Hollow Carbon Nanospheres with Developed Porous Structure and Retained N Doping for Facilitated Electrochemical Energy Storage.

Development of highly porous carbons with abundant surface functionalities and well-defined nanostructure is of significance for many important electrochemical energy storage systems. However, porous carbons suffer from a compromise between porosity, doped functionality, and nanostructure that have thus far restricted their performances. Here, we report the design of highly porous, nitrogen-enriched hollow carbon nanospheres (PN-HCNs) by an interfacial copolymerization strategy followed by NH-assisted carbonization, and further demonstrate their significance and effectiveness in enhancing the electrochemical performances.