Multi-walled carbon nanotubes (MWNT) was utilized as a conductive additive to enhance the capacity and rate capability of carbon coated LiFePO4 (C-LFP). Composites of C-LFP with MWNT (C-LFP-MWNT) were prepared by blending MWNT at different stages of C-LFP synthesis. The pre-blending (PrB) of MWNT (5, 10, 15 wt%) with LFP precursor (PrB-C-LFP-MWNT) before calcination in a reducing environment (5 vol% H2 in N2) at 750 degrees C, produced phase pure crystalline LFP with a reduction in particle size as increase in MWNT content.
View Article and Find Full Text PDFAn alternating stack (SG/GN) consisting of SnO₂-functionalized graphene oxide (SG) and amine-functionalized GO (GN) is prepared in solution. The thermally reduced SG/GN (r(SG/GN)) with decreased micro-mesopores and completely eliminated macropores, results in a high reversible capacity and excellent capacity retention (872 mA h g⁻¹ after 200 cycles at 100 mA g⁻¹) when compared to a composite without GN.
View Article and Find Full Text PDFJ Nanosci Nanotechnol
May 2012
Dye-Sensitized Solar Cells (DSSCs) comprised of TiO2 porous films with multi-walled carbon nanotubes (MWNT) were prepared at low temperature (150 degrees C). MWNT were incorporated to facilitate the fast electron transport resulting from metallic properties of carbon nanotubes. In order to enhance the effect of MWNT incorporation, TiO2-grafted MWNT (TiO2-MWNT) was synthesized which can increase the electron transport rate further due to proximity of TiO2 to MWNT The presence of TiO2 nanoparticles on the surface of MWNT was confirmed by electron microscopy and energy dispersive X-ray spectroscopy.
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