J Environ Sci (China)
November 2024
Prednisone is a synthetic glucocorticoid that is commonly used in both human and veterinary medication. Now, it is also recognized as an emerging environmental contaminant. Pregnant women may be exposed to prednisone actively or passively through multiple pathways and cause developmental toxicity to the fetus.
View Article and Find Full Text PDFFront Cell Dev Biol
October 2021
SNHG10 is a long non-coding RNA (lncRNA) found to be overexpressed in multiple human cancers including prostate cancer (PC). However, the underlying mechanisms of SNHG10 driving the progression of PC remains unclear. In this study, we investigated the role of SNHG10 in PC and found that SNHG10 expression was significantly increased in datasets extracted from The Cancer Genome Atlas.
View Article and Find Full Text PDFCr(VI) is a common heavy metal ion, which will seriously harm human body and environment. Therefore, the removal of Cr(VI) has become an attractive topic. In this work, cinder was used as a raw material to synthesize a nanoneedle material: γ-(AlOOH@FeOOH) (γ-Al@Fe).
View Article and Find Full Text PDFOwing to its wide band gap of ~3.2 eV, perovskite BiTiNbO only absorbs the solar spectrum in the ultraviolet range, which restricts its use as an effective photocatalyst. Here, a controllable and facile reduction strategy was adopted to promote the in-situ growth of metallic Bi in perovskite BiTiNbO nanosheets.
View Article and Find Full Text PDFThe advanced oxidation process (AOPs) has caused great concern in recent years. Among them, biochar has been widely studied as a catalyst for advanced oxidation process because of its low price and low environmental risk. In this study, a novel ball milling assisted KOH activation biochar (MKBC) was prepared and applied in peroxydisulfate (PDS) activation to degrade tetracycline hydrochloride (TC-H).
View Article and Find Full Text PDFIt is important to find an effective way to enhance the photocatalytic efficiency of metal-organic frameworks. In this work, an organic supermolecule perylene diimide (PDI) semiconductor with a carboxyl terminal was added into the synthesis process of MIL-53(Fe) crystals. The PDI/MIL-53(Fe) (PM) composite photocatalyst was first obtained.
View Article and Find Full Text PDFThe surface structure significantly impacts the physicochemical properties of semiconductors. Constructing heterojunction is a universal approach to tune surface structure, which can effectively accelerate the charge transfer at the interface. Here, BiOCl nanosheets which occupy high ratio of surface atoms to entire atoms were used as a model photocatalyst, and a strategy was proposed to tune its surface structure by sequential introduction of oxygen vacancies, PO and Ag on surface of BiOCl nanosheets.
View Article and Find Full Text PDFEvid Based Complement Alternat Med
February 2021
Moxa floss is a type of biomass used as the main combustion material in moxibustion, a therapy that applies heat from moxa floss combustion to points or body areas for treatment. Safety concerns regarding moxa smoke have been raised in recent years. Since moxa floss is the source material in moxibustion, its thermal behavior and pyrolysis products would be related to the products formed in moxa smoke.
View Article and Find Full Text PDFRNA binding proteins (RBPs) play significant roles in the development of tumors. However, a comprehensive analysis of the biological functions of RBPs in clear cell renal cell carcinoma (ccRCC) has not been performed. Our study aimed to construct an RBP-related risk model for prognosis prediction in ccRCC patients.
View Article and Find Full Text PDFJ Colloid Interface Sci
March 2021
Using natural minerals as persulfate activators can develop effective and economical in situ chemical oxidation technology for environmental remediation. Yet, few natural minerals can provide a high activation efficiency. Here, we demonstrate that brochantite (CuSO(OH)), a natural mineral, can be used as a persulfate activator for the rapid degradation of tetracycline hydrochloride (TC-H).
View Article and Find Full Text PDFGenet Test Mol Biomarkers
November 2020
Circular RNAs (circRNAs), a type of noncoding RNA, are associated with the occurrence and development of cancers. In recent years, their potential as biomarkers for bladder cancer (BC) has attracted increased attention. To reveal the value of circRNAs in the prognosis of BC.
View Article and Find Full Text PDFBackground: Surgical resection is the main treatment for pheochromocytoma (PHEO). Although open surgery (OS) has been shown to be safe and feasible, the safety and efficacy of laparoscopic surgery (LS) for PHEO remain controversial due to the uncertain effects of pneumoperitoneum on haemodynamics and the complexity of the tumour itself. This study was performed to compare the treatment outcomes of OS with those of LS for patients with PHEO.
View Article and Find Full Text PDFACS Appl Mater Interfaces
August 2019
One of vital issues that inhibit photoactivity of metal-organic frameworks is the poor electrical conductivity. In this work, one-dimensional mixed-valence iron chains are used to improve this poor situation in MIL-53(Fe). A series of mixed-valence MIL-53(Fe) photocatalysts were obtained through heating at different temperatures in vacuum.
View Article and Find Full Text PDFIn this study, lignin extracted from rice husk was used to synthesis double network hydrogel adsorbent, named RH-CTS/PAM gel. RH-CTS/PAM gel exhibited macroporous structure and high buried water content, which gave rise to the exceptional adsorption performance. As results, in individual systems, the equilibrium time of Pb(II), Cu(II) and Cd(II) with initial concentration of 200 mg/L could be reached within 10 min, with the theoretical maximum adsorption capacity of 374.
View Article and Find Full Text PDFIron tungstophosphoric acid pillared montmorillonite (TPAFe-Mt) as a highly efficient, stable and visible-light-responsive photo-Fenton catalyst have successfully been prepared via an impregnation method. The TPAFe-Mt catalyst exhibits exceptional visible-light photo-Fenton catalytic activities for azo-dye methyl orange, phenol and 2,4-dinitrophenol in a wide pH range from 1.0 to 5.
View Article and Find Full Text PDFAlthough oxidation of As(III) to As(V) is deemed necessary to promote arsenic removal, the oxidation process usually involves toxic byproducts, well-defined conditions, energy input or sludge generation. Moreover, extra operations are required to remove the resulting As(V). A heterogeneous catalytic process of CuFeO with peroxymonosulfate (PMS) is established for As(III) oxidation and adsorption.
View Article and Find Full Text PDFIt is hard to balance high water permeability and good mechanical strength of hydrogel adsorbents. In this study, an enhanced double network hydrogel adsorbent of poly (vinyl alcohol)/poly(2-acrylamido-2-methyl-1-propanesulfonic acid) (PVA/PAMPS) was prepared via simple free-radical polymerization. Hydrophilic PAMPS guaranteed high swellability of the adsorbent, which made the sufficient diffusion of metal ions towards adsorbent inside.
View Article and Find Full Text PDFMassive consumption of cotton fabrics has brought up a serious problem concerning the waste cotton fabrics (WCFs) disposal. It is widely accepted that if WCFs can be reutilized, there will be great business potentials. Herein, we prepared a double network hydrogel based on WCFs and polyacrylamide (Cellulose/PAM DNHs) for heavy metal removal.
View Article and Find Full Text PDFExploring and designing an efficient and robust photocatalyst toward the degradation of organic pollutants under nature sunlight irradiation is a challenging research topic. The ability to maintain the photocatalytic activity in the entire daytime will be the ultimate goal for further widespread application of solar energy-driven semiconductor photocatalysis. Here, an all-day-active Z-scheme photocatalytic system is reported by employing Ag@AgI nanoparticles decorated AgPO cubes (C-AgPO@Ag@AgI).
View Article and Find Full Text PDF"Memory catalysis" (MC) studies have received appreciable attention recently because of the unique talent to retain the catalytic performance in the dark condition. However, the MC activity is still low owing to the relatively limited electron storage capacity of the present materials. Here, a TiO@Ag composite was synthesized by a "dark-deposition (DD)" method, which is based on the electron trap effect of TiO.
View Article and Find Full Text PDFPhotocatalytic degradation is an alternative method to remove pharmaceutical compounds from water, however it is hard to achieve efficient rate because of the low efficiency of photocatalysts. In this study, an efficient Z-Scheme photocatalyst was constructed by integrating graphitic carbon nitride (CN) and reduced graphene oxide (rGO) with AP via a simple facile precipitation method. Excitedly, ternary AP/rGO/CN composite showed superior photocatalytic and anti-photocorrosion performances under both intense sunlight and weak indoor light irradiation.
View Article and Find Full Text PDFHeterogeneous Fenton-like system has been proved to be an promising alternative to Fenton system due to its easy separation. However, it's a challenge to design heterogeneous Fenton-like catalysts with high activity and great durability. Here, ternary solid solution FeZnS were prepared via hydrothermal synthesis as heterogeneous Fenton-like catalysts.
View Article and Find Full Text PDFIn photocatalyst designing, quick recombination of photo-generated electron-hole pairs in the bulk or on the surface of semiconductors is a major limiting factor in achieving high photocatalytic efficiency, which is one of the most knotty scientific issues. For this purpose, a series of CdZnS twin nanocrystal (NC) zinc blende/wurtzite (ZB/WZ) homojunctions photocatalysts were synthesized by a facile solvothermal route and innovatively employed in photocatalytic degradation. In sample CdZnS, ZB and WZ phases have the largest distribution and closest interconnection at atomic level.
View Article and Find Full Text PDFIt is highly demanded to steer the charge flow in photocatalysts for efficient photocatalytic hydrogen reactions (PHRs). In this study, we developed a smart strategy to position MoS quantum dots (QDs) at the S vacancies on a Zn facet in monolayered ZnInS (Vs-M-ZnInS) to craft a two-dimensional (2D) atomic-level heterostructure (MoSQDs@Vs-M-ZnInS). The electronic structure calculations indicated that the positive charge density of the Zn atom around the sulfur vacancy (Vs) was more intensive than other Zn atoms.
View Article and Find Full Text PDFThis study investigated the technical applicability of a combination of Phanerochaete chrysosporium (P. chrysosporium) with photocatalyst graphitic carbon nitride (g-CN) for organic matters removal from landfill leachate under visible light irradiation. Photocatalyst g-CN was well immobilized on the hyphae surface of P.
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