Complex gas formation during combined mechanical and thermal treatments of spent lithium-ion-battery cells.

Spent lithium-ion batteries (LIB) contain volatile and reactive chemicals possibly generating toxic and/or flammable gases during the related recycling. In this study, two types of spent LIB cells were subjected to combined mechanical and thermal treatments at the constant temperatures of 20 °C, 120 °C, 200 °C, and 400 °C under a nitrogen atmosphere. A total of 46 gaseous species, including electrolyte components, oxygenated hydrocarbons, hydrocarbons, and others, were qualitatively and quantitatively analyzed by mass spectrometry.

Experimental and Numerical Investigation of Flow Field and Soot Particle Size Distribution of Methane-Containing Gas Mixtures in a Swirling Burner.

The formation of soot in a swirling flow is investigated experimentally and numerically in the context of biogas combustion using a CO-diluted methane/oxygen flame. Visualization of the swirling flow field and characterization of the burner geometry is obtained through PIV measurements. The soot particle size distributions under different fuel concentrations and swirling conditions are measured, revealing an overall reduction of soot concentration and smaller particle sizes with increasing swirling intensities and leaner flames.