Background: Laser-induced breakdown spectroscopy (LIBS) has long been regarded as the future superstar for chemical analysis. However, hindered by the fact that the signal source of LIBS is a spatially and temporally unstable plasma that interacts dramatically with ambient gases, LIBS has always suffered from poor signal quality, especially low signal repeatability. Although ambient gases act as one of the most direct and critical factors affecting LIBS signals, a clear understanding on how ambient gas properties impact LIBS signals is still lacking to act as guideline for the signal quality improvement.
View Article and Find Full Text PDFBackground: Variations in plasma properties among spectra and samples lead to significant signal uncertainty and matrix effects in laser-induced breakdown spectroscopy (LIBS). To address this issue, direct compensation for plasma property variations is considered highly desirable. However, reliably compensating for the total number density variation is challenging due to inaccurate spectroscopic parameters.
View Article and Find Full Text PDFMinimizing sample damage is crucial in laser-induced breakdown spectroscopy (LIBS) for applications involving valuable samples and elemental mapping. In this study, we introduced a low-power atmospheric pressure plasma jet (APPJ) to reduce sample damage by obtaining LIBS signals at significantly lower laser fluences. The proposed technique, APPJ-assisted LIBS (APPJ-LIBS), utilized an argon APPJ to provide seed electrons and enhance the excitation.
View Article and Find Full Text PDFHigh signal uncertainty has been regarded as a critical obstacle for the quantitative analysis of laser-induced breakdown spectroscopy (LIBS). One of the most effective ways for uncertainty reduction is to directly compensate for the variation of plasma properties, especially total number density. However, reliable compensation for the variation of total number density is hard to implement.
View Article and Find Full Text PDFLaser-induced breakdown spectroscopy (LIBS) is a promising multi-elemental analysis technique and has the advantages of rapidness and minimal sample preparation. In traditional LIBS measurement, sample spectra are generally collected based on a single set of fixed experimental parameters, such as laser energy and delay time. When samples have the same main components and similar component concentrations, the difference in their spectral intensities becomes less obvious.
View Article and Find Full Text PDFThe acoustic non-linearity parameter of Rayleigh waves can be used to detect various defects (such as dislocation and micro-cracks) on material surfaces of thick-plate structures; however, it is generally low and likely to be masked by noise. Moreover, conventional methods used with non-linear Rayleigh waves exhibit a low detection efficiency. To tackle these problems, a method of exciting reversed-phase Rayleigh waves in opposite directions is proposed to measure the acoustic non-linearity parameter of materials.
View Article and Find Full Text PDFAlthough it has been reported that arctigenin (ARG) can reduce the body weight and inhibit adipogenic differentiation by activating AMP-activated protein kinase (AMPK), the exact signals responsible for the ARG-mediated antiobesity mechanism through AMPK are not well understood. In this study, we investigated the potential improvement of AGR on lipid metabolism using a high-fat diet (HFD)-induced hyperlipidemia rats and 3T3-L1 mature adipocytes. The levels of AMPK and its downstream factors were examined by Western blot analysis and real-time fluorescent quantitative polymerase chain reaction.
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