The supercritical carbon dioxide foaming characteristics of the biodegradable polymer poly(3-hydroxybutyrate-co-4-hydroxybutyrate) (P(3HB--4HB)) are studied for environmentally friendly packaging materials. The effect of the 4HB composition of the P(3HB--4HB) copolymers on the foaming conditions such as pressure and temperature is studied and the density and the expansion ratio of the resulting P(3HB--4HB) foam are together evaluated. The increase in the 4HB content reduces the crystallinity and tan δ value of P(3HB--4HB) required for the growth of the foam cells.
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