Development of Biphasic Injectable Hydrogels for Meniscus Scaffold from Photocrosslinked Glycidyl Methacrylate-Modified Poly(Vinyl Alcohol)/Glycidyl Methacrylate-Modified Silk Fibroin.

The development of a hydrogel material with a modified chemical structure of poly(vinyl alcohol) (PVA) and silk fibroin (SF) using glycidyl methacrylate (GMA) (denoted as PVA-g-GMA and SF-g-GMA) is an innovative approach in the field of biomaterials and meniscus tissue engineering in this study. The PVA-g-GMA/SF-g-GMA hydrogel was fabricated using different ratios of PVA-g-GMA to SF-g-GMA: 100/0, 75/25, 50/50, 25/75, and 0/100 (/ of dry substances), using lithium phenyl (2,4,6-trimethylbenzoyl)phosphinate (LAP) as a free radical photoinitiator, for 10 min at a low ultraviolet (UV) intensity (365 nm, 6 mW/cm). The mechanical properties, morphology, pore size, and biodegradability of the PVA-g-GMA/SF-g-GMA hydrogel were investigated.

Effect of Modified Natural Rubber on the Mechanical and Thermal Properties of Poly(Lactic Acid) and Its Composites with Nanoparticles from Biowaste.

The brittle behavior of poly(lactic acid) (PLA) and PLA composites with inorganic filler limits their applications; the addition of a toughening agent, such as a rubbery phase, was selected to transform the brittle to ductile behavior for versatility in various applications. This work aims to study the properties of PLA and PLA composite with filled nanosized hydroxyapatite (nHA) after adding modified natural rubber (MoNR), which acts as a toughening agent. MoNR refers to poly(acrylic acid-co-acrylamide)-grafted deproteinized natural rubber.

The Effect of Silver Nanoparticles/Titanium Dioxide in Poly(acrylic acid--acrylamide)-Modified, Deproteinized, Natural Rubber Composites on Dye Removal.

This work aims to enhance the dye-removal performance of prepared poly(acrylic acid--acrylamide)-modified, deproteinized, natural rubber ((PAA--PAM)-DPNR) through incorporation with silver nanoparticles/titanium dioxide. The (PAA--PAM)-DPNR was prepared by emulsion-graft copolymerization with a grafting efficiency of 10.20 ± 2.

Development of Poly(vinyl alcohol) Grafted Glycidyl Methacrylate/Cellulose Nanofiber Injectable Hydrogels for Meniscus Tissue Engineering.

This study aimed to develop poly (vinyl alcohol) grafted glycidyl methacrylate/cellulose nanofiber (PVA-g-GMA/CNF) injectable hydrogels for meniscus tissue engineering. PVA-g-GMA is an interesting polymer for preparing cross-linking injectable hydrogels with UV radiation, but it has poor mechanical properties and low cell proliferation. In this study, CNF as a reinforcing agent was selected to improve mechanical properties and cell proliferation in PVA-g-GMA injectable hydro-gels.

Reinforcement of Injectable Hydrogel for Meniscus Tissue Engineering by Using Cellulose Nanofiber from Cassava Pulp.

Injectable hydrogels can be applied to treat damaged meniscus in minimally invasive conditions. Generally, injectable hydrogels can be prepared from various polymers such as polycaprolactone (PCL) and poly (N-isopropylacrylamide) (PNIPAAm). Poly (ethylene oxide)-poly(propylene oxide)-poly(ethylene oxide) block copolymer-diacrylate (PEO-PPO-PEO-DA) is an interesting polymer due to its biodegradability and can be prepared as water-insoluble injectable hydrogel after curing with UV light at low intensity.

Preparation of Crosslinked Poly(acrylic acid--acrylamide)- Deproteinized Natural Rubber/Silica Composites as Coating Materials for Controlled Release of Fertilizer.

The crosslinked poly(acrylic acid--acrylamide)- deproteinized natural rubber/silica ((PAA--PAM)-DPNR/silica) composites were prepared and applied as coating materials for fertilizer in this work. The crosslinked (PAA--PAM)-DPNR was prepared via emulsion graft copolymerization in the presence of MBA as a crosslinking agent. The modified DPNR was mixed with various contents of silica (10 to 30 phr) to form the composites.

Biodegradable Polylactic Acid-Polyhydroxyalkanoate-Based Nanocomposites with Bio-Hydroxyapatite: Preparation and Characterization.

Biodegradable polymers play a significant role in medical applications, especially internal devices because they can be broken down and absorbed into the body without producing harmful degradation products. In this study, biodegradable polylactic acid (PLA)-polyhydroxyalkanoate (PHA)-based nanocomposites with various PHA and nano-hydroxyapatite (nHAp) contents were prepared using solution casting method. Mechanical properties, microstructure, thermal stability, thermal properties, and in vitro degradation of the PLA-PHA-based composites were investigated.

Preparation and Characterization of Acrylonitrile Butadiene Rubber Reinforced with Bio-Hydroxyapatite from Fish Scale.

This work aims to enhance the mechanical properties, oil resistance, and thermal properties of acrylonitrile butadiene rubber (NBR) by using the fish scales as a filler and using bis(triethoxysilylpropyl)tetrasulfide (TESPT) as a coupling agent (CA). The prepared fish scale particles (FSp) are B-type hydroxyapatite and the particle shape is rod-like. The filled NBR with FSp at 10 phr increased tensile strength up to 180% (4.

Potential Applications of Thermoresponsive Poly(-Isoproplacrylamide)-Grafted Nylon Membranes: Effect of Grafting Yield and Architecture on Gating Performance.

This study illustrated the potential applications of thermoresponsive poly(-isopropylacrylamide) (PNIPAm) grafted nylon membranes with different grafting yields and grafting architecture. The thermoresponsive gating performance at temperatures below and above the lower critical solution temperature (LCST) of PNIPAm (32 °C) were demonstrated. The linear PNIPAm-grafted nylon membrane exhibited a sharp response over the temperature range 20-40 °C.

Preparation of Poly(acrylic acid--acrylamide)- Deproteinized Natural Rubber and Its Effect on the Properties of Natural Rubber/Silica Composites.

This work aims to enhance the polarity of natural rubber by grafting copolymers onto deproteinized natural rubber (DPNR) to improve its compatibility with silica. Poly(acrylic acid--acrylamide)- DPNR ((PAA--PAM)-DPNR) was successfully prepared by graft copolymerization with acrylic acid and acrylamide in the latex stage, as confirmed by FTIR. The optimum conditions to obtain the highest conversion, grafting efficiency, and grafting percentage were a reaction time of 360 min, a reaction temperature of 50 °C, and an initiator concentration of 1.

Nano-Hydroxyapatite from White Seabass Scales as a Bio-Filler in Polylactic Acid Biocomposite: Preparation and Characterization.

Nano-hydroxyapatite (nHAp) as a bio-filler used in PLA composites was prepared from fish by acid deproteinization (1DP) and a combination of acid-alkali deproteinization (2DP) followed by alkali heat treatment. Moreover, the PLA/nHAp composite films were developed using solution casting method. The mechanical and thermal properties of the PLA composite films with nHAp from different steps deproteinization and contents were compared.

Effects of Titanium-Silica Oxide on Degradation Behavior and Antimicrobial Activity of Poly (Lactic Acid) Composites.

A mixed oxide of titania-silica oxides (TiSi oxides) was successfully prepared via the sol-gel technique from our previous work. The use of TiSi oxides to improve the mechanical properties, photocatalytic efficiency, antibacterial property, permeability tests, and biodegradability of polylactic acid (PLA) was demonstrated in this study. The influence of different types and contents of TiSi oxides on crystallization behavior, mechanical properties, thermal properties, and morphological properties was presented.

Structural Characterization of Titanium-Silica Oxide Using Synchrotron Radiation X-ray Absorption Spectroscopy.

In this study, titania−silica oxides (TixSiy oxides) were successfully prepared via the sol−gel technique. The Ti and Si precursors were titanium (IV), isopropoxide (TTIP), and tetraethylorthosilicate (TEOS), respectively. In this work, the effects of pH and the Ti/Si atomic ratio of titanium−silicon binary oxide (TixSiy) on the structural characteristics of TixSiy oxide are reported.

Electrospun Poly(lactic acid) and Silk Fibroin Based Nanofibrous Scaffold for Meniscus Tissue Engineering.

Biopolymer based scaffolds are commonly considered as suitable materials for medical application. Poly(lactic acid) (PLA) is one of the most popular polymers that has been used as a bioscaffold, but it has poor cell adhesion and slowly degrades in an in vitro environment. In this study, silk fibroin (SF) was selected to improve cell adhesion and degradability of electrospun PLA.

Effect of silane coupling agent treated bovine bone based carbonated hydroxyapatite on in vitro degradation behavior and bioactivity of PLA composites.

In this study, effect of treating bovine bone based carbonated hydroxyapatite (CHA) with silane coupling agent on in vitro degradation and bioactivity of PLA composites were investigated. PLA composite specimens containing CHA and silane-treated CHA were immersed in phosphate-buffered solution at 37 °C for the periods of time up to 8 weeks. The changes in specimen weights and morphologies, pH of PBS solution and PLA molecular weight were examined.