Choline Halide-Based Deep Eutectic Solvents as Biocompatible Catalysts for the Alternating Copolymerization of Epoxides and Cyclic Anhydrides.

Aliphatic polyesters have received considerable attention in recent years due to their biodegradability and biocompatible, mechanical, and thermal properties that can make them a suitable alternative to today's commercialized polymers. The ring-opening copolymerization (ROCOP) of epoxides and cyclic anhydrides is a route to synthesize a diverse array of polyesters that could be useful in many applications. However, the catalysts used rarely consider biocompatible catalysts in the case that any are left in the polymer.

Controlled, one-pot synthesis of recyclable poly(1,3-diene)-polyester block copolymers, catalyzed by yttrium β-diketiminate complexes.

The one-pot synthesis of well-defined block copolymers of olefins/1,3-dienes and polar monomers, such as cyclic esters and acrylates has long been the focus of intense research. Cationic alkyl rare earth metal catalysts, activated by organoborates, have shown to be promising for the polymerization of isoprene or styrene and ε-caprolactone. In this study, we synthesize a series of yttrium bis(alkyl) complexes supported by simple β-diketiminate ancillary ligands.

Perfectly Alternating Copolymerization of Cyclic Anhydrides and Epoxides with Yttrium β-Diketiminate Complexes.

Monometallic yttrium β-diketiminate complexes are active and controlled catalysts for perfectly alternating ring-opening copolymerization of 1-butene oxide and phthalic anhydride under mild conditions. β-Diketiminate ligands with pendant neutral donors were targeted to identify both the impact of donor strength and number of donors on rates of polymerization and the presence of undesirable side reactions. Initiating groups were also varied between alkyls, chlorides, and alkoxides.

Catalytic methods for chemical recycling or upcycling of commercial polymers.

Polymers (plastics) have transformed our lives by providing access to inexpensive and versatile materials with a variety of useful properties. While polymers have improved our lives in many ways, their longevity has created some unintended consequences. The extreme stability and durability of most commercial polymers, combined with the lack of equivalent degradable alternatives and ineffective collection and recycling policies, have led to an accumulation of polymers in landfills and oceans.