Fast Kinetics Enabled by Ion Enrichment Layer for Dendrite-Free Zinc Anode.

Aqueous zinc-ion batteries (AZIBs) are considered a promising choice for energy storage devices owing to the excellent safety and favorable capacity of the Zn anode. However, the uncontrolled dendrite growth of Zn anode severely constrains the practical applications of AZIBs. Herein, a novel ion enrichment layer of CuS is designed and constructed on the Zn foil surface to achieve dendrite-free Zn anode.

Sulfur-Vacancy Engineering Accelerates Rapid Surface Reconstruction in Ni-Co Bimetal Sulfide Nanosheet for Urea Oxidation Electrocatalysis.

Developing a highly efficient catalyst for electrocatalytic urea oxidation reaction (UOR) is not only beneficial for the degradation of urea pollutants in wastewater but also provides a benign route for hydrogen production. Herein, a sulfur-vacancy (S) engineering is proposed to accelerate the formation of metal (oxy)hydroxide on the surface of Ni-Co bimetal sulfide nanosheet arrays on nickel foam (S-CoNiS@NF) for boosting the urea oxidation electrocatalysis. As a result, the obtained S-CoNiS@NF demonstrates an outstanding electrocatalytic UOR performance, which requires a low potential of only 1.

In Situ Constructing Metal-Organic Complex Interface Layer Using Biomolecule Enabling Stabilize Zn Anode.

Aqueous zinc-ion batteries (ZIBs) are considered as a promising candidate for next-generation large-scale energy storage due to their high safety, low cost, and eco-friendliness. Unfortunately, commercialization of ZIBs is severely hindered owing to rampant dendrite growth and detrimental side reactions on the Zn anode. Herein, inspired by the metal-organic complex interphase strategy, the authors apply adenosine triphosphate (ATP) to in situ construct a multifunctional film on the metal Zn surface (marked as ATP@Zn) by a facile etching method.