For supporting active metal, the cavity confinement and mass transfer facilitation lie not in one sack, a trade-off between high activity and good stability of the catalyst is present. Porous organic cages (POCs) are expected to break the trade-off when metal particles are properly loaded. Herein, three organic cages (CC3, RCC3, and FT-RCC3) are employed to support Pd nanoclusters for catalytic hydrogenation.
View Article and Find Full Text PDFBackground: This study aimed to evaluate the clinical efficacy of the femoral neck system alone or in combination with a cannulated screw compared with other internal fixation methods for treating femoral neck fractures. We further investigated the predictive effects of tip-apex distance (TAD) on clinical efficacy.
Methods: Data from 129 young adults with femoral neck fractures followed up at The Second Affiliated Hospital of Fujian Medical University between January 2016 and June 2022 were retrospectively collected.
The development of efficient and economical electrocatalysts for oxygen evolution reaction (OER) is of paramount importance for the sustainable production of renewable fuels and energy storage systems; however, the sluggish OER kinetics involving multistep four proton-coupled electron transfer hampers progress in these systems. Fortunately, surface reconstruction offers promising potential to improve OER catalyst design. Anion modulation plays a crucial role in controlling the extent of surface reconstruction and positively persuading the reconstructed species' performances.
View Article and Find Full Text PDFThe excessive dependence on fossil fuels contributes to the majority of CO emissions, influencing on the climate change. One promising alternative to fossil fuels is green hydrogen, which can be produced through water electrolysis from renewable electricity. However, the variety and complexity of hydrogen evolution electrocatalysts currently studied increases the difficulty in the integration of catalytic theory, catalyst design and preparation, and characterization methods.
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