Structure and Mechanical Properties of iPP-Based Nanocomposites Crystallized under High Pressure.

The unique nonparallel chain arrangement in the orthorhombic γ-form lamellae of isotactic polypropylene (iPP) results in the enhancement of the mechanical properties of γ-iPP. Our study aimed at the investigation of the mechanical properties of γ-iPP nanocomposites with 1-5 wt.% multiwall carbon nanotubes (MWCNT) and 5 wt.

Plastic Deformation of High Density Polyethylene with Extended-Chain Crystal Morphology.

Samples of polyethylene with extended-chain crystal morphology, obtained by crystallization under high pressure, were subjected to uniaxial compression to various strains. Accompanying structural changes were analyzed using scanning electron microscopy. At the true strain of e = 0.

Deformation of Poly-l-lactid acid (PLLA) under Uniaxial Tension and Plane-Strain Compression.

The ability of PLLA, either amorphous or semicrystalline, to plastic deformation to large strain was investigated in a wide temperature range (T = 70-140 °C). Active deformation mechanisms have been identified and compared for two different deformation modes-uniaxial drawing and plane-strain compression. The initially amorphous PLLA was capable of significant deformation in both tension and plane-strain compression.

Microbuckling Instability and the Second Yield during the Deformation of Semicrystalline Polyethylene.

Deformation instabilities, such as microbuckling or lamellar fragmentation due to slip localization, play a very important role in the deformation of semicrystalline polymers, although it still not well explored. Such instabilities often appear necessary to modify the deformation path and facilitate strain accommodation in an energy-minimizing manner. In this work, microbuckling instability was investigated using partially oriented, injection-molded (IM) samples of high-density polyethylene, deformed by a plane-strain compression.

Morphology and Plastic Yielding of Ultrahigh Molecular Weight Polyethylene.

The structure, morphology, and mechanical properties of two compression-molded grades of ultrahigh-molecular-weight polyethylene (UHMWPE) and, for comparison, one conventional linear polyethylene (HDPE) were studied. Compression molding resulted in some preferred orientation of lamellae in the compression direction in UHMWPE samples, while no preferred orientation in HDPE. The mean crystal thickness estimated from the size distribution agrees better with those obtained from small-angle X-ray scattering (SAXS) and mechanical yield data than the thickness determined from the melting peak temperature.

Deformation Instabilities and Lamellae Fragmentation during Deformation of Cross-linked Polyethylene.

The effect of the topology of the amorphous phase and phase interconnectivity on the stability of the deformation of semicrystalline polyethylene was investigated. The chain topology was modified by crosslinking the samples with electron beam irradiation. The samples were deformed by plane-strain compression, while the accompanying structural changes were monitored with X-ray and differential scanning calorimetry (DSC).

Synthesis and physicochemical characterization of chitin dihexanoate--A new biocompatible chitin derivative--In comparison to chitin dibutyrate.

Chitin dihexanoate (DHCH) is the novel biocompatible and technologically friendly highly substituted chitin diester. Here we described optimization of DHCH and chitin dibutyrate (dibutyryl chitin, DBC) synthesis conditions (temperature and reaction time) to obtain desired polymers with high reaction yield, high substitution degree (close to 2) and appropriately high molecular weights. A two-step procedure, employing acidic anhydrides (hexanoic or butyric anhydride) as the acylation agent and methanesulfonic acid both as the catalyst and the reaction medium, was applied.