Aqueous Processed All-Polymer Solar Cells with High Open-Circuit Voltage Based on Low-Cost Thiophene-Quinoxaline Polymers.

Eco-friendly solution processing and the low-cost synthesis of photoactive materials are important requirements for the commercialization of organic solar cells (OSCs). Although varieties of aqueous-soluble acceptors have been developed, the availability of aqueous-processable polymer donors remains quite limited. In particular, the generally shallow highest occupied molecular orbital (HOMO) energy levels of existing polymer donors limit further increases in the power conversion efficiency (PCE).

Enhancing the Performance of Wide-Bandgap Polymer-Based Organic Solar Cells through Silver Nanorod Integration.

Light trapping induced by the introduction of metallic nanoparticles has been shown to improve photo absorption in organic solar cells (OSCs). Researchers in the fields of plasmonics and organic photovoltaics work together to boost sunlight absorption and photon-electron interactions in order to improve device performance. In this contribution, an inverted OSC was fabricated by using indacenodithieno[3,2-]thiophene--2,2'-bithiazole () as a wide-band gap donor copolymer and (6,6)-phenyl-C-butyric acid methyl ester (PCBM) as an acceptor.

On the Conformation of Dimeric Acceptors and Their Polymer Solar Cells with Efficiency over 18 .

The determination of molecular conformations of oligomeric acceptors (OAs) and their impact on molecular packing are crucial for understanding the photovoltaic performance of their resulting polymer solar cells (PSCs) but have not been well studied yet. Herein, we synthesized two dimeric acceptor materials, DIBP3F-Se and DIBP3F-S, which bridged two segments of Y6-derivatives by selenophene and thiophene, respectively. Theoretical simulation and experimental 1D and 2D NMR spectroscopic studies prove that both dimers exhibit O-shaped conformations other than S- or U-shaped counter-ones.

Embedding plasmonic gold nanoparticles in a ZnO layer enhanced the performance of inverted organic solar cells based on an indacenodithieno[3,2-]thiophene--5,5'-di(thiophen-2-yl)-2,2'-bithiazole-based push-pull polymer.

Recently, plasmonic nanoparticles (NPs) have attracted considerable attention as good candidates for enhancing the power conversion efficiency (PCE) of organic solar cells (OSCs) owing to their localized surface plasmon resonance (LSPR). In this study, the effect of embedding colloidal gold nanoparticles (cAu NPs) in the ZnO electron transport layer (ETL) on the PCEs of wide band gap polymer-based inverted OSCs was investigated. The active layer was composed of a bulk heterojunction of conjugated polymer based on indacenodithieno[3,2-]thiophene and 5,5'-di(thiophen-2-yl)-2,2'-bithiazole PIDTT-DTBTz as a donor and [6,6]-phenyl-C71-butyric acid methyl ester (PCBM) as an acceptor.

Effects of Flexible Conjugation-Break Spacers of Non-Conjugated Polymer Acceptors on Photovoltaic and Mechanical Properties of All-Polymer Solar Cells.

Highlights: A series of non-conjugated acceptor polymers with flexible conjugation-break spacers (FCBSs) of different lengths were synthesized. The effect of FCBSs length on solubility of the acceptor polymers, and their photovoltaic and mechanical properties in all-polymer solar cells were explored. This work provides useful guidelines for the design of semiconducting polymers by introducing FCBS with proper length, which can giantly improved properties that are not possible to be achieved by the state-of-the-art fully conjugated polymers.

A porphyrin pentamer as a bright emitter for NIR OLEDs.

The luminescence and electroluminescence of an ethyne-linked zinc(ii) porphyrin pentamer have been investigated, by testing blends in two different conjugated polymer matrices, at a range of concentrations. The best results were obtained for blends with the conjugated polymer PIDT-2TPD, at a porphyrin loading of 1 wt%. This host matrix was selected because the excellent overlap between its emission spectrum and the low-energy region of the absorption spectrum of the porphyrin oligomer leads to efficient energy transfer.

Polymer Acceptors with Flexible Spacers Afford Efficient and Mechanically Robust All-Polymer Solar Cells.

High efficiency and mechanical robustness are both crucial for the practical applications of all-polymer solar cells (all-PSCs) in stretchable and wearable electronics. In this regard, a series of new polymer acceptors (P s) is reported by incorporating a flexible conjugation-break spacer (FCBS) to achieve highly efficient and mechanically robust all-PSCs. Incorporation of FCBS affords the effective modulation of the crystallinity and pre-aggregation of the P s, and achieves the optimal blend morphology with polymer donor (P ), increasing both the photovoltaic and mechanical properties of all-PSCs.

Highly Stable Indacenodithieno[3,2-]thiophene-Based Donor-Acceptor Copolymers for Hybrid Electrochromic and Energy Storage Applications.

Stable doping of indacenodithieno[3,2-]thiophene (IDTT) structures enables easy color tuning and significant improvement in the charge storage capacity of electrochromic polymers, making use of their full potential as electrochromic supercapacitors and in other emerging hybrid applications. Here, the IDTT structure is copolymerized with four different donor-acceptor-donor (DAD) units, with subtle changes in their electron-donating and electron-withdrawing characters, so as to obtain four different donor-acceptor copolymers. The polymers attain important form factor requirements for electrochromic supercapacitors: desired switching between achromatic black and transparent states (*** 45.

Reduced Nonradiative Voltage Loss in Terpolymer Solar Cells.

The dissociation of hybrid local exciton and charge transfer excitons (LE-CT) in efficient bulk-heterojunction nonfullerene solar cells contributes to reduced nonradiative photovoltage loss, a mechanism that still remains unclear. Herein we studied the energetic and entropic contribution in the hybrid LE-CT exciton dissociation in devices based on a conjugated terpolymer. Compared with reference devices based on ternary blends, the terpolymer devices demonstrated a significant reduction in the nonradiative photovoltage loss, regardless of the acceptor molecule, be it fullerene or nonfullerene.

Recent Advances in n-Type Polymers for All-Polymer Solar Cells.

All-polymer solar cells (all-PSCs) based on n- and p-type polymers have emerged as promising alternatives to fullerene-based solar cells due to their unique advantages such as good chemical and electronic adjustability, and better thermal and photochemical stabilities. Rapid advances have been made in the development of n-type polymers consisting of various electron acceptor units for all-PSCs. So far, more than 200 n-type polymer acceptors have been reported.

Efficient Near-Infrared Electroluminescence at 840 nm with "Metal-Free" Small-Molecule:Polymer Blends.

Due to the so-called energy-gap law and aggregation quenching, the efficiency of organic light-emitting diodes (OLEDs) emitting above 800 nm is significantly lower than that of visible ones. Successful exploitation of triplet emission in phosphorescent materials containing heavy metals has been reported, with OLEDs achieving remarkable external quantum efficiencies (EQEs) up to 3.8% (peak wavelength > 800 nm).

High Performance All-Polymer Photodetector Comprising a Donor-Acceptor-Acceptor Structured Indacenodithiophene-Bithieno[3,4-]Pyrroletetrone Copolymer.

The synthesis of an acceptor polymer PIDT-2TPD, comprising indacenodithiophene (IDT) as the electron-rich unit and an interconnected bithieno[3,4-]pyrrole-4,4',6,6'-tetrone (2TPD) as the electron-deficient unit, and its application for all-polymer photodetectors is reported. The optical, electrochemical, charge transport, and device properties of a blend of poly(3-hexylthiophene) and PIDT-2TPD are studied. The blend shows strong complementary absorption and balanced electron and hole mobility, which are desired properties for a photoactive layer.