Assessing and Optimizing Large Language Models on Spondyloarthritis Multi-Choice Question Answering: Protocol for Enhancement and Assessment.

Background: Spondyloarthritis (SpA), a chronic inflammatory disorder, predominantly impacts the sacroiliac joints and spine, significantly escalating the risk of disability. SpA's complexity, as evidenced by its diverse clinical presentations and symptoms that often mimic other diseases, presents substantial challenges in its accurate diagnosis and differentiation. This complexity becomes even more pronounced in nonspecialist health care environments due to limited resources, resulting in delayed referrals, increased misdiagnosis rates, and exacerbated disability outcomes for patients with SpA.

Encapsulation and thermal properties of composite phase change materials based on cobalt/nitrogen double-doped ZIF-67 derived carbon.

To solve the problems of easy leakage and weak thermal conductivity of single-phase change material, in this experiment, cobalt/nitrogen-doped ZIF-67 derived carbon (CoN-ZIF-C) was constructed as the carrier material, and paraffin was used as the phase change core material to construct thermally enhanced shaped composite phase change materials (P@CoN-ZIF-C). The composite PCMs were characterized using scanning electron microscopy, isothermal nitrogen adsorption-desorption, X-ray diffraction, and Fourier infrared spectroscopy, and their performance was evaluated using transient planar heat source techniques, differential scanning calorimetry, and thermal cycling tests. The results indicated that the impurities of the acid-washed porous carbon material were reduced and the loading of the paraffin was 60%, and the prepared P@CoN-ZIF-C had an excellent thermal performance.

Research progress on MOFs and their derivatives as promising and efficient electrode materials for electrocatalytic hydrogen production from water.

Hydrogen energy is considered to be the most potential "ultimate energy source" due to its high combustion calorific value, cleanliness, and pollution-free characteristics. Furthermore, the production of hydrogen the electrolysis of water has the advantages of simplicity, high efficiency, environmentally safe, and high-purity hydrogen. However, it is also associated with issues such as high-power consumption for the reaction and limited large-scale application of noble metal catalysts.

Synergistic Catalytic Performance of Toluene Degradation Based on Non-Thermal Plasma and Mn/Ce-Based Bimetal-Organic Frameworks.

A series of Mn/Ce-based bimetal-organic frameworks, recorded as MCDx (x = 1, 2, 4, 6), were prepared by a solvothermal synthesis method to explore their effects and performance in the synergistic catalysis of toluene under the irradiation of non-thermal plasma. The catalytic properties of different manganese loadings in MCDx for degradation of toluene were investigated. The microphysical structures of the material were analyzed by powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR) and thermogravimetric analysis (TGA).

Two-year online measurements of volatile organic compounds (VOCs) at four sites in a Chinese city: Significant impact of petrochemical industry.

Volatile organic compounds (VOCs) management has been recently given a high priority in China to mitigate ozone (O) air pollution. However, there is a relatively poor understanding of VOCs due to their complexity and fewer observations. To better understand the pollution characteristics of VOCs and their impact on O pollution, two-year continuous measurements were conducted at four representative sites in Ji'nan, eastern China.

Biomethylation and Volatilization of Arsenic by Model Protozoan Tetrahymena pyriformis under Different Phosphate Regimes.

, a freshwater protozoan, is common in aquatic systems. Arsenic detoxification through biotransformation by is important but poorly understood. Arsenic metabolic pathways (including cellular accumulation, effluxion, biomethylation, and volatilization) of were investigated at various phosphate concentrations.

Macrokinetics of magnesium sulfite oxidation inhibited by ascorbic acid.

Magnesia flue gas desulfurization is a promising process for small to medium scale industrial coal-fired boilers in order to reduce sulfur dioxide emissions, in which oxidation control of magnesium sulfite is of great importance for the recycling of products. Effects of four inhibitors were compared by kinetic experiments indicating that ascorbic acid is the best additive, which retards the oxidation process of magnesium sulfite in trace presence. The macrokinetics of magnesium sulfite oxidation inhibited by ascorbic acid were studied.