Exploring low-cost, high-activity, and structurally stable nonprecious metal electrocatalysts for sluggish oxygen evolution reaction (OER) is paramount for water electrolysis. Herein, we successfully prepare a novel Fe,Co-CeO/CeF@MXene heterostructure with Fe-Co dual active sites and oxygen vacancies for alkaline OER using an energy-free consumption co-deposition method. Impressively, Fe,Co-CeO/CeF@MXene achieves an ultralow overpotential of 192 mV and a long-term stability of 110 h at 10 mA cm without structural changes, thereby outperforming the commercial IrO (345 mV).
View Article and Find Full Text PDFACS Appl Mater Interfaces
December 2022
Artificial neurons as the basic units of spiking neural network (SNN) have attracted increasing interest in energy-efficient neuromorphic computing. 2D transition metal dichalcogenide (TMD)-based devices have great potential for high-performance and low-power artificial neural devices, owing to their unique ion motion, interface engineering, and resistive switching behaviors. Although there are widespread applications of TMD-based artificial synapses in neural networks, TMD-based neurons are seldom reported due to the lack of bio-plausible multi-mechanisms to mimic leaking, integrating, and firing biological behaviors without external assistance.
View Article and Find Full Text PDFThe assembly of single-walled carbon nanotubes (CNTs) into high-density horizontal arrays is strongly desired for practical applications, but challenges remain despite myriads of research efforts. Herein, we developed a non-destructive soft-lock drawing method to achieve ultraclean single-walled CNT arrays with a very high degree of alignment (angle standard deviation of ~0.03°).
View Article and Find Full Text PDFArchitectured materials on length scales from nanometers to meters are desirable for diverse applications. Recent advances in additive manufacturing have made mass production of complex architectured materials technologically and economically feasible. Existing architecture design approaches such as bioinspiration, Edisonian, and optimization, however, generally rely on experienced designers' prior knowledge, limiting broad applications of architectured materials.
View Article and Find Full Text PDFThe performance and reliability of large-area graphene grown by chemical vapor deposition are often limited by the presence of wrinkles and the transfer-process-induced polymer residue. Here, we report a transfer approach using paraffin as a support layer, whose thermal properties, low chemical reactivity and non-covalent affinity to graphene enable transfer of wrinkle-reduced and clean large-area graphene. The paraffin-transferred graphene has smooth morphology and high electrical reliability with uniform sheet resistance with ~1% deviation over a centimeter-scale area.
View Article and Find Full Text PDFGraphene grown by chemical vapor deposition is transferred by a very simple, yet effective approach from the growth substrate onto substrates with rough features. This novel and facile method not only results in satisfactory transfer on substrates with terraces or grooves, but also gives rise to a successful result for uneven growth substrates.
View Article and Find Full Text PDFProc Natl Acad Sci U S A
December 2013
Metallic glasses (MGs) exhibit greater elastic limit and stronger resistance to plastic deformation than their crystalline metal counterparts. Their capacity to withstand plastic straining is further enhanced at submicrometer length scales. For a range of microelectromechanical applications, the resistance of MGs to damage and cracking from thermal and mechanical stress or strain cycling under partial or complete constraint is of considerable scientific and technological interest.
View Article and Find Full Text PDFThe electronic and magnetic properties of bilayer graphene (BLG) depend on the stacking order between the two layers. We introduce a new conceptual structure of "slip corona" on BLG, which is a transition region between A-A stacking close to a nanopore composed of bilayer edges (BLEs) and A-B stacking far away. For an extremely small nanopore (diameter D(pore) < ~5 nm), both atomistic simulations and a continuum model reach consistent descriptions on the shape and size of this "corona" (diameter ~50 nm), which is much larger than the width of the typical dislocation core (~1 nm) in 3D metals or the nanopore itself, due to the weak van der Waals interactions and low interlayer shear resistance between two adjacent layers of graphene.
View Article and Find Full Text PDFObjective: To investigate the mechanical characteristics of new type two-head automatic pressure external fixator in the view of biomechanics.
Methods: Fifteen fresh and humid specimens were selected and divided into experimental group (5 cases) and control group (10 cases). The control group were respectively applied with DHS (5 cases) and traditional external fixator (5 cases).