Dielectric capacitors are vital for modern power and electronic systems, and accurate assessment of their dielectric properties is paramount. However, in many prevailing reports, the fringing effect near electrodes and parasitic capacitance in the test circuit were often neglected, leading to overrated dielectric performances. Here, the serious impacts of the fringing effect and parasitic capacitance are investigated both experimentally and theoretically on different dielectrics including AlO, SrTiO, etc.
View Article and Find Full Text PDFBACKGROUND The aim of this study was to investigate the clinical utility of ultrasound shear wave elastography (SWE) for assessment of renal fibrosis in post-renal transplant patients. MATERIAL AND METHODS We selected 183 patients who underwent renal transplantation. The complete dataset was randomly partitioned into a training cohort (128 cases) and a validation cohort (55 cases).
View Article and Find Full Text PDFOxidative Balance Scores (OBS) are utilized to assess an individual's antioxidant status, encompassing both dietary and lifestyle factors that contribute to oxidative balance. This study investigates the relationship between OBS and chronic kidney disease (CKD) prevalence among U.S.
View Article and Find Full Text PDFACS Appl Mater Interfaces
May 2024
The recent discovery of ferroelectricity in pure ZrO has drawn much attention, but the information storage and processing performances of ferroelectric ZrO-based nonvolatile devices remain open for further exploration. Here, a ZrO (∼8 nm)-based ferroelectric capacitor using RuO oxide electrodes is fabricated, and the ferroelectric orthorhombic phase evolution under electric field cycling is studied. A ferroelectric remnant polarization (2) of >30 μC/cm, leakage current density of ∼2.
View Article and Find Full Text PDFACS Appl Mater Interfaces
March 2024
The commercial capacitor using dielectric biaxially oriented polypropylene (BOPP) can work effectively only at low temperatures (less than 105 °C). Polyphenylene oxide (PPO), with better heat resistance and a higher dielectric constant, is promising for capacitors operating at elevated temperatures, but its charge-discharge efficiency (η) degrades greatly under high fields at 125 °C. Here, SiO layers are magnetron sputtered on both sides of the PPO film, forming a composite material of SiO/PPO/SiO.
View Article and Find Full Text PDFThe big data era requires ultrafast, low-power, and silicon-compatible materials and devices for information storage and processing. Here, ferroelectric tunnel junctions (FTJs) based on SiO/HfZrO composite barrier and both conducting electrodes are designed and fabricated on Si substrates. The FTJ achieves the fastest write speed of 500 ps under 5 V (2 orders of magnitude faster than reported silicon-compatible FTJs) or 10 ns speed at a low voltage of 1.
View Article and Find Full Text PDFPolymer dielectric capacitors are fundamental in advanced electronics and power grids but suffer from low energy density, hindering miniaturization of compact electrical systems. It is shown that high-energy and strong penetrating γ-irradiation significantly enhances capacitive energy storage performance of polymer dielectrics. γ-irradiated biaxially oriented polypropylene (BOPP) films exhibit an extraordinarily high energy density of 10.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2023
The emergence of complementary metal-oxide semiconductor (CMOS)-compatible HfO-based ferroelectric materials provides a promising way to achieve ferroelectric field-effect transistors (FeFETs) with a steep subthreshold swing (SS) reduced to below the Boltzmann thermodynamics limit (∼60 mV/dec at room temperature), which has important implications for lowering power consumption. In this work, a metal-oxide-semiconductor field-effect transistor (MOSFET) is connected with HfZrO (HZO)-based ferroelectric capacitors with different capacitances. By adjusting the capacitance of ferroelectric capacitors, an ultralow of ∼0.
View Article and Find Full Text PDFPolymer dielectrics with high operation temperature (∼150 °C) and excellent capacitive energy storage performance are vital for electric power systems and advanced electronic devices. Here, a very convenient and competitive strategy by preparing ultraviolet-irradiated cyclic olefin copolymer films is demonstrated to be effective in improving the energy storage performance at high temperatures. Compared with the unirradiated film, irradiated films exhibit a higher dielectric constant, higher breakdown strength and stronger mechanical properties as a result of the emergence of the carbonyl group and cross-linking network.
View Article and Find Full Text PDFElectrical modulation of magnetic states in single-phase multiferroic materials, using domain-wall magnetoelectric (ME) coupling, can be enhanced substantially by controlling the population density of the ferroelectric (FE) domain walls during polarization switching. In this work, we investigate the domain-wall ME coupling in multiferroic h-YbFeO thin films, in which the FE domain walls induce clamped antiferromagnetic (AFM) domain walls with reduced magnetization magnitude. Simulation according to the phenomenological theory indicates that the domain-wall ME effect is dramatically enhanced when the separation between the FE domain walls shrinks below the characteristic width of the clamped AFM domain walls during the ferroelectric switching.
View Article and Find Full Text PDFThe weakly correlated nature of 5d oxide SrIrO determines its rare ferromagnetism, and the control of its magnetic order is even less studied. Tailoring structure distortion is currently a main route to tune the magnetic order of 5d iridates, but only for the spatially confined insulating counterparts. Here, we have realized ferromagnetic order in metallic SrIrO by construction of SrIrO/ferromagnetic-insulator (LaCoO) superlattices, which reveal a giant coercivity of ∼10 T and saturation field of ∼25 T with strong perpendicular magnetic anisotropy.
View Article and Find Full Text PDFSupercritical relaxor nanograined ferroelectrics are demonstrated for high-performance dielectric capacitors, showing record-high overall properties of energy density ≈13.1 J cm and field-insensitive efficiency ≈90% at ≈74 kV mm and superior charge-discharge performances of high power density ≈700 MW cm , high discharge energy density ≈6.67 J cm , and ultrashort discharge time <40 ns at 55 kV mm .
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2022
Ferroelectric tunnel junction (FTJ) is one promising candidate for next-generation nonvolatile data storage and neural network computing systems. In this work, the high-performance 50 nm-diameter Au/Ti/PbZrTiO (∼3 nm, (111)-oriented)/Nb:SrTiO (Nb: 0.7 wt %) FTJs are achieved to demonstrate the scaling down capability of FTJ.
View Article and Find Full Text PDFHybrid halide perovskites have emerged as highly promising photovoltaic materials because of their exceptional optoelectronic properties, which are often optimized via compositional engineering like mixing halides. It is well established that hybrid perovskites undergo a series of structural phase transitions as temperature varies. In this work, the authors find that phase transitions are substantially suppressed in mixed-halide hybrid perovskite single crystals of MAPbI Br (MA = CH NH and x = 1 or 2) using a complementary suite of diffraction and spectroscopic techniques.
View Article and Find Full Text PDFBackground: Abnormal expression of splicing factor 3A subunit 3 (SF3A3), a component of the spliceosome, has been confirmed to be related to the occurrence and development of various cancers. However, the expression and function of SF3A3 in bladder cancer (BC) remains unclear.
Methods: The SF3A3 mRNA and protein level were measured in clinical samples and cell lines by quantitative real-time PCR, Western blot and immunofluorescence staining.
The rapid development of neuro-inspired computing demands synaptic devices with ultrafast speed, low power consumption, and multiple non-volatile states, among other features. Here, a high-performance synaptic device is designed and established based on a Ag/PbZrTiO (PZT, (111)-oriented)/Nb:SrTiO ferroelectric tunnel junction (FTJ). The advantages of (111)-oriented PZT (~1.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2022
HfO-based ferroelectric materials are good candidates for constructing next-generation nonvolatile memories and high-performance electronic synapses and have attracted extensive attention from both academia and industry. Here, a HfZrO-based ferroelectric tunnel junction (FTJ) memristor is successfully fabricated by epitaxially growing a HfZrO film on a 0.7 wt % Nb-doped SrTiO (001) substrate with a buffer layer of LaSrMnO (∼1 u.
View Article and Find Full Text PDFThe developments of next-generation electric power systems and electronics demand for high temperature (≈150 °C), high energy density, high efficiency, scalable, and low-cost polymer-based dielectric capacitors are still scarce. Here, the nanocomposites based on polyimide-poly(amic acid) copolymers with a very low amount of boron nitride nanosheets are designed and synthesized. Under the actual working condition in hybrid electric vehicles of 200 MV m and 150 °C, a high energy density of 1.
View Article and Find Full Text PDFRNA-binding motif protein 24 (RBM24) acts as a multifunctional determinant of cell fate, proliferation, apoptosis, and differentiation during development by regulating premRNA splicing and mRNA stability. It is also implicated in carcinogenesis, but the functions of RBM24 in bladder cancer (BC) remain unclear. In the present study, we revealed that RBM24 was upregulated in BC tissues.
View Article and Find Full Text PDFWe report that continuous MOF films with highly controlled thickness (from 44 to 5100 nm) can be deposited over length scales greater than 80 centimeters by a facile, fast, and cost-effective spray-coating method. Such success relies on our discovery of unprecedented perfectly dispersed colloidal solutions consisting of amorphous MOF nanoparticles, which we adopted as precursors that readily converted to the crystalline films upon low-temperature in situ heating. The colloidal solutions allow for the fabrication of compact and uniform MOF films on a great deal of substrates such as fluorine-doped tin oxide, glass, SiO , Al O , Si, Cu, and even flexible polycarbonate, widening their technological applications where substrates are essential.
View Article and Find Full Text PDFBackground: Circular RNAs (circRNAs) have received increasing attention in cancer development. However, a substantial number of circRNAs still require characterization. The purpose of this study is to uncover novel circRNAs and their molecular mechanism in bladder cancer (BCa).
View Article and Find Full Text PDFNanotechnology
September 2020
We report on the thermal and thermoelectric properties of individual nanocrystalline Bi Te nanotubes synthesized by the solution phase method using 3ω method and a microfabricated testbench. Measurements show that the nanotubes offer improved ZT compared to bulk BiTe near room temperature due to an enhanced Seebeck coefficient and suppressed thermal conductivity. This improvement in ZT originates from the nanocrystalline nature and low dimensionality of the nanotubes.
View Article and Find Full Text PDFPolymer-based dielectric materials play a key role in advanced electronic devices and electric power systems. Although extensive research has been devoted to improve their energy-storage performances, it is a great challenge to increase the breakdown strength of polymer nanocomposites in terms of achieving high energy density and good reliability under high voltages. Here, a general strategy is proposed to significantly improve their breakdown strength and energy storage by adding negatively charged Ca Nb O nanosheets.
View Article and Find Full Text PDFNext-generation non-volatile memories with ultrafast speed, low power consumption, and high density are highly desired in the era of big data. Here, we report a high performance memristor based on a Ag/BaTiO/Nb:SrTiO ferroelectric tunnel junction (FTJ) with the fastest operation speed (600 ps) and the highest number of states (32 states or 5 bits) per cell among the reported FTJs. The sub-nanosecond resistive switching maintains up to 358 K, and the write current density is as low as 4 × 10 A cm.
View Article and Find Full Text PDFThe transcription factor E2F1 regulates the expression of the miR-20b-5p precursor and is involved in epithelial-to-mesenchymal transition (EMT). Transforming growth factor-β1 (TGF-β1) induces EMT in prostate cancer (PCa) by binding to TGF-beta receptor 2 (TGFBR2) to activate TGF-β signaling. However, the relationship between TGFBR2, E2F1, and miR-20b-5p in the modulation of EMT in PCa cells remains unknown.
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