Study on the relationships between the oil HLB value and emulsion stabilization.

In order to study the relationship between the HLB value of oil and emulsion stabilization, the optimal formation of emulsification system was determined, and then, the properties of emulsion, such as particle size, stability, interfacial tension and zeta potential, were tested by laser particle analyzer, stability analyzer, and interfacial tensiometer. Experimental results showed that the optimal ratio of emulsification was Tween 80 : Span 80 = 5 : 5. Meanwhile, when the HLB value of the emulsification system was close to that of oil, the emulsion exhibited the best stability.

Characteristics of Weak-Gel Flooding and Its Application in LD10-1 Oilfield.

Weak gel is a kind of three-dimensional cross-linking system with low polymer concentration and appropriate cross-linking agents, dominated by intermolecular cross-linking, supplemented by intramolecular cross-linking, and with a weak cross-linking degree. In this paper, the microstructure and properties of the weak gel were observed and evaluated under different conditions. Seepage behavior experiments and parallel core displacement experiments were carried out to evaluate profile control and flooding performance of the weak gel.

Doubly Dynamic Hydrogel Formed by Combining Boronate Ester and Acylhydrazone Bonds.

The incorporation of double dynamic bonds into hydrogels provides an effective strategy to engineer their performance on demand. Herein, novel hydrogels were PREPARED by combining two kinetically distinct dynamic covalent bonds, boronate ester and acylhydrazone bonds, and the synergistic properties of the hydrogels were studied comprehensively. The functional diblock copolymers P(-isopropyl acrylamide-co--acryloyl-3-aminophenylboronic acid)-b-(-isopropyl acrylamide-co-diacetone acrylamide) (PAD) were prepared via reversible addition-fragmentation chain transfer (RAFT) polymerization.

Insights into the Assembly of the Pseudogemini Surfactant at the Oil/Water Interface: A Molecular Simulation Study.

The interfacial assembly process and configuration of the pseudogemini surfactant fabricated by sodium dodecyl benzene sulfonate (SDBS) and 4,4'-oxydianilinium chloride (ODC) were studied using quantum mechanical calculations and molecular dynamics (MD) simulations. The MD simulation results revealed that SDBS and ODC showed the vertical and horizontal arrangements at the oil/water interface, respectively, and the interfacial assembled configuration presented an unexpected "H" shape rather than the traditional "U" shape. The radial distribution functions between the head groups and water molecules were employed to explore the effects of the surrounding water molecules on the SDBS/ODC interaction.

Wormlike micelles with a unique ladder shape formed by a C-tailed zwitterionic surfactant bearing a bulky piperazine group.

Wormlike micelles (WLMs) have been successfully constructed from many different C-tailed surfactants. Here, we creatively introduced a bulky piperazine group onto a C-tailed zwitterionic surfactant, N-erucamidopropyl-N,N-piperazine-N-methyl ammonium propanesulfonate (EDPS), and investigated the micellar structure and properties of the EDPS WLMs via molecular dynamics simulation, cryo-TEM and rheological techniques. It was found that 25 mM EDPS increased the zero-shear viscosity to as high as ∼10 mPa s.

pH-Switchable IFT variations and emulsions based on the dynamic noncovalent surfactant/salt assembly at the water/oil interface.

Additional HCl can facilely control the dynamic noncovalent interaction between anionic surfactant sodium dodecyl benzene sulfonate (SDBS) and additional organic matter, 4,4'-oxydianiline (ODA), at the water/oil interface. At low HCl concentration (ODA/HCl molar ratio (r) = 1 : 1.5, [ODA] = 250 mg L-1), the ODA+ ions effectively enhanced the SDBS ability to reduce the water/oil interfacial tension (IFT) by about two orders of magnitude, while the (SDBS)2/ODA2+ gemini-like surfactants could be constructed at a relatively high HCl concentration (r = 1 : 4, [ODA] = 250 mg L-1), which could largely reduce the IFT to 1.

Wormlike micelles formed by sodium erucate in the presence of a tetraalkylammonium hydrotrope.

Anionic wormlike micelles, particularly those formed by long-chain carboxylate surfactants, are relatively less documented though their cationic or zwitterionic counterparts are frequently reported. In this study, the wormlike micelles of sodium erucate (NaOEr), a C22-tailed anionic surfactant with a monounsaturated tail, in the presence of a tetraalkylammonium hydrotrope were investigated for the first time. The different effects of two hydrotropes, benzyl trimethyl ammonium bromide (BTAB) and tetramethyl ammonium bromide (TMAB), on the phase behavior and rheological behaviors were compared, and the influences of surfactant concentration and temperature on the rheological properties of NaOEr solutions were also examined.