Polarization-dependent hard X-ray excited optical luminescence (XEOL) was used to study not only the optical properties but also the crystallographic orientations of a non-polar a-plane ZnO wafer. In addition to a positive-edge jump and extra oscillations in the near-band-edge (NBE) XEOL yield, we observed a blue shift of the NBE emission peak that follows the polarization-dependent X-ray absorption near-edge structure (XANES) as the X-ray energy is tuned across the Zn K-edge. This NBE blue shift is caused by the larger X-ray absorption, generating higher free carriers to reduce the exciton-LO phonon coupling, which causes a decrease in the exciton activation energy.
View Article and Find Full Text PDFWe report on the room temperature polariton lasing and photon lasing in a ZnO-based hybrid microcavity under optical pumping. A series of experimental studies of the polariton lasing (exciton-photon detunings of δ = -119 meV) in the strong-coupling regime are discussed and compared to a photon lasing (δ = -45 meV) in the weak-coupling regime obtained in the same structure. The measured threshold power density (31.
View Article and Find Full Text PDFWide bandgap semiconductors are promising materials for the development of polariton-based optoelectronic devices operating at room temperature (RT). We report the characteristics of ZnO-based microcavities (MCs) in the strong coupling regime at RT with a vacuum Rabi splitting of 72 meV. The impact of scattering states of excitons on polariton dispersion is investigated.
View Article and Find Full Text PDFStandards of low electrolytic conductivity were developed to satisfy the demands of the U.S. Navy and American industry for the measurement of high quality water.
View Article and Find Full Text PDFJ Res Natl Bur Stand A Phys Chem
January 1970
The mean stoichiometric activity coefficients of hydrofluoric acid in aqueous solutions have been calculated from measurements of electrolytic conductivity, the electromotive forces of galvanic cells without liquid junction, and the freezing-point depression. Values obtained from freezing-point depressions were converted to values for 25 °C using known values of the heats of dilution and apparent molal heat capacities of aqueous solutions of hydrofluoric acid of various concentrations. It is also shown that values for the concentrations of the various ionic species in hydrofluoric acid, namely, H, F, , and HF depend on the functions used to represent the ionic activity coefficients whereas values of the mean activity, , are independent of such functions.
View Article and Find Full Text PDF