The assumption of local equilibrium, especially in test standards for assessing the leaching of hazardous substances from materials, is crucial for the use of test results and the robustness of testing. However, previous studies of contact time conditions in percolation test standard have evaluated equilibrium and robustness separately. Therefore, this study tests the assumption of local equilibrium in the up-flow percolation test, standardized as ISO 21268-3 in 2019, and discusses the relationship between the similarity of test results and degree of equilibrium.
View Article and Find Full Text PDFA simple method for measuring the concentration of nano/microplastics (N/MPs) in soil, which is difficult owing to the size of the filter mesh and the resolution of the measuring instrument, was investigated. A spectrophotometer was used for the measurements and polystyrene particles were used as the N/MP samples. When measuring N/MP concentrations in soil suspensions, absorbance was measured at two wavelengths, and the best combination of wavelengths for measurement was extracted because soil particles and leached components interfere with N/MP absorbance.
View Article and Find Full Text PDFSoil batch leaching tests are conducted worldwide to quantify the leaching of hazardous substances from contaminated soil. In the extracts of soil batch leaching tests, some inorganic substances such as arsenic and lead are released both in colloidal and dissolved form. Recent studies have found that soil colloidal particles with small diameters persist in the filtrate even after the extracts are filtered through a membrane filter (MF) with a pore size of 0.
View Article and Find Full Text PDFA large amount of excavated soils with low-level As contamination caused by civil construction projects is of great concern in Japan. This study investigated the chemical speciation and extractability of As in 24 soil samples from the sites affected and unaffected (naturally contaminated) by anthropogenic pollution. The results of As K-edge XANES demonstrated that naturally contaminated soils were grouped into two types: (i) soils containing FeAsS-like and AsS-like species (ave.
View Article and Find Full Text PDFSoil leaching tests are commonly used to evaluate the leachability of hazardous materials, such as heavy metals, from the soil. Batch leaching tests often enhance soil colloidal mobility and may require solid-liquid separation procedures to remove excess soil particles. However, batch leaching test results depend on particles that can pass through a 0.
View Article and Find Full Text PDFThe leaching behavior of cathode ray tube (CRT) funnel glass containing 23 mass percent of Pb in 0.001 N HCl, distilled water, and 0.001 N NaOH at 90°C was investigated using a static method.
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