Nitrate pollution in surface water and ground water has drawn wide attention, which has brought challenges to human health and natural ecology. Electroreduction of nitrate to NH in waste water was a way to turn waste into wealth, which has attracted interest of many researchers. Using Nickel foam as substrate, we prepared Pd/In bimetallic electrode (NF-Pd/In) according to a two-step electrodeposition method.
View Article and Find Full Text PDFHigh nitrate concentration in water can lead to eutrophication and the disruption of healthy aquatic ecosystems. Additionally, in the human digestive system, it has the potential to be reduced to nitrite, which can be damaging to people's physical health. Catalytic hydrogenation of nitrate is one of the strategies for removing nitrate from water.
View Article and Find Full Text PDFAn innovative Pd-Me (Pd-Cu, Pd-In and Pd-Sn) bimetallic catalyst supported on porous chelating DOWEX M4195 resin (D) was established to reduce the nitrate almost entirely and achieved high selectivity to the expected harmless form of nitrogen. In this study, sodium borohydride (NaBH) was applied in preparing bimetallic catalysts by liquid-phase reduction as the prestoring reductant. Pd-In/D and Pd-Sn/D groups performed well in Nselectivity (all above 97%).
View Article and Find Full Text PDFNitrate pollution in ground water and surface water has been becoming a worldwide problem that poses a great challenge to steady water ecosystem and human health. Electrochemical reduction is a promising way to remove nitrate from water because of advantages. We prepared Pd/Sn modified nickel foam (NF) electrode according to a two-step electrodeposition method.
View Article and Find Full Text PDFElectrochemical reduction is a promising technology to remove nitrate from water. The metallic composition and geometry of electrodes usually dominate the nitrate removal property. Based on nickel foam (NF), we prepared Cu/Pd bimetallic electrode using hydrogen bubbles dynamic template according to a two-step electrodeposition method (Pd after Cu).
View Article and Find Full Text PDFCatalytic hydrogen reduction has appeared as a promising strategy for chemical denitrification with advantages of high activity and simple operation. However, the risk and low utilization of H is the disadvantage of catalytic hydrogen reduction. In recent years, catalytic reduction reactions in the presence of sodium borohydride (NaBH) have been extensively studied.
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
October 2021
Catalytic hydrogen reduction appears to be a promising strategy for nitrate removal. However, the danger and low utilization of H are the disadvantages of catalytic hydrogen reduction. Sodium borohydride (NaBH), considered a potential candidate for hydrogen storage, has been investigated as an electron source for the catalytic reduction of contaminants.
View Article and Find Full Text PDFGiven the prevalence of nitrate and phosphate in surface and groundwater, it is important to develop technology for the simultaneous removal of nitrate and phosphate. In this study, we prepared the bimetallic nanoparticles of Fe coupled with copper or nickel supported on chelating resin DOW 3N (D-Fe/Ni and D-Fe/Cu) for removing nitrate and phosphate simultaneously. XPS profiles revealed that Cu has better ability than Ni to increase the stability of Fe nanoparticles and prevent nZVI from oxidation.
View Article and Find Full Text PDFWe studied a new strategy for pretreatment of rice straw (RS) to enhance enzymatic hydrolysis under mild condition. This approach uses the synergy of sodium carbonate (NaCO) and the bacterial strain Cupriavidus basilensis B-8 (hereafter B-8). After synergistic NaCO and B-8 pretreatment (SNBP), the reducing sugar yield varied from 335.
View Article and Find Full Text PDFThe mixture of 1-hydroxyethane-1,1-diphosphonic acid (HEDP), and polyacrylic acid (PAA) and synthesized hydrolyzed polymaleic anhydride (HPMA) was optimized by using simplex lattice of Design-Expert software through calcium carbonate precipitation method. The optimum mass ratio of HEDP, PAA and synthesized HPMA was obtained at 10/10/80, which showed excellent performance on controlling calcium carbonate deposition. The antiscale efficiency of the optimum mixture was 84% and 95%, respectively, in the calcium carbonate precipitation test and the calcium carbonate scale deposit test.
View Article and Find Full Text PDFSecondary-treated municipal wastewater (MWW) could supply a viable alternative water resource for cooling water systems. Inorganic salts in the concentrated cooling water pose a great challenge to corrosion control chemicals. In this study, the inhibition effect of 1-hydroxy ethylidene-1,1-diphosphonic acid (HEDP), trimethylene phosphonic acid (ATMP) and 2-phosphonobutane-1,2,4-tricarboxylic acid (PBTCA) on corrosion of carbon steel in secondary-treated MWW was investigated by the means of potentiodynamic polarization and electrochemical impedance spectroscopy.
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