Extracting cervical spine popping sound during neck movement and analyzing its frequency using wavelet transform.

With the excessive use of smartphones, cervical spine pain is becoming increasingly prevalent. A denoised cervical spine popping sound can aid in monitoring and estimating the state of the cervical spine. However, cervical spine popping sounds that are collected when a subject performs neck movements is contaminated by constant noise.

Sensitivity and Resistance Risk Assessment of f. sp. to Triadimefon in China.

Wheat stripe rust, caused by f. sp. (), is a destructive disease of wheat that seriously threatens production safety in wheat-producing areas worldwide.

Low-Operating-Temperature NO Sensor Based on a CeO/ZnO Heterojunction.

CeO/ZnO-heterojunction-nanorod-array-based chemiresistive sensors were studied for their low-operating-temperature and gas-detecting characteristics. Arrays of CeO/ZnO heterojunction nanorods were synthesized using anodic electrodeposition coating followed by hydrothermal treatment. The sensor based on this CeO/ZnO heterojunction demonstrated a much higher sensitivity to NO at a low operating temperature (120 °C) than the pure-ZnO-based sensor.

Structure engineering of alveoli-like ZSM-5 with encapsulated Pt nanoparticles for the enhanced benzene oxidation.

Inspired by the alveolar configuration, an alveoli-like ZSM-5 and the corresponding platinum encapsulated nanocomposite (Pt@PZ5) were fabricated a dual-template method and a controlled selective desilication-recrystallization strategy. The dimensions of the central cavity, interconnected zeolitic vesicles, and mesoporous shell could be tuned by adjusting the synthesis parameters, as verified by scanning electron microscopy, transmission electron microscopy, nitrogen physisorption investigations, X-ray photoelectron spectroscopy, and X-ray diffraction techniques. Thanks to these properties and merits, the alveoli-like Pt@PZ5 showed the highest catalytic performance with excellent stability, obtaining 100% benzene conversion at 180 °C.

Phase separation of RNA-binding protein promotes polymerase binding and transcription.

An RNA-involved phase-separation model has been proposed for transcription control. However, the molecular links that connect RNA to the transcription machinery remain missing. Here we find that RNA-binding proteins (RBPs) constitute half of the chromatin proteome in embryonic stem cells (ESCs), some being colocalized with RNA polymerase (Pol) II at promoters and enhancers.

Regio- and Diastereoselective [3+2] Annulation of Aliphatic Aldimines with Alkenes by Scandium-Catalyzed β-C(sp )-H Activation.

Here we report for the first time the regio- and diastereoselective [3+2] annulation of a wide range of aliphatic aldimines with alkenes via the activation of an unactivated β-C(sp )-H bond by half-sandwich scandium catalysts. This protocol offers a straightforward and atom-efficient route for the synthesis of a new family of multi-substituted aminocyclopentane derivatives from easily accessible aliphatic aldimines and alkenes. The annulation of aldimines with styrenes exclusively afforded the 5-aryl-trans-substituted 1-aminocyclopentane derivatives with excellent diastereoselectivity through the 2,1-insertion of a styrene unit.

A novel pyroptosis-related gene signature to predict outcomes in laryngeal squamous cell carcinoma.

Pyroptosis, a pro-inflammatory form of programmed cell death, is associated with carcinogenesis and progression. However, there is little information concerning pyroptosis-related genes (PRGs) in laryngeal squamous cell carcinoma (LSCC). Herein, we aim to explore the prognostic value of PRGs in LSCC.

Removing EOG Artifacts from the EEG signal of Methamphetamine Addicts.

EEG can be used to characterize the electrical activity of the cerebral cortex, but it is also susceptible to interference. Compared with the other artifacts, Electrooculogram (EOG) artifacts have a greater impact on EEG processing and are more difficult to remove. Here, we mainly compared the regression and ICA algorithms both based on the EOG channels for the effect of removing EOG artifacts in the Stroop experiment of methamphetamine addicts.

Aerobic biocathodes with potential regulation for ammonia oxidation with concomitant cathodic oxygen reduction and their microbial communities.

Aerobic biocathodes are effective construct for the simultaneous nitrification and denitrification, but the disturbance of cathodic oxygen reduction on ammonia oxidation and denitrification remains unclear. In this study, we revealed the oxygen reduction peak at -0.4 V (versus silver/silver chloride) by cyclic voltammetry analysis at a cathode without a biofilm.

Role of Sexual Reproduction in the Evolution of the Wheat Stripe Rust Fungus Races in China.

Experimental and population genetic approaches have reshaped our view of how fungal pathogens reproduce, with consequences for our understanding of fungal invasions. f. sp.

Construction of an m6A-related lncRNA pair prognostic signature and prediction of the immune landscape in head and neck squamous cell carcinoma.

Background: Mounting evidence indicates that aberrantly expressed N6-methylandenosine (m6A) modification regulators and long noncoding RNA (lncRNA) influence the development of head and neck squamous cell carcinoma (HNSCC). However, the prognosis of m6A-related lncRNA (mrlncRNA) in HNSCC has not yet been evaluated.

Methods: We retrieved transcriptome, somatic mutation, and clinical information from The Cancer Genome Atlas database and established a differently expressed mrlncRNA (DEmrlncRNA) pair signature based on least absolute shrinkage and selection operator Cox regression and multivariate Cox analyses.

Highly Efficient Heteroleptic Cerium(III) Complexes with a Substituted Pyrazole Ancillary Ligand and Their Application in Blue Organic Light-Emitting Diodes.

Compared with red and green organic light-emitting diodes (OLEDs), blue is the bottleneck that restricts the wide development of OLEDs from being the next-generation technology for displays and lighting. As a new type of emitter, a Ce(III) complex shows many satisfactory advantages, such as a short excited-state lifetime, 100% theoretical exciton utilization efficiency, and tunable emission color. Herein we synthesized three heteroleptic Ce(III) complexes Ce(Tp)(dtfpz), Ce(Tp)(dmpz), and Ce(Tp)(dppz) with the hydrotris(3,5-dimethylpyrazolyl)borate (Tp) main ligand and different substituted pyrazole ancillary ligands, namely, 3,5-di(trifluomethyl)pyrazolyl (dtfpz), 3,5-dimethylpyrazolyl (dmpz), and 3,5-diphenylpyrazolyl (dppz), and studied their structures and luminescence properties.

Formal (3 + 1 + 1) Carboannulation of Morita-Baylis-Hillman Carbonates with Pyridinium Ylides: Access to Spiro-Cyclopentadiene Oxindoles.

An efficient formal (3 + 1 + 1) carboannulation strategy of Morita-Baylis-Hillman (MBH) carbonates with pyridinium ylides was developed for constructing diversely functionalized spiro-cyclopentadiene oxindoles. The reaction initiates with an S2' olefination of MBH carbonates with pyridinium ylides. The generated dienes then engage in a challenging (4 + 1) ylide carboannulation, which has been rarely reported before.

Solvent-Free Solid-State Lithium Battery Based on LiFePO and MWCNT/PEO/PVDF-HFP for High-Temperature Applications.

Rechargeable lithium-ion batteries (LIBs) have a wide range of applications but face challenges in harsh working or operating environments at high temperatures. In this work, a solid polymer electrolyte with MWCNT-COOH as an additive (MWCNT-SPE) was obtained. MWCNT-SPE has a high thermal stability and can be used in high-temperature operating environments.

Enterochromaffin Cells: Sentinels to Gut Microbiota in Hyperalgesia?

In recent years, increasing studies have been conducted on the mechanism of gut microbiota in neuropsychiatric diseases and non-neuropsychiatric diseases. The academic community has also recognized the existence of the microbiota-gut-brain axis. Chronic pain has always been an urgent difficulty for human beings, which often causes anxiety, depression, and other mental symptoms, seriously affecting people's quality of life.

Transcription factor BZR2 activates chitinase Cht20.2 transcription to confer resistance to wheat stripe rust.

The brassinosteroid pathway promotes a variety of physiological processes in plants and the brassinosteroid insensitive1-ethylmethane sulfonate suppressor (BES)/brassinazole-resistant (BZR) functions as one of its key regulators. We previously showed that the BES/BZR-type transcription factor TaBZR2 mediates the drought stress response in wheat (Triticum aestivum) by directly upregulating the transcriptional activity of glutathione S-transferase 1. However, the function of TaBZR2 in plants under biotic stresses is unknown.

Construction of CF-Functionalized Fully Substituted Benzonitriles through Rauhut-Currier Reaction Initiated [3 + 3] Benzannulation.

Though numerous cyanation reactions have been developed for the synthesis of benzonitriles, the construction of valuable fully substituted benzonitriles is still a challenging task. Herein, we reported a tertiary amine-catalyzed [3 + 3]-benzannulation for the green synthesis of CF-functionalized fully substituted benzonitriles. This strategy features exclusive chemoselectivity, high atom-economy, and good step-economy with environment-friendly reagents and mild conditions.

Lanthanide Cerium(III) Tris(pyrazolyl)borate Complexes: Efficient Blue Emitters for Doublet Organic Light-Emitting Diodes.

Organic light-emitting diodes (OLEDs) have had commercial success in displays and lighting. Compared to red and green OLEDs, blue OLEDs are still the bottleneck because the high-energy and long-lived triplet exciton in traditional blue OLEDs causes the short operational lifetime of the device. As a new type emitter, lanthanide complexes with a 5d-4f transition could have short excited-state lifetimes on the order of nanoseconds.

Adjacent single-atom irons boosting molecular oxygen activation on MnO.

Efficient molecular oxygen activation is crucial for catalytic oxidation reaction, but highly depends on the construction of active sites. In this study, we demonstrate that dual adjacent Fe atoms anchored on MnO can assemble into a diatomic site, also called as MnO-hosted Fe dimer, which activates molecular oxygen to form an active intermediate species Fe(O = O)Fe for highly efficient CO oxidation. These adjacent single-atom Fe sites exhibit a stronger O activation performance than the conventional surface oxygen vacancy activation sites.

Evasion of Antiviral Innate Immunity by Porcine Reproductive and Respiratory Syndrome Virus.

Innate immunity is the front line for antiviral immune responses and bridges adaptive immunity against viral infections. However, various viruses have evolved many strategies to evade host innate immunity. A typical virus is the porcine reproductive and respiratory syndrome virus (PRRSV), one of the most globally devastating viruses threatening the swine industry worldwide.

Tin(II) Acetylacetonate as a New Type of Tin Compensator Additive for Tin-Based Perovskite Solar Cells.

Tin (Sn)-based perovskite is one of the most promising candidates for lead (Pb)-free perovskite light-absorbing materials applied in solar cells. However, the intrinsic Sn vacancy () defects seriously hinder the device performance, making the reported maximum power efficiency (PCE) of Sn-based perovskite solar cells (PSCs) far behind those of Pb-based ones. During the study, SnF has been demonstrated as an indispensable Sn compensator additive to improve the device performance.

[Study on endpoint determination method of tablet coating based on 3σ criteria and logic regression].

This paper explores the statistical distribution characteristics of coating film thickness, so as to present a new method for determining coating endpoint based on 3σ criterion and logic regression. Firstly, the spectrum and thickness of 4 batch samples were collected. Secondly, the spectral range of normal products was obtained by 3σ criterion, with the spectral feature NI as the number of test spectrum in the above range.

Vapor heat treatment against Planococcus lilacinus Cockerell (Hemiptera:Pseudococcidae) on dragon fruit.

Background: The coffee mealybug Planococcus lilacinus Cockerell, is an invasive pest that infests dragon fruit [Selenicereus undatus (Haworth) D.R. Hunt], that may require a phytosanitary treatment to meet quarantine requirements.

3D printing of recombinant Escherichia coli/Au nanocomposites as agitating paddles towards robust catalytic reduction of 4-nitrophenol.

Three-dimensional (3D) printing technology has received remarkable attention in manufacturing catalysts with tailored shapes and high precision, particularly facilitating catalyst recovery, maximizing heat/mass transfer, as well as enhancing catalytic performance. Herein, an engineered recombinant Escherichia coli strain (denoted as e-E. coli) with overexpressing metallothionein (a metal-binding protein) was explored to synthesize Au nanoparticles serving as both reducing and stabilizing agents.

De-dimerization of PTB is catalyzed by PDI and is involved in the regulation of p53 translation.

Polypyrimidine tract-binding protein (PTB) is an RNA binding protein existing both as dimer and monomer and shuttling between nucleus and cytoplasm. However, the regulation of PTB dimerization and the relationship between their functions and subcellular localization are unknown. Here we find that PTB presents as dimer and monomer in nucleus and cytoplasm respectively, and a disulfide bond involving Cysteine 23 is critical for the dimerization of PTB.