Products distribution during in situ and ex situ catalytic fast pyrolysis of Chinese herb residues.

Catalytic fast pyrolysis (CFP) for biomass treatment is a research hotspot but there is little information about the difference between the in situ and ex situ methods. In present work, the Ni-Fe/CaO-AlO catalysts with different Ni/Fe ratios have been synthesized by coprecipitation method, and the product distribution about the Chinese herb residue (CHR) catalytic fast pyrolysis by in situ and ex situ methods in a quartz tube reactor system has been investigated. The results show that the CFP pyrolysis would upgrade the quality of bio-oil but decrease the yields, no matter in situ or ex situ CFP process.

Pyrolysis gas from biomass and plastics over X-Mo@MgO (X = Ni, Fe, Co) catalysts into functional carbon nanocomposite: Gas reforming reaction and proper process mechanisms.

The metal catalysts X-Mo@MgO (X = Ni, Fe, Co) was studied as excellent catalyst for catalytic pyrolysis conversion of biomass and plastics into functional carbon nanocomposite. The proper reaction mechanism of the process was explored through the gas composition, and explored the bactericidal performance of functional carbon nanocomposite. The results showed that the Ni, Fe and Co-based catalysts elevated H gas yield reached to 57%, 34% and 44% as the addition of Mo, due to Mo or its oxide species for scission of small molecule compound.