The COVID-19 epidemic not only impacted China's economy but also induced periodic anxiety among employees, especially during its peak. Even as governmental controls relaxed, enterprises seemed unaffected externally. However, beneath the surface, the lingering effects on employee mental health persisted.
View Article and Find Full Text PDFThis study effectively coupled anammox and mixotrophic denitrification at a high nitrogen load rate of 6.84 g N/L/d with 40 mg/L Fe(II). Fe(II) enhanced the activity of nitrate reductase, nitrite reductase, and hydrazine dehydrogenase enzymes, facilitating accelerated ATP synthesis.
View Article and Find Full Text PDFThis article delves into the predefined-time output-feedback leader-following consensus problem of uncertain pure-feedback nonlinear multiagent systems for the first time. To streamline subsequent design, the original systems in pure-feedback form are first transformed into canonical systems. Following this, a distributed predefined-time extended state observer (ESO) and a local predefined-time ESO are developed to reconstruct the unknown states/lumped disturbance of the transformed leader system and follower systems, respectively.
View Article and Find Full Text PDFGM Crops Food
December 2024
Soybean is one of the important oil crops and a major source of protein and lipids. Drought can cause severe soybean yields. Dehydrin protein (DHN) is a subfamily of LEA proteins that play an important role in plant responses to abiotic stresses.
View Article and Find Full Text PDFThe start-up of a relatively high nitrogen load PD/Anammox in an EGSB reactor was achieved through strategies of bioaugmentation, mass transfer enhancement, and COD/NO-N control, with NRR of 5.2 g N/L/d. Longitudinal heterogeneity in EGSB reactor induced divergent nitrogen conversion pathways and enriched different functional microorganisms between stratified sludge.
View Article and Find Full Text PDFThe 1,2-iminylalkylation of diazenes using alkyl iodides in combination with an -benzoyl oxime is reported. In this transformation, -benzoyl oxime acted as a radical precursor and XAT mediator. In addition to common alkyl iodides, other alkyl iodides such as iodomethane, iodomethane-, trifluoroiodomethane, ethyl difluoroiodoacetate, and iodoalkanes containing unprotected hydroxyl and amide groups can also serve as C-radical precursors in the 1,2-iminylalkylation with electrophilic diazenes as radical acceptors.
View Article and Find Full Text PDFIn this study, a metal-free difunctionalization strategy for diazenes was developed using a range of bifunctionalization reagents. This strategy involves a unique N(sp)-N(sp) radical coupling between the hydrazine radical and the imine radical. More than 30 triazane core motifs were constructed by installing imines and various functional groups, including alkyl, phenyl, cyanoalkyl, and sulfonyl groups, on both ends of the nitrogen-nitrogen bond of diazenes in an efficient manner.
View Article and Find Full Text PDFIn this study, we developed a strategy using commercially available alkyl iodides and -benzoyl oxime to efficiently introduce alkyl and iminyl groups via energy transfer and halogen-atom transfer processes. We performed three-component 1,2-carboimination of olefins and four-component 1,4-carboimination across olefins and alkynes, resulting in the synthesis of over 60 nitrogen-containing molecules. Moreover, this transformation enables the synthesis of molecules with sensitive groups that were previously difficult to achieve.
View Article and Find Full Text PDFFe(II) participates in complex Fe-N cycles and effects on the microbial metabolism in the anaerobic ammonium oxidation (anammox) dominated system. In this study, the inhibitory effects and mechanisms of Fe(II)-mediated multi-metabolism in anammox were revealed, and the potential role of Fe(II) in the nitrogen cycle was evaluated. The results showed that the long-term accumulation of high Fe(II) concentrations (70-80 mg/L) led to a hysteretic inhibition of anammox.
View Article and Find Full Text PDFA new class of iminosulfonylation reagents were developed and extensively used in the 1,2-iminosulfonylation of various olefins. Olefins containing bioactive molecules, such as indomethacin, gemfibrozil, clofibrate, and fenbufen, afforded the desired iminosulfonylation products in synthetically useful yields. Furthermore, the first remote 1,6-iminosulfonylation of alkenes was realized by using oxime ester bifunctionalization reagents.
View Article and Find Full Text PDFThe quantized control problem for a heavy-lift launch vehicle (HLV) under actuator faults and rate gyro malfunctions is addressed in this paper. A predefined-time observer (PTO) is designed to reconstruct the immeasurable time derivative of attitude tracking errors with the settling time precisely predefined by one design parameter. Thus, parameter tuning for temporal demands is more straightforward and less conservative for the PTO than for fixed-time observers.
View Article and Find Full Text PDFA vinyl radical-mediated 1,5-hydrogen atom transfer strategy for remote C(sp)-H imination under visible-light-induced photochemical metal-free conditions afforded diverse γ-imino alkenes with excellent stereoselectivity. Oxime ester-based bifunctional reagents provided not only nucleophilic alkyl radicals for radical addition reactions with electron-deficient alkynes but also long-lived steady-state imine radicals for trapping alkyl radicals following the intramolecular 1,5-hydrogen migration of unstable olefin radicals.
View Article and Find Full Text PDFThis paper investigates the fixed-time distributed estimation problem for a class of second-order nonlinear systems with uncertain input, unknown nonlinearity and matched perturbation. A fixed-time distributed extended state observer (FxTDESO) consisting of a group of local observer nodes under directed communication topology is proposed, and each node can reconstruct both the full state and unknown dynamics of the system. To achieve fixed-time stability, a Lyapunov function is elaborated, and based on this, sufficient conditions for the existence of the FxTDESO are established.
View Article and Find Full Text PDFWith the global pandemic of COVID-19, it has been striking psychological burdens on individuals. Under this background, more and more people get wellbeing by watching live broadcasts. However, the psychological mechanism behind this phenomenon is still a black box.
View Article and Find Full Text PDFThe modular cyanoalkylamination of alkenes using bench-stable and easy-to-handle α-imino-oxy acid oxime esters as difunctional reagents creates new synthetic avenues. A metal-free photosensitization protocol for the installation of both amino and cyanoalkyl functionalities onto alkene feedstocks in a single step via two differently reactive nitrogen-centered radicals was developed via energy-transfer catalysis. Excellent functional group tolerance and mild reaction conditions also render this protocol suitable for the cyanoalkylamination of pharmaceutically relevant molecule-derived alkenes.
View Article and Find Full Text PDFWater Environ Res
September 2021
Fe(II) is one of the commonly used additives in wastewater treatment and proved to be beneficial for promoting microbial activity. In this study, the effects of Fe(II) on the specific anammox activity (SAA) and reactor performance were proved to be concentration-dependent. In the short-term experiment, low concentration of Fe(II) (5-80 mg/L) significantly enhanced the SAA, while high concentration of Fe(II) (120-300 mg/L) inhibited the SAA.
View Article and Find Full Text PDFEnvironmental degradation has severely affected the natural cycle of ecosystem. It's high time now and humans should execute strategies effectively to protect the further degradation. Initially, we need to understand the ways that might affect the environment.
View Article and Find Full Text PDFThe study intends to explore the following objectives: initially, to examine the non-linear connection between globalization, renewable energy consumption, and environmental degradation. Secondly, to evaluate the role of globalization in increasing or decreasing the carbon emission at the threshold level for different income countries. Panel smooth transition regression (PSTR) is an econometric technique that has been applied for estimation utilizing the data from 1995 to 2017.
View Article and Find Full Text PDFBackground: The COVID-19 epidemic not only cast a shadow on China's economic development but also caused phased panic and anxiety among the Chinese population. At the stage when the spread of the epidemic is not completely controlled, the business activities will surely cause employees to worry and produce a work stress reaction.
Objective: This study explores the impact of psychosocial stress caused by the COVID-19 epidemic on the work stress of returned workers.
Int J Environ Res Public Health
March 2019
Patient satisfaction can identify specific areas of improvement in public sector hospitals. However, the Pakistani healthcare system, and quality of service delivery is rarely assessed through the perspective of patient satisfaction. Our study demonstrated the performance of public healthcare systems in Pakistan by interacting with physical services (tangible and environmental), doctor⁻patient communication, and pharmacy and laboratory services based on patient satisfaction.
View Article and Find Full Text PDFOn a large sample of 2288 Han Chinese undergraduates, we investigated how religion and DRD4 are related to human altruistic giving behavior as measured with the Andreoni-Miller Dictator Game. This game enables us to clearly specify (non-)selfishness, efficiency, and fairness motives for sharing. Participants were further classified into religious categories (Christian, Buddhist-Tao, and No Religion) based on self-reports, and genotyped for the dopamine D4 receptor (DRD4) gene exon III VNTR.
View Article and Find Full Text PDFTwin and family studies suggest that political attitudes are partially determined by an individual's genotype. The dopamine D4 receptor gene (DRD4) exon III repeat region that has been extensively studied in connection with human behaviour, is a plausible candidate to contribute to individual differences in political attitudes. A first United States study provisionally identified this gene with political attitude along a liberal-conservative axis albeit contingent upon number of friends.
View Article and Find Full Text PDFSoc Cogn Affect Neurosci
December 2014
Humans are willing to punish norm violations even at a substantial personal cost. Using fMRI and a variant of the ultimatum game and functional magnetic resonance imaging, we investigated how the brain differentially responds to fairness in loss and gain domains. Participants (responders) received offers from anonymous partners indicating a division of an amount of monetary gain or loss.
View Article and Find Full Text PDFSoc Cogn Affect Neurosci
August 2014
Creativity enables humans to adapt flexibly to changing circumstances, to manage complex social relations and to survive and prosper through social, technological and medical innovations. In humans, chronic, trait-based as well as temporary, state-based approach orientation has been linked to increased capacity for divergent rather than convergent thinking, to more global and holistic processing styles and to more original ideation and creative problem solving. Here, we link creative cognition to oxytocin, a hypothalamic neuropeptide known to up-regulate approach orientation in both animals and humans.
View Article and Find Full Text PDFHuman beings are an extraordinarily altruistic species often willing to help strangers at a considerable cost (sometimes life itself) to themselves. But as Darwin noted "… he who was ready to sacrifice his life, as many a savage has been, rather than betray his comrades, would often leave no offspring to inherit his noble nature." Hence, this is the paradox of altruism.
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