Embedding fiber optic sensors (FOSs) within parts for strain measurement is attracting widespread interest due to its great potential in the field of structural health monitoring (SHM). This work proposes a novel method of embedding FOSs using capillaries within solid structures and investigates fiber positions and orientation uncertainties within capillaries of different sizes and their influences on strain measurement accuracies. To investigate how the fiber positions and orientation variations influence strain measurement accuracy, both analytical and numerical models are utilized to predict strain distributions along embedded fibers at different positions and with different orientations within the specimen.
View Article and Find Full Text PDFACS Appl Mater Interfaces
October 2023
Passive daytime radiative cooling (PDRC) relies on simultaneous reflection of sunlight and radiation toward cold outer space. Current designs of PDRC coatings have demonstrated potential as eco-friendly alternatives to traditional electrical air conditioning (AC). While many features of PDRC have been individually optimized in different studies, for practical impact, it is essential for a system to demonstrate excellence in all essential aspects, like the materials that nature has created.
View Article and Find Full Text PDFWe found that temperature-dependent infrared spectroscopy measurements (i.e., reflectance or transmittance) using a Fourier-transform spectrometer can have substantial errors, especially for elevated sample temperatures and collection using an objective lens.
View Article and Find Full Text PDFWe demonstrate spatial modification of the optical properties of thin-film metal oxides, zinc oxide (ZnO) and vanadium dioxide (VO) as representatives, using a commercial focused ion beam (FIB) system. Using a Ga FIB and thermal annealing, we demonstrated variable doping of a wide-bandgap semiconductor, ZnO, achieving carrier concentrations from 10 cm to 10 cm. Using the same FIB without subsequent thermal annealing, we defect-engineered a correlated semiconductor, VO, locally modifying its insulator-to-metal transition (IMT) temperature by up to ∼25 °C.
View Article and Find Full Text PDFAn induced-transmission filter (ITF) uses an ultrathin metallic layer positioned at an electric-field node within a dielectric thin-film bandpass filter to select one transmission band while suppressing other bands that would have been present without the metal layer. We introduce a switchable mid-infrared ITF where the metal can be "switched on and off", enabling the modulation of the filter response from a single band to multiband. The switching is enabled by the reversible insulator-to-metal phase transition of a subwavelength film of vanadium dioxide (VO).
View Article and Find Full Text PDFStructural characterization of biologically formed materials is essential for understanding biological phenomena and their enviro-nment, and for generating new bio-inspired engineering concepts. For example, nacre-the inner lining of some mollusk shells-encodes local environmental conditions throughout its formation and has exceptional strength due to its nanoscale brick-and-mortar structure. This layered structure, comprising alternating transparent aragonite (CaCO) tablets and thinner organic polymer layers, also results in stunning interference colors.
View Article and Find Full Text PDFWe propose a new type of reflective polarizer based on polarization-dependent coupling to surface plasmon polaritons (SPPs) from free space. This inexpensive polarizer is relatively narrowband but features an extinction ratio of up to 1000 with efficiency of up to 95% for the desired polarization (numbers from a calculation) and thus can be stacked to achieve extinction ratios of 10 or more. As a proof of concept, we experimentally realized a polarizer based on nanoporous aluminum oxide that operates around a wavelength of 10.
View Article and Find Full Text PDFA novel background-free fluorescent sensory receptor, with the potential to enable an in situ sensing strategy with new chromophores generated upon the detection event, was designed for the detection of glutathione by forming a fancy 16-ring fluorescent product with one/two-photon excited fluorescence.
View Article and Find Full Text PDFShaping is very necessary in order to obtain a wide and flat supercontinuum (SC). Via numerical simulations, we accurately demonstrated shaping the SC using the fiber cascading method to significantly increase the width as well as the flatness of the spectrum in silica photonic crystal fiber (PCF). The cascaded PCF contains two segments, each of which has dual zero-dispersion frequencies (ZDFs).
View Article and Find Full Text PDFThermal emission is the process by which all objects at nonzero temperatures emit light and is well described by the Planck, Kirchhoff, and Stefan-Boltzmann laws. For most solids, the thermally emitted power increases monotonically with temperature in a one-to-one relationship that enables applications such as infrared imaging and noncontact thermometry. Here, we demonstrated ultrathin thermal emitters that violate this one-to-one relationship via the use of samarium nickel oxide (SmNiO), a strongly correlated quantum material that undergoes a fully reversible, temperature-driven solid-state phase transition.
View Article and Find Full Text PDFAcetylcholinesterase (AChE) is an important enzyme associated with many nervous diseases, demonstrating the great need for smarter sensing platform with improved sensitivity, selectivity and simplified operation. A "turn on" fluorometric assay is described herein for AChE activity detection, according to the specific enzyme catalyzed reaction of acetylcholine (ATCh) by AChE, which generates thiocholine (TCh) as the product. The well-designed fluorescent probe HBTP possesses ESIPT (Excited State Intramolecular Proton Transfer) nature, leading to a larger Stokes shift, which could be quenched upon coordination with Cu.
View Article and Find Full Text PDFA step-index tellurite optical fiber with loss ∼0.02 dB/m at ∼1545 nm was fabricated based on TeO-BiO-ZnO-NaO glass. With a nanosecond laser operated at ∼1545 nmas the pump source, second-harmonic generation (SHG) was observed in the 2.
View Article and Find Full Text PDFWe explore how to acquire the tunable ultra-short pulse sequences in a quasi-discrete spectral supercontinuum (SC) via the formation of dark solitons in a fiber with two zero dispersion wavelengths (ZDWs). These dark solitons are produced by pumping two pulses in the normal dispersion that are identical but delayed one with respect to the other. Few-cycle pulses with high power as dual pumps experience temporal breakdown, resulting in a nearly-complete conversion of pump energy into two normal dispersion regions to form the ultra-short pulse sequences separated by dark solitons.
View Article and Find Full Text PDFMelanoma is an aggressive malignant tumor that undergoes rapid growth and metastasis in a short time; tyrosinase (TYR) is an important biomarker for melanoma diagnosis as it is over-expressed in melanoma cells. Therefore, the detection of TYR activity is of great significance. Although several fluorescent probes have been reported for the determination of tyrosinase activity in vitro and in vivo, only few of them possess a ratiometric pattern to provide built-in self-calibration for signal correction.
View Article and Find Full Text PDFSpectrochim Acta A Mol Biomol Spectrosc
December 2019
Accurate detection of human serum albumin (HSA) in biological samples is quite meaningful for early disease diagnosis and treatment. Herein, a novel fluorescent probe 1-ethyl-4-[2-[4-(diethylamino)-2-hydroxyphenyl]ethenyl]]-pyridinium salt (DEHP) was developed for HSA determination. The inherent fluorescence of DEHP is essentially negligible at physiological conditions assigned to the well-developed twisted intramolecular charge transfer (TICT) protocol.
View Article and Find Full Text PDFWe demonstrate the generation of nanosecond mid-infrared pulses via fast modulation of thermal emissivity enabled by the absorption of visible pump pulses in unpatterned silicon and gallium arsenide. The free-carrier dynamics in these materials result in nanosecond-scale modulation of thermal emissivity, which leads to nanosecond pulsed thermal emission. To our knowledge, the nanosecond thermal-emissivity modulation in this work is three orders of magnitude faster than what has been previously demonstrated.
View Article and Find Full Text PDFThermal emission is a ubiquitous and fundamental process by which all objects at non-zero temperatures radiate electromagnetic energy. This process is often assumed to be incoherent in both space and time, resulting in broadband, omnidirectional light emission toward the far field, with a spectral density related to the emitter temperature by Planck's law. Over the past two decades, there has been considerable progress in engineering the spectrum, directionality, polarization and temporal response of thermally emitted light using nanostructured materials.
View Article and Find Full Text PDFBased on induced modulation instability, we present a numerical study on harnessing rogue wave for supercontinuum generation in cascaded photonic crystal fibers. By selecting optimum modulation frequency, we achieve supercontinuum with a great improvement on spectrum stability when long-pulse is used as the pump. In this case, rogue wave can be obtained in the first segmented photonic crystal fiber with one zero dispersion wavelength in a controllable manner.
View Article and Find Full Text PDFWith the size of plasmonic devices entering into the nanoscale region, the impact of quantum physics needs to be considered. In the past, the quantum size effect on linear material properties has been studied extensively. However, the nonlinear aspects have not been explored much so far.
View Article and Find Full Text PDFWe study intermodal four-wave mixing (FWM) in few-mode fibers in the presence of birefringence fluctuations and random linear mode coupling. Two different intermodal FWM processes are investigated by including all nonlinear contributions to the phase-matching condition and FWM bandwidth. We find that one of the FWM processes has a much larger bandwidth than the other.
View Article and Find Full Text PDFWe consider propagation of an electromagnetic (EM) wave through a dynamic optical medium whose refractive index varies with time. Specifically, we focus on the reflection and transmission of EM waves from a temporal boundary and clarify the two different physical processes that contribute to them. One process is related to impedance mismatch, while the other results from temporal scaling related to a sudden change in the speed of light at the temporal boundary.
View Article and Find Full Text PDFThe polarization filter characters of a gold-coated and liquid-filled photonic crystal fiber are studied using the finite element method. Results show that the resonance strength and wavelengths are different in two polarized directions. Filling liquid of refractive index n=1.
View Article and Find Full Text PDFWe apply our recently developed time-transformation method for studying the propagation of few-cycle optical pulses inside a nonlinear Kerr medium after taking into account that changes in the refractive index vary with the electric field as E2 and not by its average over an optical cycle. Our technique correctly predicts carrier-wave shocking and generation of odd-order harmonics inside a Kerr medium, the two features found earlier with directly solving Maxwell's equations using the finite-difference time-domain (FDTD) methods. We extend our method to study the impact of a finite response of the Kerr nonlinearity on harmonic generation and to include chromatic dispersion that cannot be ignored for ultrashort pulses.
View Article and Find Full Text PDFWe present a time-transformation approach for studying the propagation of optical pulses inside a nonlinear medium. Unlike the conventional way of solving for the slowly varying amplitude of an optical pulse, our new approach maps directly the input electric field to the output one, without making the slowly varying envelope approximation. Conceptually, the time-transformation approach shows that the effect of propagation through a nonlinear medium is to change the relative spacing and duration of various temporal slices of the pulse.
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