level to guarantee a compact structure as well as to make the optical elements easy to be assembled.

Chiral bisoxazoline ligands designed to stabilize bimetallic complexes.

Chiral bisoxazoline ligands containing naphthyridine, pyridazine, pyrazole, and phenol bridging units were prepared and shown to form bimetallic complexes with various metal salts. X-ray crystal structures of bis-nickel naphthyridine-bridged, bis-zinc pyridazine-bridged, and bis-nickel as well as bis-palladium pyrazole-bridged complexes were obtained.

Catadioptric freeform optical system design for LED off-axis road illumination applications.

The aim of this paper is to develop a new composite structure of catadioptric optical system containing both freeform refractive surface and freeform total internal reflective (TIR) surface for LED road illumination applications. The role of freeform refractive part is to generate the shifted general rectangular illumination pattern to optimally match the shape of the road surface. The application of TIR mechanism is aimed to control the stray light in the sidewalk direction of the road luminaire and maximize the efficient energy efficiency.

Synthesis of Polycyclic Imidazolidinones via Amine Redox-Annulation.

α-Ketoamides undergo redox-annulations with cyclic secondary amines, such as 1,2,3,4-tetrahydroisoquinoline, pyrrolidine, piperidine, and morpholine. Catalytic amounts of benzoic acid significantly accelerate these transformations. This approach provides polycyclic imidazolidinone derivatives in typically good yields.