Enhanced Refractive Index Sensitivity through Combining a Sol-Gel Adsorbate with a TiO Nanoimprinted Metasurface for Gas Sensing.

We combine a gas-adsorbent microporous hybrid silica layer and a dense TiO Mie resonator array (metasurface), both obtained by sol-gel deposition and nanoimprint lithography, to form nanocomposite systems with high sensitivity for refractive index (RI) variations induced by gas adsorption. Using optical transduction based on direct specular reflection, we show spectral shifts of 4470 nm/RIU corresponding to 0.2 nm/ppm gas (air concentration) and reflection intensity changes of * = 17 (R/RIU) and 0.

Scalable Disordered Hyperuniform Architectures Nanoimprint Lithography of Metal Oxides.

Fabrication and scaling of disordered hyperuniform materials remain hampered by the difficulties in controlling the spontaneous phenomena leading to this novel kind of exotic arrangement of objects. Here, we demonstrate a hybrid top-down/bottom-up approach based on sol-gel dip-coating and nanoimprint lithography for the faithful reproduction of disordered hyperuniform metasurfaces in metal oxides. Nano- to microstructures made of silica and titania can be directly printed over several cm on glass and on silicon substrates.

Nanoconfined water vapour as a probe to evaluate plasmonic heating.

Engineering photothermal effects in plasmonic materials is of paramount importance for many applications, such as cancer therapy, chemical synthesis, cold catalysis and, more recently, metasurfaces. The evaluation of plasmonic heating at the nanoscale is challenging and generally requires sophisticated equipments and/or temperature-sensitive probes such as fluorescent molecules or materials. Here, we propose to use water vapor as a probe to evaluate the local heating around plasmonic nanoparticles.

Following in Situ the Degradation of Mesoporous Silica in Biorelevant Conditions: At Last, a Good Comprehension of the Structure Influence.

Mesoporous silica nanoparticles (MSNs) have seen a fast development as drug delivery carriers thanks to their tunable porosity and high loading capacity. The employ of MSNs in biomedical applications requires a good understanding of their degradation behavior both to control drug release and to assess possible toxicity issues on human health. In this work, we study mesoporous silica degradation in biologically relevant conditions through in situ ellipsometry on model mesoporous nanoparticle or continuous thin films, in buffer solution and in media containing proteins.

Femtosecond Direct Laser-Induced Assembly of Monolayer of Gold Nanostructures with Tunable Surface Plasmon Resonance and High Performance Localized Surface Plasmon Resonance and Surface Enhanced Raman Scattering Sensing.

We show femtosecond direct laser-induced assembly of gold nanostructures with plasmon resonance band variable as a function of laser irradiation in a wide range of visible wavelengths. A system of 2-photon lithography is used to achieve site-selectively controlled dewetting of a thin gold film into nanostructures in which size and shape are highly dependent on the laser power. Simultaneous measurements of localized surface plasmon resonance (LSPR) and surface enhanced Raman scattering (SERS) in the presence of various concentrations of trans-1,2-bis(4-pyridyl) ethylene (BPE) as target molecule are performed in order to highlight the relationship between structural dimensions, plasmonic effect, and detection activity.