Stretching tethered polymer chains: density functional approach.

We propose application of density functional theory to calculate the force acting on a selected segment of a tethered polymer chain that leads to stretching the chain. The density functional allows one to determine the effects due to the presence of other chains and solvent molecules. For high and moderate solvent densities the plot of the force versus the distance of the segment from the surface exhibits oscillatory behavior that has not been predicted by other approaches.

Monomer density profiles for polymer chains in confined geometries: massive field theory approach.

Taking into account the well known correspondence between the field theoretical ϕ(4) O(n)-vector model in the limit n → 0 and the behavior of long flexible polymer chains in a good solvent, the universal density-force relation is analyzed and the corresponding universal amplitude ratio B(real) is obtained using the massive field theory approach in fixed space dimensions d < 4. The monomer density profiles of ideal chains and real polymer chains with excluded volume interaction in a good solvent between two parallel repulsive walls, one repulsive and one inert wall, are obtained in the framework of the massive field theory approach up to one-loop order. Besides, the monomer density profiles for the dilute polymer solution confined in semi-infinite space containing mesoscopic spherical particle of big radius are calculated.

Polymer chains in confined geometries: massive field theory approach.

The massive field theory approach in fixed space dimensions d<4 is applied to investigate a dilute solution of long-flexible polymer chains in a good solvent between two parallel repulsive walls, two inert walls, and for the mixed case of one inert and one repulsive wall. The well-known correspondence between the field theoretical phi4 O(n) -vector model in the limit n-->0 and the behavior of long-flexible polymer chains in a good solvent is used to calculate the depletion interaction potential and the depletion force up to one-loop order. In order to make the theory UV finite in renormalization-group sense in 3 View Article and Find Full Text PDF

Critical adsorption of polymers in a medium with long-range correlated quenched disorder.

The process of adsorption on a planar wall of long flexible polymer chains in a medium with quenched long-range correlated disorder is investigated. We focus on the case of correlations between defects or impurities that decay according to the power law x(-a) for large distances x , where x= (r,z) . A field theoretical approach in d=4-epsilon and directly in d=3 dimensions up to one-loop order for the semi-infinite |phi|(4) m-vector model (in the limit m-->0 ) with a planar boundary is used.