Publications by authors named "Yutaro Sakaguchi"

Complications of neurofibromatosis type 1 include fatal bleeding events due to vascular fragility. In this case of hemorrhagic shock due to a neurofibroma, the bleeding was controlled using an occlusion balloon and endovascular treatment which stabilized the patient. Systemic vascular investigation for bleeding sites is important to prevent fatal outcomes.

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Interactions of three different types of electronic angular momenta, namely, spin, orbital, and total angular momenta from different origins in a photoexcited neutral bis(phthalocyaninato)terbium single-molecule magnet (PcTb, where Pc denotes a phthalocyaninato anion) have been studied. We have conducted varied-temperature and varied-magnetic-field magnetic circular dichroism (MCD) measurements on the highest occupied molecular orbital-lowest unoccupied molecular orbital electronic transition in the ligand side of the neutral PcTb to reveal the quantum nature of the system composed of a π-radical with a spin angular momentum S, the 4f system with a total angular momentum J, and the cyclic π conjugate system with a photoinduced orbital angular momentum L. We have constructed a new theoretical model that gives a quantitative agreement to the temperature and magnetic field dependence of MCD.

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The presence of a new electronic interaction, which couples a 4 f-electronic system with a total angular momentum J and a photoexcited cyclic π-conjugated system with an orbital angular momentum L, in the bis(phthalocyaninato)dysprosium single-molecule magnet ([DyPc ] ) is reported. Two π-π* excited states in the visible spectral region of the [DyPc ] complex, which are denoted here as Q and Q , showed significantly different temperature and field dependences of the magnetic circular dichroism (MCD) A-term intensity. This phenomenon not only indicates the presence of a "J-L" interaction, but also that the interaction generates two different preferred orientations of the J-L pair, either parallel (for the Q band) or antiparallel (for the Q band), depending on the excitation energy.

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