An ultra-sensitive photoelectrochemical (PEC) biosensor for amyloid-beta 40 (Aβ40), a biomarker for Alzheimer's disease (AD), was developed using g-C₃N₄ modified with gold nanoparticles (Au NPs) to form Au-C₃N₄. This was further combined with TiO₂ to create a tightly bonded TiO₂/Au-C₃N₄ heterojunction, leading to a highly responsive photocatalytic process. Furthermore, the incorporation of noble metal Au NPs not only enhances photocurrent generation but also securely immobilizes the aptamer through Au-S bonds, providing additional surface binding sites.
View Article and Find Full Text PDFThe sensitivity and specificity of a semiconductor photoelectrochemical (PEC) aptamer biosensor are determined by the separation and transport of the photoinduced carriers as well as aptamer probe immobilization. In this study, an thermal transformation organic polymer strategy was employed to produce an ∼2.5 nm carbon quantum layer on the surface of the BiVO(BVO) photoanode.
View Article and Find Full Text PDFGaN-based quantum well infrared detectors can make up for the weakness of GaAs-based quantum well infrared detectors for short-wave infrared detection. In this work, GaN/AlN (1.8 nm/1.
View Article and Find Full Text PDFSurface passivation of the photoelectrode by wide bandgap semiconductor quantum layer is an important strategy to improve work stability and surface state inhibition. However, an inevitable energy barrier is generated during the quantum tunneling process of the photocarriers. To overcome this shortage, a tandem photo-generated hole transfer route is fabricated on BiVO photoanode by doped dual-quantum layers modification, Ni-ZnO (5 nm) and Rh-SrTiO (≈10 nm).
View Article and Find Full Text PDFIn this study, we developed a crystal-reconstructed-BiVO aptamer photoelectrochemical (PEC) biosensor by a high-energy laser treatment technique. This biosensor achieves a limit of detection (LOD) (0.82 ag mL), linear detection range (1 ag mL to 2 ng mL), and resolution ratio (∼18 molecules per mL) for prostate-specific antigen (PSA) tumor biomarker detection.
View Article and Find Full Text PDFIn this work, we fabricate a novel bismuth vanadate/two dimensional-carbon nitride/deoxyribonucleic acid (BiVO/2D-CN/DNA) aptamer photoelectrochemical (PEC) sensor, and this sensor provides a record detection sensitivity area (5 × 10 μg/L - 10 μg/L) for Microcystin-LR (MC-LR). Meanwhile, except for MC-LR detection, this sensor presents highly sensitivity for tumor marker, heavy metal ion, antibiotic also by changing the DNA aptamer. Photo charge dynamic and theory calculation results reveal that 2D-CN is a key material for multifunctional interface reconciliation of this PEC aptamer sensor.
View Article and Find Full Text PDFPolyaniline/silver/silver phosphate (PANI/Ag/Ag3PO4) composite was prepared by in situ depositing silver phosphate (Ag3PO4) nanoparticles on the surface of polyaniline (PANI). The best photocatalytic Rhodamine B degradation performance is obtained by the 20 wt % PANI/Ag/Ag3PO4 composite, which is approximately 4 times higher than that of pure Ag3PO4. Meanwhile, the photocatalytic stability of Ag3PO4 is significantly improved by introducing PANI into the PANI/Ag/Ag3PO4 composite.
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2013
In the present paper, the graphene-ZnO composite with quasi-shell-core structure was successfully prepared using a one-step wet chemical method. The photocatalytic Rhodamine B degradation property and the photoelectrochemical performance of the graphene-ZnO quasi-shell-core composite are dependent on the amount of graphene oxide that is added. When the amount of graphene oxide added is 10 mg, the graphene-ZnO quasi-shell-core composite possesses the optimal photocatalytic degradation efficiency and the best photoelectrochemical performance.
View Article and Find Full Text PDFA ZnFe2O4-ZnO nanorod array (NRA) with a three-dimensional network nanometer structure was prepared. The photoelectrochemical performance of the ZnFe2O4-ZnO NRA composite is significantly improved due to the formation of a p-n heterojunction electric field at the interface between ZnFe2O4 and ZnO, the increase of the overall utilization efficiency of incident light energy, and the visible light absorption capability of ZnFe2O4.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2013
A ZnO nanorod array with comparatively long nanorods was successfully prepared on a Ti substrate by applying a hydrothermal method twice. CdS nanoparticles with high crystallinity were deposited onto the surface of ZnO nanorods through a galvanostatic electrodeposition method. CdS-sensitized ZnO nanorod arrays after being hydrothermally grown twice with the second growth time of 6 h possessed the best photoelectrochemical performance.
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