Flexible Self-Powered Weak Light Detectors Based on ZnO/CsPbBr/γ-CuI Heterojunctions.

Halide perovskites (HPs) with marvelous optical and electrical properties are regarded as one of the competitive candidates for building next-generation photodetectors (PDs). However, combining their excellent properties with satisfactory long-term robustness is still challenging, ultimately limiting the practical applications of HP-based PDs. Herein, a high vacuum deposition system is employed to fabricate flexible self-powered PDs with a ZnO/CsPbBr/γ-CuI structure, which shows excellent stability and outstanding performance in weak light detection.

Quasi-two-dimensional α-molybdenum oxide thin film prepared by magnetron sputtering for neuromorphic computing.

Two-dimensional (2D) layered materials have attracted intensive attention in recent years due to their rich physical properties, and shown great promise due to their low power consumption and high integration density in integrated electronics. However, mostly limited to mechanical exfoliation, large scale preparation of the 2D materials for application is still challenging. Herein, quasi-2D α-molybdenum oxide (α-MoO) thin film with an area larger than 100 cm was fabricated by magnetron sputtering, which is compatible with modern semiconductor industry.

Separately enhanced dual emissions of the amphiphilic derivative of 2-(2'-hydroxylphenyl) benzothiazole by supramolecular complexation.

Here, we report separately enhanced dual emissions of the amphiphilic derivative of 2-(2'-hydroxyphenyl)benzothiazole (denoted as HBT-11) by supramolecular complexation with cyclodextrins (CDs). When dispersed in water, HBT-11 shows two relatively weak emission bands, which can be assigned to the emissions of enol- and keto-forms, the two tautomers, owing to excited-state intramolecular proton transfers. Upon the addition of α-CD and β-CD, the keto- and enol-emissions, respectively, are separately enhanced; the enhancement effect is due to the formation of HBT-11/α-CD and HBT-11/β-CD complexes through multiple hydrogen bonding and host-guest interactions, respectively.

Tuning the emission of a water-soluble 3-hydroxyflavone derivative by host-guest complexation.

3-Hydroxyflavone derivatives have great potential as fluorescent probes for bio-labeling in aqueous medium. They were extensively studied in various organic solvents for the "excited state intramolecular proton transfer" process, but seldom addressed in aqueous solution due to the poor water solubility. Herein, an amphiphilic molecule bearing 3-hydroxyflavone and oligo(ethylene oxide) (denoted as 3HF-EO) was designed and synthesized.

A near-infrared multifunctional fluorescent probe with an inherent tumor-targeting property for bioimaging.

A mitochondria-targeting probe, by conjugating a quaternary ammonium cation with glucosamine modified pH-activated cyanine, was designed and synthesized. This probe has excellent selectivity and sensitivity toward pH, stability, cellular membrane permeability and low cytotoxicity. Owing to the acidic feature of tumors and the more negative mitochondrial membrane potential of tumor cells than that of normal cells, this probe can selectively accumulate in tumor cells and light up its fluorescence.

[Study on cell senescence induced by D-galactose in cultured rat mesenchymal stem cells].

Objective: To study morphological and biological senescence changes induced by D-galactose in the cultured rat mesenchymal stem cells.

Methods: After 3rd generations cultured in the DMEM-F12, MSCs were changed into DMEM-F12 medium containing 8 g/L D-galactose and cultured to the 6th generations as the inducement group. The comparison were the 6th generations which was cultured in the DMEM-F12 medium all along, and then identified by surface wave.