Identifying the Bifunctional Mechanism in Alkaline Water Electrolysis by Lewis Pairs at the Single-Atom Scale.

The bifunctional mechanism, involving multiactive compositions to simultaneously dissociate water molecules and optimize intermediate adsorption, has been widely used in the design of catalysts to boost water electrolysis for sustainable hydrogen energy production but remains debatable due to difficulties in accurately identifying the reaction process. Here, we proposed the concept of well-defined Lewis pairs in single-atom catalysts, with a unique acid-base nature, to comprehensively understand the exact role of multiactive compositions in an alkaline hydrogen evolution reaction. By facilely adjusting active moieties, the induced synergistic effect between Lewis pairs (M-P/S/Cr pairs, M = Ru, Ir, Pt) can significantly facilitate the cleavage of the H-OH bond and accelerate the removal of intermediates, thereby switching the rate-determining step from the Volmer step to the Heyrovsky step.

n-ZrS/p-ZrOS Photoanodes with NiOOH/FeOOH Oxygen Evolution Catalysts for Photoelectrochemical Water Oxidation.

Photoelectrochemical water splitting offers a promising approach for carbon neutrality, but its commercial prospects are still hampered by a lack of efficient and stable photoelectrodes with earth-abundant materials. Here, we report a strategy to construct an efficient photoanode with a coaxial nanobelt structure, comprising a buried-ZrS/ZrOS n-p junction, for photoelectrochemical water splitting. The p-type ZrOS layer, formed on the surface of the n-type ZrS nanobelt through a pulsed-ozone-treatment method, acts as a hole collection layer for hole extraction and a protective layer to shield the photoanode from photocorrosion.

Fabrication of Single-Crystal Violet Phosphorus Flakes For Ultrasensitive Photodetection.

Violet phosphorus (VP) has attracted a lot of attention for its unique physicochemical properties and emerging potential in photoelectronic applications. Although VP has a van der Waals (vdW) structure similar to that of other 2D semiconductors, direct synthesis of VP on a substrate is still challenging. Moreover, optoelectronic devices composed of transfer-free VP flakes have not been demonstrated.

Selectively Confined Black Phosphorus Nanowires in Carbon Nanotubes.

Nanoconfinement of low-dimensional materials opens up a new territory for tailoring material hybridization to produce novel geometric structures for applications in electronics, catalysis, and photonics. Despite the progress made in the encapsulation of 2D materials, exploration of their definite crystal structures into lower-dimensional nanomaterials is still largely unexplored. Herein, one-dimensional black phosphorus (BP) nanowires with an aspect ratio of over 100 produced by confining BP into the CNT (conf-BP@CNT) are reported.

Achieving High-Performance Electrocatalytic Water Oxidation on Ni(OH) with Optimized Intermediate Binding Energy Enabled by S-Doping and CeO -Interfacing.

The adsorption energy of the reaction intermediates has a crucial influence on the electrocatalytic activity. Ni-based materials possess high oxygen evolution reaction (OER) performance in alkaline, however too strong binding of *OH and high energy barrier of the rate-determining step (RDS) severely limit their OER activity. Herein, a facile strategy is shown to fabricate novel vertical nanorod-like arrays hybrid structure with the interface contact of S-doped Ni(OH) and CeO in situ grown on Ni foam (S-Ni(OH) /CeO /NF) through a one-pot route.

Single-Atom Pt Doping Induced p-Type to n-Type Transition in NiO Nanosheets toward Self-Gating Modulated Electrocatalytic Hydrogen Evolution Reaction.

Exploring highly efficient single atom catalysts with defined active centers and tunable electronic structures is highly desirable. Herein, we developed an efficient hydrogen evolution reaction (HER) electrocatalyst through a self-gating phenomenon induced by Pt single atoms (SAs) supported on ultrathin NiO nanosheets (Pt-NiO). The Ni atoms in NiO are partially replaced by the atomically dispersed Pt atoms, leading to a transition from p-type NiO into n-type Pt-NiO.

Selective photoelectrochemical oxidation of glucose to glucaric acid by single atom Pt decorated defective TiO.

Photoelectrochemical reaction is emerging as a powerful approach for biomass conversion. However, it has been rarely explored for glucose conversion into value-added chemicals. Here we develop a photoelectrochemical approach for selective oxidation of glucose to high value-added glucaric acid by using single-atom Pt anchored on defective TiO nanorod arrays as photoanode.

Sequential Electrodeposition of Bifunctional Catalytically Active Structures in MoO /Ni-NiO Composite Electrocatalysts for Selective Hydrogen and Oxygen Evolution.

Exploring earth-abundant and highly efficient electrocatalysts is critical for further development of water electrolyzer systems. Integrating bifunctional catalytically active sites into one multi-component might greatly improve the overall water-splitting performance. In this work, amorphous NiO nanosheets coupled with ultrafine Ni and MoO nanoparticles (MoO /Ni-NiO), which contains two heterostructures (i.

Nanophase graphene frameworks.

Nanophase graphene frameworks (NGFs) assembled by interconnected domains have massive interfaces, where the interfacial interaction and the compact architectures drastically elevate the durability of graphene towards physical and chemical destruction. The excellent electrical conductivity of the NGFs can be perfectly maintained even after 1500 friction cycles or 3 h flame treatment.