Publications by authors named "Zhaoqi Zhu"

Heat waves (HW) are projected to become more frequent and intense with climate change, potentially enhancing the invasiveness of certain plant species. This study aims to compare the physiological and photosynthetic responses of the invasive and its native congener under simulated heat wave conditions (40.1 °C, derived from local historical data).

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Global climate change and invasive plants significantly impact biodiversity and ecosystem functions. This study focuses on the effects of progressive warming on microbial communities within the invasion community, simulated through six stages of invasion progression, from minimal to dominant presence alongside native , in bulk soils collected from a natural habitat and cultivated under controlled greenhouse conditions. Utilizing high-throughput sequencing and microbial community analysis on 72 samples collected from the invasion community, the shifts in soil microbiota under varying warming scenarios were investigated (+0 °C, +1.

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Purpose: Inflammatory processes have been involved in diabetic retinopathy (DR). Interleukin (IL)-17A, a pro-inflammatory cytokine, is associated with DR occurrence and development. However, mechanisms underlying the IL-17A impact on DR need further investigations.

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Background: Autism spectrum disorder (ASD) often presents with atypical visual processing, prompting investigation into its connection with retinal features. This study aimed to (I) compare intraretinal layer thickness in the peripapillary region between ASD and neurotypical (NT) groups, (II) assess associations between intraretinal layer thickness and clinical parameters (social functioning and cognitive levels) in ASD subjects, and (III) evaluate the potential of intraretinal layer thickness as a biomarker for ASD.

Methods: Participants were recruited through convenience sampling from the Children's Mental Health Research Center at The Affiliated Brain Hospital of Nanjing Medical University and the Department of Ophthalmology at The First Affiliated Hospital of Nanjing Medical University, Nanjing, China, between December 2019 and August 2023.

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This study investigates how variations in diurnal temperature and phosphorus concentration affect the growth of native Artemisia argyi and invasive Solidago canadensis under intraspecific and interspecific competition. We conducted factorial experiments to assess the impacts of warming, including an increased diurnal temperature range (DTRinc), a symmetric increase in diurnal temperature range (DTRsys), a decreased diurnal temperature range (DTRdec) and phosphorus application (5 g and 10 g P m yr) on both intra- and inter-specific competition among plants. The results indicated that (1) the DTRsys for A.

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In recent years, there has been a growing interest in liquid biopsy due to its non-invasive diagnostic value. Postoperative drainage fluid (PDF) is the fluid exudate from the wound site following lymph node dissection. PDF is regarded as a medical waste with no specific clinical significance.

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Lymph node metastasis (LNM) is a typical marker in oral squamous cell carcinoma (OSCC) indicating poor prognosis. Pathological examination by artificial image acquisition and analysis, as the main diagnostic method for LNM, often takes a week or longer which may cause great anxiety of the patient and also retard timely treatment. However, there are few efficient fast LNM diagnosis methods in clinical applications currently.

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Article Synopsis
  • * In this study, scientists used special eye scanning technology to compare the retinas of children with ASD to those without, focusing on a specific area of the eye called the macula.
  • * They found that children with ASD had thicker parts of the retina and different blood vessel sizes, especially in one eye, which could help understand ASD better in the future.
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Aerogels have been widely studied in the field of thermal insulation. Herein, we reported a kind of conjugated micropolymer (CMP) aerogel synthesized by 1,3,5-triethynylbenzene and 2-amino-3,5-dibromopyridine. To enhance the flame-retardant property, we composited hydroxyapatite (HAP) nanowires with a CMP aerogel.

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Porous iron-nitrogen-doped carbons (FeNC) offer a great platform for construction of cathodic oxygen reduction reaction (ORR) catalysts in fuel cells. However, challenges still remain regarding with the collapse of carbon-skeleton during pyrolysis, uneven distribution of active sites and aggregation of metal atoms. In this work, we synthesized Fe, N co-doped conjugated microporous polymer (FeN-CMP) through a facile bottom-up strategy using 1,3,5-triethynylbenzene and iron-chelated 3,8-dibromo-1,10-phenanthroline as monomers, ensuring the uniform coordination of N with Fe element in network.

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The development of polymer materials with excellent flame retardancy has been paid increasing attention for their valuable applications in saving energy in modern architecture. Herein, conjugated microporous polymers hollow nanospheres (CMPs-HNS) were prepared by Sonogashira-Hagihara cross-coupling reaction with 1,3,5-triacetylenebenzene, 3-amino-2,6-dibromopyridine, and 2,4,6-tribromoaniline as building blocks using SiO nanoparticles as hard templates. To enhance the flame-retardant performance of the CMPs-HNS, antimony pentoxide solution (SbO) and bisphenol A-bis (diphenyl phosphate) (BDP) were coated onto the as-prepared CMP-HNS (CMPs-HNS-BSb) by a simple immersion method.

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Article Synopsis
  • The review explores the importance of solar photothermal conversion and storage (SPCS) technology in addressing the uneven availability of solar energy.
  • It evaluates various phase change materials and composite designs, comparing their effectiveness in aspects like energy density, thermal conductivity, and stability.
  • The paper also identifies existing challenges and future directions for SPCS technology to optimize solar energy utilization across multiple industries.
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  • The legacy effects of invasive plant species can obstruct the recovery of native ecosystems, particularly under conditions of nitrogen deposition, which favors the growth of invasives and can lead to further invasions.
  • The study hypothesizes that nitrogen deposition exacerbates these legacy effects, exploring mechanisms related to community structure, nitrogen metabolism, geochemical cycles, and microbial interactions.
  • Findings indicate that microorganisms, particularly nitrogen-fixing bacteria, play a crucial role in this process, influencing plant-soil feedback and offering insights for managing invasive species and enhancing ecosystem recovery.
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Water environmental pollution especially caused by bacteria, viruses and other microorganisms always would accelerate the spread of infectious diseases and has been one of the issues highly concerned by the World Health Organization for a long time. The development of novel antibacterial materials with high activity for water cleanness was of great importance for public health and ecological sustainable development. In this work, we developed two really free-standing conjugated microprous polymers (CMPs) film with large size and processibility by a simple and convenient solid surface-assisted polymerization between bromo- and aryl-acetylene monomers.

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Article Synopsis
  • * This composite evaporator can efficiently work in various weather conditions, achieving evaporation rates of 1.57 kg/m²/h and 2.79 kg/m²/h under different light intensities, with an impressive solar evaporation efficiency of over 91%.
  • * Notably, the evaporator can continue to function effectively even when solar illumination is inconsistent, thanks to the energy storage capabilities of the phase change material, suggesting a promising approach for continuous desalination efforts.
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The creation of high-performance thermal insulation and flame-retardant materials is of great importance for minimizing energy consumption and reducing fire risk for modern buildings. Herein, we report the creation of a new composite aerogel, which was prepared by incorporation of 9,10-Dihydro-9-oxa-10-phosphaphenanthrene 10-Oxide-3-Aminopropyl triethoxysilane (DOPO-KH550) modified hollow glass microspheres (HGM) into polyvinyl alcohol (PVA) using citric acid as a cross-linker, as a kind of thermal insulation and flame retardant materials (abbreviated as PVA-DKHGM). The as-synthesized PVA-DKHGM composite exhibits superior thermal conductivity of 0.

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Solar steam generation (SSG) emerges as a paramount technology for efficient and sustainable desalination and wastewater purification. The innovative development of porous aerogel materials for solar steam generation heralds a new era in photothermal materials. In this study, a category of β-cyclodextrin-grafted graphene oxide/sodium anionic polysaccharide alginate composite aerogels (named GO-CD/SA) with solar steam generation behavior and wastewater purification properties is developed.

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Solar-driven interfacial evaporation (SDIE) with excellent photothermal conversion efficiency is emerging as one of the frontier technologies for freshwater production. In this work, novel carbonized conjugate microporous polymers (CCMPs) hollow microspheres-based composite hydrogel membranes (CCMPsHM-CHM) for efficient SDIE are reported. The precursor, CMPs hollow microspheres (CMPsHM), is synthesized by an Sonogashira-Hagihara cross-coupling reaction using a hard template method.

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Solar steam generation is widely used in seawater desalination because of its high efficiency and environmental protection. However, using low-cost materials to produce efficient solar evaporators is a severe challenge. In this study, a porous carbon material was prepared by combining Attapulgite (ATP), Polyethylene glycol (PEG) and Manganese dioxide nanowires (MnONWs) composite, through freeze-drying and high-temperature carbonization.

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Air pollution has become a challenging environmental problem worldwide due to rapid industrial development and excessive emissions of vehicle exhaust. Herein, we report a preparation of conjugated microporous polymer membranes (CMPM) with a hierarchical porous structure by electrospun polyvinylpyrrolidone (PVP) nanofibers as a template for effective removal of PM from airborne and vehicle exhaust. CMP membranes have hierarchical holes, where the macropores are from electrospun nanofiber membranes and the mesopores are from polymer synthesis.

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Electrical impedance tomography (EIT) technology is an important imaging approach to show the conductivity distribution of the area noninvasively. Recently, 3D EIT has been extensively studied for its more comprehensive display of electrical properties. Nonetheless, most 3D EIT electrode models are based on multilayer ring electrodes and only suitable for specific scenarios.

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Phase change materials (PCMs) with ideal light-to-thermal conversion efficiency play an important role in solar energy storage and conversion. Hence, we report the fabrication of a novel composite PCMs (CPCMs) device based on ZnO nanorods deposited indium tin oxide (ITO) glass loading with fatty amines. ZnO nanorods were deposited on the ITO glass using a three-electrode electrodeposition method, and 1-Hexadecylamine (HDA) was loaded on the ITO glass via spin-coating, followed by spraying polypyrrole (ppy) on the surface of CPCM device to improve thermal conductivity and solar absorption.

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The cathodic oxygen reduction reaction (ORR) is important in the development of renewable energy devices, to produce novel and non-precious metal catalysts with high electrocatalytic activity to reduce the consumption of non-renewable platinum (Pt) catalyst. In this work, we developed N-doped and Fe/N dual-doped porous carbons as catalysts for ORR simply by high-temperature pyrolysis of porphyrin-based conjugated microporous polymers (CMPs). By combination of heteroatom doping, highly porous structure and tubular morphology, the as-prepared carbon samples exhibited high electrocatalytic activity with 4-electron transfer mechanism, nearly close to the commercial Pt/C catalyst.

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Highly efficient harvesting, transfer, and storage of solar energy are of great significance for the sustainability of society Herein, we report the design and synthesis of conjugated microporous polymers hollow spheres (CMPs-HS) coated by graphene (GCMPs-HS) and compounded with the phase change material (PCM) octadecanol (GCMPs@ODA) for efficient solar photothermal conversion. The as-synthesized CMPs-HS shows a high specific surface (519.95 m g and 309.

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The accumulation of non-degradable microplastics (MPs) originated from the mass production and huge consumption of plastics of modern industry in the water environment has resulted in severe pollution problems globally. Herein, we report for the first time the preparation of holey TiCTx (h-TiCTx) membranes obtained by etching CoO nanoparticles embedded on TiCTx nanosheets followed by simple vacuum filtration using polymeric membranes as supporting matrix for efficient removal of MPs from wastewater. The h-TiCTx nanosheets exhibit a planar porous structure which present nano-holes with an average hole-size of 25 nm in diameter, which facilitated the construction of membranes with better water flux for the separation of MPs.

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