Perfluoroalkyl and poly-fluoroalkyl substances (PFAS) release from textiles is a source of human exposure, but the mechanisms behind this release remain insufficiently studied. This research investigates the release and transport mechanisms of PFAS in outdoor jacket fabrics treated with a short side-chain fluorinated polymers (CF-SFPs) for durable water repellency (DWR). PA-based and PET-based fabrics were exposed to outdoor conditions and subjected to accelerated aging, followed by abrasion, washing, and drying experiments to simulate wear and degradation.
View Article and Find Full Text PDFIn this study, a fluorescent probe (GMP-Tb-SSA) utilizing lanthanide coordination polymer nanoparticles, GMP-Tb, as a sensing platform, and 5-sulfosalicylic acid (SSA) as a cofactor ligand was proposed for the detection of copper ions (Cu). GMP-Tb was synthesized by the self-assembly of guanine monophosphate (GMP) and terbium ion (Tb), and SSA was introduced as a sensitizer into the GMP-Tb network. Cu could efficiently inhibit the electron transfer from the ligand GMP to the central ion, Tb, leading to a significant quench of fluorescence of Tb.
View Article and Find Full Text PDFEcotoxicol Environ Saf
January 2024
In recent years, with the increasing global focus on environmental protection, the issue of microfiber release from denim during the washing process has gained attention. In this study, a programmable washing device simulating household drum washing was designed and developed, microfibers and indigo dyes released from denim washing were quantitatively detected, and we have also developed a novel method for estimating the release of microfibers during washing. The effects of washing time, washing temperature, and washing load on microfiber and indigo dye release from denim were explored.
View Article and Find Full Text PDFAs an effective ingredient of disinfectants, ClO inevitably remains in water, which induces potential health hazards such as lung damage and kidney disease. In this study, we synthesized stimulus-responsive dual-ligand luminol-Tb-GMP coordination polymer nanoparticles (luminol-Tb-GMP CPNPs) as highly selective fluorescent probes for the real-time and visual detection of ClO . CPNPs consist of Tb , a nuclear metal, that coordinates with GMP and luminol, an auxiliary ligand.
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