Alternating electrodeposition fabrication of graphene-buffered nickel-cobalt layered double hydroxide supercapacitor electrodes with superior rate capability.

Combining pseudocapacitive materials with carbon materials, such as graphene, is a promising strategy to enhance their performance. In this study, we present a novel and feasible approach involving the alternating electrodeposition of reduced graphene oxide (rGO) and nickel-cobalt layered double hydroxide (NiCo-LDH) onto carbon cloth (CC) current collectors to fabricate binder-free supercapacitor electrodes with a layered LDH/rGO/LDH/rGO/CC architecture. The rGO layers are not only coated on CC substrate to regulate the electrodeposition of LDH nanosheets, but also interposed between the LDH layers to further enhance conductivity and provide buffering effects.

Oxidative MnO Template Assisted Electrochemical Fabrication of Graphene/Polypyrrole Supercapacitor Electrodes.

Improving the morphological structure of active materials is a reliable strategy for the fabrication of high-performance supercapacitor electrodes. In this study, we introduce a feasible approach to constructing the graphene/polypyrrole (PPy) composite film implanted onto the current collector through a two-step electrochemical deposition method utilizing MnO as an intermediary template. The reduced graphene oxide (rGO) hydrogel film is first hydrothermally grown on a carbon cloth (CC) substrate to obtain a porous rGO@CC electrode on which MnO is electrodeposited.

Causal roles of educational duration in bone mineral density and risk factors for osteoporosis: a Mendelian randomization study.

Background: Educational duration might play a vital role in preventing the occurrence and development of osteoporosis(OP).

Purpose: To assess the causal effect of educational duration on bone mineral density(BMD) and risk factors for OP by Mendelian randomization(MR) study.

Methods: The causal relationship was analyzed using data from genome-wide association study(GWAS).

CAUSAL ROLES OF SERUM URIC ACID LEVELS AND GOUT IN SEPSIS: A MENDELIAN RANDOMIZATION STUDY.

Objective: Several epidemiological studies have identified a potential link between serum uric acid (UA), gout, and sepsis. The primary objective of this study is to delve deeper into this connection, investigating the causal effect of UA and gout on sepsis by applying Mendelian randomization (MR). Methods: The causal relationship was analyzed using data from Genome-Wide Association Study (GWAS).

One-Step Fabrication of Integrated Graphene/Polypyrrole/Carbon Cloth Films for Supercapacitor Electrodes.

The facile and cost-effective preparation of supercapacitor electrodes is significant for the application of this kind of electrochemical energy-storing module. In this work, we designed a feasible strategy to fabricate a binary active material onto a current collector in one step. A colloidal mixture of graphene oxide and pyrrole layered on a carbon cloth could undergo a redox reaction through a mild hydrothermal process to yield a reduced graphene oxide/polypyrrole hydrogel film anchored onto the carbon cloth.

Mesoporous TiO layer suppresses ion accumulation in perovskite solar cells.

Ion accumulation in perovskite solar cells can be highly suppressed by a mesoporous TiO layer. This is evidenced by the decrease of the ion-related electrostatic potential with increasing the thickness of the mesoporous layer, accounted for by the electron population in the shallow trap states of the TiO nanocrystals.

Does prior exposure to immune checkpoint inhibitors treatment affect incidence and mortality of COVID-19 among the cancer patients: The systematic review and meta-analysis.

Background: Immune checkpoint inhibitors (ICIs) treatment among cancer patients has been shown to have antiviral effects by reactivating exhausted T cells. However, they could also trigger inflammatory storm. Therefore, prior exposure to ICIs may influence the risk of SARS-CoV2 infection and subsequent mortality.

Influence of the MACl additive on grain boundaries, trap-state properties, and charge dynamics in perovskite solar cells.

Grain boundary trap passivation in perovskite films has become one of the most effective strategies for suppressing the charge recombination and enhancing the photovoltaic performance of perovskite solar cells, whereas the relevant trap-state properties and the charge carrier dynamics need to be further clarified. In this work, the CH3NH3Cl (MACl) additive is introduced into the MAI:PbI2 precursor solution to obtain perovskite films comprising various grain sizes with distinct grain boundaries and trap-state properties. The influence of grain boundary traps passivated with the MACl additive on trap-state properties and charge carrier transport/recombination dynamics is systematically studied with time-resolved spectroscopic and transient photoelectric characterization.

[Analysis of related factors of carbapenem resistant Klebsiella pneumoniae infection in patients with artificial airway].

Objective: To analyze the clinical characteristics and related influencing factors of carbapenem resistant Klebsiella pneumoniae (CRKP) in patients with artificial airway and mechanical ventilation in intensive care unit (ICU), and provide theoretical basis for clinical prevention of Klebsiella pneumoniae infection.

Methods: The clinical data of patients with pulmonary infection of Klebsiella pneumoniae in ICU of Beijing Shijitan Hospital Affiliated to Capital Medical University from January 2016 to December 2019 were collected. Compared CRKP pneumonia patients (study group) with carbapenem antibiotic sensitive Klebsiella pneumoniae (CSKP) pneumonia patients (control group), the clinical characteristics [gender, age, acute physiology and chronic health evaluation II (APACHE II), duration of mechanical ventilation, proportion of patients with mechanical ventilation > 10 days, use of antibiotics before detection of Klebsiella pneumoniae, white blood cell count (WBC), C-reactive protein (CRP), procalcitonin (PCT), albumin, bedridden for more than 1 month before admission, 28-day mortality] were analyzed.

The influence of the electron transport layer on charge dynamics and trap-state properties in planar perovskite solar cells.

Despite the outstanding photovoltaic performance of perovskite solar cells, the correlation between the electron transport layer and the mechanism of photoelectric conversion is still not fully understood. In this paper, the relationship between photovoltaic performance and carrier dynamics is systematically studied in both TiO- and SnO-based planar perovskite devices. It is found that the different electron transport layers result in distinct forward scan results and charge dynamics.

Modification of NiO hole transport layer for acceleration of charge extraction in inverted perovskite solar cells.

The modification of the inorganic hole transport layer has been an efficient method for optimizing the performance of inverted perovskite solar cells. In this work, we propose a facile modification of a compact NiO film with NiO nanoparticles and explore the effects on the charge carrier dynamic behaviors and photovoltaic performance of inverted perovskite devices. The modification of the NiO hole transport layer can not only enlarge the surface area and infiltration ability, but also adjust the valence band maximum to well match that of perovskite.

Preparation of graphene/Au aerogel film through the hydrothermal process and application for HO detection.

In this paper, one-step preparation of graphene/gold nanoparticle hydrogel film through the hydrothermal method is reported. The hydrogel film could be formed on a glass substrate under hydrothermal conditions, and upon freeze-drying, the aerogel film of 40 μm thickness with satisfying flexibility and strength is obtained. The aerogel composite film is characterized by scanning/transmission electron microscopy, X-ray diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy.

Charge carrier recombination dynamics in a bi-cationic perovskite solar cell.

The compositional engineering is of great importance to tune the electrical and optical properties of perovskite and improve the photovoltaic performance of perovskite solar cells. The exploration of the corresponding photoelectric conversion processes, especially the carrier recombination dynamics, will contribute to the optimization of the devices. In this work, perovskite with mixed methylammonium (MA) and formamidinium (FA) as organic cations, MA0.

Identification of novel uracil derivatives incorporating benzoic acid moieties as highly potent Dipeptidyl Peptidase-IV inhibitors.

Dipeptidyl Peptidase-IV (DPP-4) is a validated therapeutic target for type 2 diabetes. Aiming to interact with both residues Try629 and Lys554 in S' site, a series of novel uracil derivatives 1a-l and 2a-i incorporating benzoic acid moieties at the N position were designed and evaluated for their DPP-4 inhibitory activity. Structure-activity relationships (SAR) study led to the identification of the optimal compound 2b as a potent and selective DPP-4 inhibitor (IC = 1.

Characterization of the influences of morphology on the intrinsic properties of perovskite films by temperature-dependent and time-resolved spectroscopies.

Organic-inorganic halide perovskites have attracted enormous attention owing to their promising application in photovoltaic devices. The morphology of the perovskites is the key to driving the performance of perovskite devices, which necessitates a systematic study. In this work, two typical morphologies, i.

Synthesis, crystal structure and photophysical properties of 1,4-bis(1,3-diazaazulen-2-yl)benzene: a new π building block.

A dimerized 1,3-diazaazulene derivative, namely 1,4-bis(1,3-diazaazulen-2-yl)benzene [or 2,2'-(1,4-phenylene)bis(1,3-diazaazulene)], CHN, (I), has been synthesized successfully through the condensation reaction between 2-methoxytropone and benzene-1,4-dicarboximidamide hydrochloride, and was characterized by H NMR and C NMR spectroscopies, and ESI-MS. X-ray diffraction analysis reveals that (I) has a nearly planar structure with good π-electron delocalization, indicating that it might serve as a π building block. The crystal belongs to the monoclinic system.

Dual antiplatelet therapy after coronary artery bypass surgery: is there an increase in bleeding risk? A meta-analysis.

Objectives: There is increasing evidence that dual antiplatelet therapy (DAPT) when compared with single antiplatelet therapy may improve venous graft patency after coronary artery bypass graft. However, it is not yet known whether postoperative administration of DAPT may increase the potential risk of bleeding, especially in the early postoperative period.

Methods: We searched studies on PubMed, Embase, Web of Science and the Cochrane Central Register of Controlled Trials.

Multiple-Trapping Model for the Charge Recombination Dynamics in Mesoporous-Structured Perovskite Solar Cells.

The photovoltaic performance of organic-inorganic hybrid perovskite solar cells has reached a bottleneck after rapid development in last few years. Further breakthrough in this field requires deeper understanding of the underlying mechanism of the photoelectric conversion process in the device, especially the dynamics of charge-carrier recombination. Originating from dye-sensitized solar cells (DSSCs), mesoporous-structured perovskite solar cells (MPSCs) have shown many similarities to DSSCs with respect to their photoelectric dynamics.

Power output and carrier dynamics studies of perovskite solar cells under working conditions.

Perovskite solar cells have emerged as promising photovoltaic systems with superb power conversion efficiency. For the practical application of perovskite devices, the greatest concerns are the power output density and the related dynamics under working conditions. In this study, the working conditions of planar and mesoscopic perovskite solar cells are simulated and the power output density evolutions with the working voltage are highlighted.

Adverse Effects of Excess Residual PbI on Photovoltaic Performance, Charge Separation, and Trap-State Properties in Mesoporous Structured Perovskite Solar Cells.

Organic-inorganic halide perovskite solar cells have rapidly come to prominence in the photovoltaic field. In this context, CH NH PbI , as the most widely adopted active layer, has been attracting great attention. Generally, in a CH NH PbI layer, unreacted PbI inevitably coexists with the perovskite crystals, especially following a two-step fabrication process.

The Influence of Morphology and PbI on the Intrinsic Trap State Distribution in Perovskite Films Determined by Using Temperature-Dependent Fluorescence Spectroscopy.

Perovskite films with different particle sizes and PbI contents were prepared by using a controlled single or sequential method. By means of temperature-dependent fluorescence spectroscopy, the energetic distribution of intrinsic intragap trap states in perovskite was quantitatively determined, and the radiative charge recombinations through the band edge and via trap states were studied. Furthermore, a series of thermodynamic parameters, such as the demarcation energy between radiative and nonradiative recombination regions, detrapping activation energy, and characteristic temperature, were extracted based on which of the possible radiative and nonradiative recombination mechanisms were proposed.

Carbon nanotube composite microspheres as a highly efficient solid-phase microextraction coating for sensitive determination of phthalate acid esters in water samples.

Multiwalled carbon nanotubes (MWCNTs) on polystyrene (PS) microspheres have been designed and prepared by layer-by-layer assembly via electrostatic interaction. MWCNTs@PS was characterized by scanning electron microscopy (SEM) and thermogravimetric analysis (TGA). The new materials were employed as a novel solid-phase microextraction (SPME) coating to enrich trace level of phthalate acid esters (PAEs) in water samples.

Mechanism of biphasic charge recombination and accumulation in TiO2 mesoporous structured perovskite solar cells.

Organic-inorganic halide perovskite solar cells are becoming the next big thing in the photovoltaic field owing to their rapidly developing photoelectric conversion performance. Herein, mesoporous structured perovskite devices with various perovskite grain sizes are fabricated by a sequential dropping method, and the charge recombination dynamics is investigated by transient optical-electric measurements. All devices exhibit an overall power conversion efficiency around 15%.

Trap-limited charge recombination in intrinsic perovskite film and meso-superstructured perovskite solar cells and the passivation effect of the hole-transport material on trap states.

Charge recombination dynamics in intrinsic perovskite film and in meso-superstructured perovskite solar cells have been systematically studied, which are found to be mediated by the energetic distribution of intra-gap trap states as described by the trap-limited recombination theory. Besides, the passivation effect of the hole-transport material on trap states is discussed.