Spectrochim Acta A Mol Biomol Spectrosc
August 2021
The paper presents a comprehensive study of the LiKNO- R (R = α-AlO, γ-AlO, SiO) and (LiNO - LiClO4) - γ- AlO composite salt systems by vibrational spectroscopy, X-ray diffractometry, and differential scanning calorimetry. According to the results of Raman spectra and XRD analysis, it has been found that in the case of a sufficiently small filler (15 nm-γ-AlO and SiO), an amorphous phase appears, both for systems based on LiKNO and for the nanocomposite based on (LiNO)-(LiClO). In the case of nanocomposites based on the LiKNO system, this additionally leads to the formation of the metastable KNO (R3m) phase.
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