This paper studied the effect of additives of 0.5-20 wt.% synthetic CaSiO wollastonite on the thermodynamic, mechanical, and tribological characteristics and structure of polymer composite materials (PCM) based on ultra-high-molecular weight polyethylene (UHMWPE).
View Article and Find Full Text PDFThe non-steady-state photoelectromotive force is excited in a monoclinic gallium oxide crystal at wavelength λ = 457 nm. The crystal grown in an oxygen atmosphere is insulating and highly transparent for a visible light, nevertheless, the formation of dynamic space-charge gratings and observation of the photo-EMF signal is achieved without application of any electric field to the sample. The dependencies of the signal amplitude on the frequency of phase modulation, light intensity, spatial frequency and light polarization are measured.
View Article and Find Full Text PDFControllable targeted deposition of an analyte dissolved in a liquid drop evaporating on a superhydrophobic surface has recently emerged as a promising concentrator approach with various applications ranging from ultrasensitive bioidentification to DNA molecule sorting. Here, we demonstrate that surface textures with non-uniform wettability fabricated using direct easy-to-implement femtosecond-pulse filament-assisted ablation of polytetrafluoroethylene substrates can be used to concentrate and deposit an analyte at a designated location out of a water droplet. The proposed surface textures contain a central superhydrophilic trap surrounded by superhydrophobic periodically arranged pillars with a hierarchical roughness.
View Article and Find Full Text PDFPulsed laser nanotexturing of metal films represents an ultra-fast, high-performance and cost-effective processing technology for fabrication of various functional surfaces widely used in plasmonics, biosensing, and photovoltaics. However, this approach usually requires high-NA lenses to focus a laser beam onto a few-micron spot as well as a micropositioning platform to move this spot along the sample surface, which increases the cost of the produced functional surfaces and limits the performance of laser-assisted nanotexturing techniques. In this paper we report on a laser-assisted technology for the fabrication of large-scale nanotextured metal substrates.
View Article and Find Full Text PDFSurface-enhanced Raman scattering (SERS) and surface-enhanced photoluminescence (SEPL) are emerging as versatile widespread methods for biological, chemical, and physical characterization in close proximity of nanostructured surfaces of plasmonic materials. Meanwhile, single-step, facile, cheap, and green technologies for large-scale fabrication of efficient SERS or SEPL substrates, routinely demonstrating both broad plasmonic response and high enhancement characteristics, are still missing. In this research, single-pulse spallative micron-size craters in a thick Ag film with their internal nanotexture in the form of nanosized tips are for the first time shown to demonstrate strong polarization-dependent enhancement of SEPL and SERS responses from a nanometer-thick covering Rhodamine 6G layer with average enhancement factors of 40 and 2 × 10(6), respectively.
View Article and Find Full Text PDFSimple high-performance, two-stage hybrid technique was developed for fabrication of different plasmonic nanostructures, including nanorods, nanorings, as well as more complex structures on glass substrates. In this technique, a thin noble-metal film on a dielectric substrate is irradiated by a single tightly focused nanosecond laser pulse and then the modified region is slowly polished by an accelerated argon ion (Ar(+)) beam. As a result, each nanosecond laser pulse locally modifies the initial metal film through initiation of fast melting and subsequent hydrodynamic processes, while the following Ar(+)-ion polishing removes the rest of the film, revealing the hidden topography features and fabricating separate plasmonic structures on the glass substrate.
View Article and Find Full Text PDFWe present a novel optical element - fiber microaxicon (FMA) for laser radiation focusing into a diffraction-limited spot with Bessel-like profile as well as for precision laser nanostructuring of metal film surfaces. Using the developed FMA for single-pulse irradiation of Au/Pd metal films on quartz substrate we have demonstrated the formation of submicron hollow microbumps with a small spike atop as well as hollow spherical nanoparticles. Experimental conditions for controllable and reproducible formation of ordered arrays of such microstructures were defined.
View Article and Find Full Text PDFWe demonstrate analytically and numerically that the detection of the spectral response of a single spherical Au nanoantenna allows one to map very small (down to 5·10(-4) RIU) variations of the refractive index of an optically transparent sample. Spectral shift of the dipole local plasmon resonance wavelength of the nanoantenna and the spectral sensitivity of the method developed was estimated by using simple analytical quasi-static model. A pointed scanning probe based on fiber microaxicon with the Au spherical nanoantenna attached to its tip was proposed to realize the RI mapping method.
View Article and Find Full Text PDFA photoelectric response of a Bi12SiO20 crystal grown in an argon atmosphere on a linearly polarized light (which is referred to as the linear photogalvanic effect) is reported for the first time in the nanosecond-time domain. Optimal geometry for detection of the photo-induced current concerning the orientation of the polarization state of the incident light in respect to the crystallographic axes of a sample was determined considering both the natural optical activity and light absorption of sillenite crystals. Spectral dependence of the photogalvanic current was measured in the visible part (410 - 610 nm) of the spectrum.
View Article and Find Full Text PDFSilicatein genes are involved in spicule formation in demosponges (Demospongiae: Porifera). However, numerous attempts to isolate silicatein genes from glass sponges (Hexactinellida: Porifera) resulted in a limited success. In the present investigation, we performed analysis of potential silicatein/cathepsin transcripts in three different species of glass sponges (Pheronema raphanus, Aulosaccus schulzei, and Bathydorus levis).
View Article and Find Full Text PDFSilicatein genes are known to be involved in siliceous spicule formation in marine sponges. Proteins encoded by these genes, silicateins, were recently proposed for nanobiotechnological applications. We studied silicatein genes of marine sponges Latrunculia oparinae collected in the west Pacific region, shelf of Kuril Islands.
View Article and Find Full Text PDFWe propose a novel multiplexing system for sensing of dynamic strains excited in different multimode optical fibers. Multiplexing of the sensors is implemented by using vectorial wave mixing technique in the reflection geometry of hologram formation in a photorefractive crystal of CdTe:V. We analyzed different mechanisms of the crosstalk between measuring channels and showed that system performance is strongly affected by residual stresses of the photorefractive crystal.
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