Janus Membrane with a Dense Hydrophilic Surface Layer for Robust Fouling and Wetting Resistance in Membrane Distillation: New Insights into Wetting Resistance.

Although membrane distillation (MD) has been identified as a promising technology to treat hypersaline wastewaters, its practical applications face two prominent challenges: membrane wetting and fouling. Herein, we report a facile and scalable approach for fabricating a Janus MD membrane comprising a dense polyvinyl alcohol (PVA) surface layer and a hydrophobic polyvinylidene fluoride (PVDF) membrane substrate. By testing the Janus membrane in direct contact MD experiments using feeds containing a sodium dodecyl sulfate (SDS) surfactant or/and mineral oil, we demonstrated that the dense Janus membrane can simultaneously resist wetting and fouling.

Comparison of Energy Consumption of Osmotically Assisted Reverse Osmosis and Low-Salt-Rejection Reverse Osmosis for Brine Management.

Minimum and zero liquid discharge (MLD/ZLD) are emerging brine management strategies that attract heightened attention. Although conventional reverse osmosis (RO) can improve the energy efficiency of MLD/ZLD processes, its application is limited by the maximum hydraulic pressure (Δ) that can be applied in current membrane modules. To overcome such limitation, novel RO-based technologies, including osmotically assisted RO (OARO) and low-salt-rejection RO (LSRRO), have been proposed.

Nanofiltration-Inspired Janus Membranes with Simultaneous Wetting and Fouling Resistance for Membrane Distillation.

Membranes with robust antiwetting and antifouling properties are highly desirable for membrane distillation (MD) of wastewater. Herein, we have proposed and demonstrated a highly effective method to mitigate wetting and fouling by designing nanofiltration (NF)-inspired Janus membranes for MD applications. The NF-inspired Janus membrane (referred to as PVDF-P-CQD) consists of a hydrophobic polyvinylidene fluoride (PVDF) membrane and a thin polydopamine/polyethylenimine (PDA/PEI) layer grafted by sodium-functionalized carbon quantum dots (Na-CQDs) to improve its hydrophilicity.

Can Composite Janus Membranes with an Ultrathin Dense Hydrophilic Layer Resist Wetting in Membrane Distillation?

Tackling membrane wetting is an ongoing challenge for large-scale applications of membrane distillation (MD). Herein, composite Janus MD membranes comprising an ultrathin dense hydrophilic layer are developed by layer-by-layer assembling cationic polyethyleneimine and anionic poly(sodium 4-styrenesulfonate) polyelectrolytes on a hydrophobic polyvinylidene fluoride substrate. Using surfactant-containing saline water as the feed with low surface tension, experiments reveal that the number of polyelectrolyte layers, rather than surface wettability or surface charge, determines the anti-wetting performance of the composite Janus membranes.

Design of omniphobic interfaces for membrane distillation - A review.

Membrane distillation (MD) has a great potential in treating high salinity industrial wastewater due to its unique characteristics. Nevertheless, the implementation of MD for industrial wastewater reclamation must be conducted with precaution because low-surface-tension contaminates in feed solutions may easily wet the membranes. In recent years, omniphobic membranes that exhibit strong repellence towards liquids with a wide range of surface tensions have been proposed as a promising solution to deal with the wetting problem.