Commercial deployment of lithium anodes has been severely impeded by the poor battery safety, unsatisfying cycling lifespan, and efficiency. Recently, building artificial interfacial layers over a lithium anode was regarded as an effective strategy to stabilize the electrode. However, the fabrications reported so far have mostly been conducted directly upon lithium foil, often requiring stringent reaction conditions with indispensable inert environment protection and highly specialized reagents due to the high reactivity of metallic lithium.
View Article and Find Full Text PDFPorcine reproductive and respiratory syndrome (PRRS) is one of the most common diseases in the global swine industry. PRRSV infection is highly restricted to cells of the monocyte-macrophage lineage. However, the lack of antibodies to swine monocyte-macrophage lineage markers significantly hampers PRRSV research.
View Article and Find Full Text PDFTwo-dimensional (2D) materials exhibit high sensitivity to structural defects due to the nature of interface-type materials, and the corresponding structural defects can effectively modulate their inherent properties in turn, giving them a wide application range in high-performance and functional devices. 2D γ-GaS is a defective semiconductor with outstanding optoelectronic properties. However, its controllable preparation has not been implemented yet, which hinders exploring its potential applications.
View Article and Find Full Text PDFTo understand the future trajectory of health expenditure in China if current trends continue and the estimated impact of reforms, this study projected health expenditure by disease and function from 2015 to 2035. Current health expenditure in China is projected to grow 8.4 percent annually, on average, in that period.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2019
Enhancing the light extraction efficiency is a prevalent but vital challenge for most solid-state lighting technologies, especially for deep ultraviolet light-emitting diodes (DUV-LEDs). In this paper, inspired by the microstructure of the butterfly's eye, we propose and fabricate a flexible fluoropolymer film (FFP film) to tackle this issue for all-mode, full-wavelength light extraction enhancement for most solid-state lighting technologies compatibly. The experimental results demonstrate that compared with one mounted with a smooth FFP film, the light output power of DUV-LED is enhanced up to 26.
View Article and Find Full Text PDFThe polarization and threshold of distributed feedback (DFB) polymer lasers were controlled by adjusting the cavity coupling. The cavity of DFB polymer lasers consisted of two gratings, which was fabricated by a two-beam multi-exposure holographic technique. The coupling strength of the cavity modes was tuned by changing the angle between the two gratings.
View Article and Find Full Text PDFPotassium-ion batteries (PIBs) are one of the emerging energy-storage technologies due to the low cost of potassium and theoretically high energy density. However, the development of PIBs is hindered by the poor K transport kinetics and the structural instability of the cathode materials during K intercalation/deintercalation. In this work, birnessite nanosheet arrays with high K content (K MnO ⋅0.
View Article and Find Full Text PDFAnisotropic aerogel-foam composites were developed by embedding a reduced graphene oxide (rGO)/chitosan aerogel directly into an open-cell polyurethane foam through an in situ bidirectional freeze-drying process. The resulting aerogel-foam composites possess both excellent compression-resilience performance and stable piezo-resistive properties due, respectively, to the excellent mechanical properties of polyurethane foams and to the presence of a chitosan-based aerogel loaded with rGO. The latter, indeed, provides outstanding electrical properties due to its conductive and parallel flat lamellar structure.
View Article and Find Full Text PDFSelf-powered devices are widely used in the detection and sensing fields. Asymmetric metal contacts provide an effective way to obtain self-powered devices. Finding two stable metallic electrode materials with large work function differences is the key to obtain highly efficient asymmetric metal contacts structures.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
June 2019
A new nonlinear optical (NLO) oxysulfide, Sr Cd Sb O S , which contains the functional groups [SbO S ] (x=0, 1) with a 5s electron configuration, is synthesized by a solid-state reaction. This compound displays a phase-matchable second harmonic generation (SHG) response four times stronger than AgGaS (AGS) under laser irradiation at 2.09 μm.
View Article and Find Full Text PDFFront Endocrinol (Lausanne)
March 2019
To explore serum zinc-α2-glycoprotein (ZAG) changes in patients with or without premature coronary artery disease (PCAD) and its association with several cardiovascular risk factors. A total of 3,364 patients who were undergone coronary angiography in Peking Union Medical College Hospital were screened. According to the degree of coronary artery stenosis, the number of 364 patients with PCAD (age <55 years in males and <65 years in females) and 126 age and gender matched patients without premature coronary artery disease (NPCAD) were recruited in our present study.
View Article and Find Full Text PDFCompared with their 3D counterparts, layered 2D Ruddlesden-Popper perovskites (2D RPPs) with the formula of (A')A Pb X exhibit improved photo and moisture stability. To develop flexible single-crystalline electronics and wearable devices, cost-effective growth of large-area single crystals of 2D RPPs with large lateral size, ultrathin thickness, parallel orientation, and well-defined and controlled n values are highly desirable, but it remains still a challenge. Here, we modified the space-confined aqueous solution growth method to fabricate single-crystalline films of (BA)(MA) Pb X and n = 1, 2, 3, respectively, with the lateral size reaching millimeter and thickness about 400-1000 nm.
View Article and Find Full Text PDFThe graphene nanosheets (GNS)/polydimethylsiloxane (PDMS) composite films with out-of-plane dielectric actuation behavior were prepared through a layer-by-layer spin coating process. The GNS-PDMS/PDMS composite films with 1~3 layers of GNS-PDMS films were spin coated on top of the PDMS film. The dielectric, mechanical, and electromechanical actuation properties of the composite films were investigated.
View Article and Find Full Text PDFSimultaneous distributed feedback (DFB) lasing and linear polarized random lasing are observed in a compound cavity, which consists of a grating cavity and a random cavity. The grating cavity is fabricated by interference lithography. A light-emitting polymer doped with silver nanoparticles is spin-coated on the grating, forming a random cavity.
View Article and Find Full Text PDFLactide-Caprolactone copolymer (LACL) was added to a Polylactide/Poly(ε-caprolactone) (PLA/PCL) blend as a compatibilizer through solution mixing and the casting method. The melt crystallization behavior and crystalline morphology of PLA, PLA/PCL, and PLA/PCL/LACL were investigated using differential scanning calorimeter (DSC) and polarized optical microscopy (POM), respectively. The temperature of the shortest crystallization time for the samples was observed at 105 °C.
View Article and Find Full Text PDFA random laser was achieved in a polymer membrane with silver nanoflowers on a flexible substrate. The strong confinement of the polymer waveguide and the localized field enhancement of silver nanoflowers were essential for the low-threshold random lasing action. The lasing wavelength can be tuned by bending the flexible substrate.
View Article and Find Full Text PDFThe effect of cavity structures on the tuning properties of polymer lasers was investigated in two common distributed-feedback cavities. The configurations of the two cavities are substrate/grating/active waveguide and substrate/active waveguide/grating, respectively. The polymer lasers were operated in the liquid environment, and the laser wavelength was tuned dynamically by changing the refractive index of the liquid.
View Article and Find Full Text PDFPolymers (Basel)
February 2019
In this study, high-order distributed-feedback (DFB) polymer lasers were comparatively investigated. Their performance relies on multiple lasing directions and their advantages include their high manufacturing tolerances due to the large grating periods. Nine laser cavities were fabricated by spin-coating the gain polymer films onto a grating structure, which was manufactured via interference lithography that operated at the 2, 3, and 4 DFB orders.
View Article and Find Full Text PDFAs a superstar organic semiconductor, fullerene (C ) is versatile in nature for its multiple photoelectric applications. However, owing to its natural 0D structure, a challenge still remains unbeaten as to growth of 1D fullerene crystals with tunable sizes. Herein, reported is an efficient approach to grow C as super-long crystalline fibers with tunable lengths and diameters in supramolecular gel by synergic changes of anti-solvent, gel length, crystallization time or fullerene concentration.
View Article and Find Full Text PDFThe monotonic work function of graphene makes it difficult to meet the electrode requirements of every device with different band structures. Two-dimensional (2D) transition metal carbides (TMCs), such as carbides in MXene, are considered good candidates for electrodes as a complement to graphene. Carbides in MXene have been used to make electrodes for use in devices such as lithium batteries.
View Article and Find Full Text PDFBackground: The clinical use of tirofiban remains controversial for patients with acute ischemic stroke (AIS), we aimed to conduct a meta- analysis of cohort studies to assess the efficacy and safety of tirofiban for AIS patients.
Methods: All apparently unconfounded randomized controlled trials (RCTs) and case-controlled studies, with or without blinding, of tirofiban in individuals with AIS will be included in this review. We will conduct a literature search in 2 databases Pubmed and Embase, using indexing terms related to cerebral infarctions and tirofiban to include articles indexed as of Jan 31, 2019 in the English language only.
ACS Appl Mater Interfaces
March 2019
The dendritic lithium formation and sustained lithium consumption caused by the uncontrollable side reactions between lithium and electrolytes seriously restrict the applications of lithium anodes in high-energy density batteries, especially in carbonate electrolytes. Ameliorating the surface status of lithium anodes is critical for modulating lithium deposition behavior and improving the cycling stability of lithium metal batteries. Herein, magnesium chloride salt is first reported as a carbonate electrolyte additive for lithium surface modification by in situ reaction.
View Article and Find Full Text PDFGene therapy has immense potential as a therapeutic approach to serious diseases. However, efficient delivery and real-time tracking of gene therapeutic agents have not been solved well for successful gene-based therapeutics. Herein we present a versatile gene-delivery strategy for efficient and visualized delivery of therapeutic genes into the targeted nucleus.
View Article and Find Full Text PDFLow-dimensional semiconductors have attracted considerable attention due to their unique structures and remarkable properties, which makes them promising materials for a wide range of applications related to electronics and optoelectronics. Herein, the preparation of 1D Sb Se nanowires (NWs) with high crystal quality via chemical vapor deposition growth is reported. The obtained Sb Se NWs have triangular prism morphology with aspect ratio range from 2 to 200, and three primary lattice orientations can be achieved on the sixfold symmetry mica substrate.
View Article and Find Full Text PDFGeneralized anxiety disorder (GAD) is characterized by excessive and uncontrollable worry about everyday life. Prior neuroimaging studies have demonstrated that GAD is associated with disruptions in specific brain regions; however, little is known about the global functional connectivity maps in adolescents with GAD. Here, first-episode, medication-naive, adolescent GAD patients ( = 36) and healthy controls ( = 28) (HCs) underwent resting-state functional MRI (R-fMRI) and completed a package of questionnaires to assess clinical symptoms.
View Article and Find Full Text PDF