Sulfobetaine ionic liquid crystals based on strong acids: phase behavior and electrochemistry.

A group of new zwitterion based ionic liquid crystals (ILCs) have been synthesized. Depending on the counter anion (mesylate or hydrogen sulfate) the phase behavior of the resulting ILCs is quite different. Mesylate based ILCs show complex phase behavior with multiple phases depending on the alkyl chain length.

Dual Nature of Large and Anisotropic Glass-Forming Molecules in Terms of Debye-Stokes-Einstein Relation Revealed.

The fundamental Debye-Stokes-Einstein (DSE) relation between rotational relaxation times and shear viscosity attracts longstanding research interest as one of the most important characteristics of many glass-forming liquids. Here, we provide strong evidence, missing so far, for the relevance of anisotropy for DSE-related behavior. Dielectric spectroscopy and shear viscosity measurements were employed to get insight into the decoupling between reorientation relaxation times and viscosity for anisotropic glass-formers with dipole moments oriented parallel or perpendicular to the long molecular axis.

3D Printable Polymer Electrolytes for Ionic Conduction based on Protic Ionic Liquids.

A range of protic ionic liquids (PILs) based on tri-n-alkylammonium cations and mesylate/triflate anions were incorporated into a polymer matrix to form ionogels (IGs). These systems were investigated for their thermal and electrochemical behaviour, as well as under the aspect of ion motion via PFG-NMR. The ionic conductivities of the ILs/IGs are in the range of 10-10 S/cm at elevated temperatures and the diffusion coefficients are around 10 m s.

Crystallization Kinetics of Phosphonium Ionic Liquids: Effect of Cation Alkyl Chain Length and Thermal History.

The effects of alkyl chain length on the crystallization kinetics and ion mobility of tetraalkylphosphonium, [P][TFSI], ( = 2, 6, 8, and 12) ionic liquids were studied by differential scanning calorimetry (DSC) and broadband dielectric spectroscopy (BDS) over a wide temperature range. The liquid-glass transition temperature () and ion dynamics examined over a broad range were almost insensitive to structural modifications of the phosphonium cation. In contrast, the crystallization kinetics were strongly affected by the length of the fourth alkyl chain.